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    Process for the preparation of a mono-N-alkylpiperazine
    11.
    发明授权
    Process for the preparation of a mono-N-alkylpiperazine 有权
    制备单-N-烷基哌嗪的方法

    公开(公告)号：US08927712B2

    公开(公告)日：2015-01-06

    申请号：US13906931

    申请日：2013-05-31

    Applicant: BASF SE

    Inventor： Roland Bou Chedid ,  Johann-Peter Melder ,  Ulrich Abel ,  Roman Dostalek ,  Bernd Stein

    IPC: C07D241/04 ,  C07D295/00 ,  C07D295/088 ,  B01J23/83 ,  B01J35/02 ,  B01J37/00 ,  B01J37/03 ,  C07D295/03 ,  B01J37/08 ,  B01J37/18

    CPC classification number: C07D295/088 ,  B01J23/83 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  B01J2523/00 ,  C07D295/03 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/3706

    Abstract: Process for the preparation of a mono-N-alkylpiperazine of the formula I in which R1 is C1- to C5-alkyl or 2-(2-hydroxyethoxy)ethyl, by reacting diethanolamine (DEOA) of the formula II with a primary amine of the formula H2N—R1 (III) in the presence of hydrogen and a catalyst molding, where the reaction is carried out in the liquid phase at an absolute pressure in the range from 150 to 250 bar and the amination is carried out by means of a catalyst molding, the precursor of which can be prepared according to a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide is provided, (ii) pulverulent metallic copper and/or copper flakes and optionally graphite is added to the oxidic material, (iii) the mixture resulting from step ii is shaped to give a molding, where the oxidic material is obtainable by simultaneous or successive precipitation of the component copper oxide, of the component aluminum oxide and of the component lanthanum oxide and subsequent drying and calcination and, after the shaping according to step iii, the catalyst molding is calcined again.

    Abstract translation: 通过使式II的二乙醇胺（DEOA）与式Ⅰ的伯胺反应制备其中R 1为C 1 -C 5 - 烷基或2-（2-羟基乙氧基）乙基的式I的单-N-烷基哌嗪的方法 在氢气和催化剂模塑的存在下，式H2N-R1（III），其中反应在150-250巴的绝对压力下在液相中进行，并且胺化通过 催化剂成型，其前体可以根据其中（i）包含氧化铜，氧化铝和氧化镧的氧化物质的方法制备，（ii）加入粉末状金属铜和/或铜片以及任选的石墨 （iii）由步骤ii得到的混合物成型为得到模制品，其中氧化物质可通过组分氧化铜，组分氧化铝和组分氧化镧同时或连续沉淀获得，以及 随后的干燥和煅烧，并且根据步骤iii的成型后，再次煅烧催化剂成型。

    Process for the preparation of a mono-N-alkypiperazine
    12.
    发明授权
    Process for the preparation of a mono-N-alkypiperazine 有权
    制备单-N-哌嗪的方法

    公开(公告)号：US08884015B2

    公开(公告)日：2014-11-11

    申请号：US13906960

    申请日：2013-05-31

    Applicant: BASF SE

    Inventor： Roland Bou Chedid ,  Johann-Peter Melder ,  Ulrich Abel ,  Roman Dostalek ,  Bernd Stein

    IPC: C07D241/04 ,  C07D295/00 ,  C07D295/088 ,  C07D295/03 ,  B01J23/835

    CPC classification number: C07D295/088 ,  B01J23/835 ,  C07D295/03

    Abstract: Process for the preparation of a mono-N-alkylpiperazine of the formula I in which R1 is C1- to C5-alkyl or 2-(2-hydroxyethoxy)ethyl, by reacting diethanolamine (DEOA) of the formula II with a primary amine of the formula H2N—R1 (III) in the presence of hydrogen and a supported, metal-containing catalyst, where the catalytically active mass of the catalyst, prior to its reduction with hydrogen, comprises oxygen-containing compounds of aluminum, copper, nickel and cobalt and, in the range from 0.2 to 5.0% by weight, oxygen-containing compounds of tin, calculated as SnO, and the reaction is carried out in the liquid phase at an absolute pressure in the range from 95 to 145 bar.

    Abstract translation: 通过使式II的二乙醇胺（DEOA）与式Ⅰ的伯胺反应制备其中R 1为C 1 -C 5 - 烷基或2-（2-羟基乙氧基）乙基的式I的单-N-烷基哌嗪的方法 在氢气和负载的含金属催化剂存在下，式H2N-R1（III），其中催化剂的催化活性物质在用氢还原之前包含含铝的铝，铜，镍和 钴，并且在0.2至5.0重量％的范围内，以SnO计算的含锡化合物的锡和反应在液相中以95至145巴的绝对压力进行。

    Process for the Preparation of a Mono-N-Alkypiperazine
    14.
    发明申请
    Process for the Preparation of a Mono-N-Alkypiperazine 有权
    单-N-哌啶的制备方法

    公开(公告)号：US20130324732A1

    公开(公告)日：2013-12-05

    申请号：US13906960

    申请日：2013-05-31

    Applicant: BASF SE

    Inventor： Roland Bou Chedid ,  Johann-Peter Melder ,  Ulrich Abel ,  Roman Dostalek ,  Bernd Stein

    IPC: C07D295/088 ,  B01J23/835 ,  C07D295/03

    CPC classification number: C07D295/088 ,  B01J23/835 ,  C07D295/03

    Abstract: Process for the preparation of a mono-N-alkylpiperazine of the formula I in which R1 is C1- to C5-alkyl or 2-(2-hydroxyethoxy)ethyl, by reacting diethanolamine (DEOA) of the formula II with a primary amine of the formula H2N—R1 (III) in the presence of hydrogen and a supported, metal-containing catalyst, where the catalytically active mass of the catalyst, prior to its reduction with hydrogen, comprises oxygen-containing compounds of aluminum, copper, nickel and cobalt and, in the range from 0.2 to 5.0% by weight, oxygen-containing compounds of tin, calculated as SnO, and the reaction is carried out in the liquid phase at an absolute pressure in the range from 95 to 145 bar.

    Abstract translation: 通过使式II的二乙醇胺（DEOA）与式Ⅰ的伯胺反应制备其中R 1为C 1 -C 5 - 烷基或2-（2-羟基乙氧基）乙基的式I的单-N-烷基哌嗪的方法 在氢气和负载的含金属催化剂存在下，式H2N-R1（III），其中催化剂的催化活性物质在用氢还原之前包含含铝的铝，铜，镍和 钴，并且在0.2至5.0重量％的范围内，以SnO计算的含锡化合物的锡和反应在液相中以95至145巴的绝对压力进行。

    PROCESS FOR THE PREPARATION OF A MONO-N-ALKYLPIPERAZINE
    15.
    发明申请
    PROCESS FOR THE PREPARATION OF A MONO-N-ALKYLPIPERAZINE 有权
    制备单-N-烷基哌嗪的方法

    公开(公告)号：US20130324731A1

    公开(公告)日：2013-12-05

    申请号：US13906931

    申请日：2013-05-31

    Applicant: BASF SE

    Inventor： Roland Bou Chedid ,  Johann-Peter Melder ,  Ulrich Abel ,  Roman Dostalek ,  Bernd Stein

    IPC: C07D295/088 ,  C07D295/03 ,  B01J23/83

    CPC classification number: C07D295/088 ,  B01J23/83 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  B01J2523/00 ,  C07D295/03 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/3706

    Abstract: Process for the preparation of a mono-N-alkylpiperazine of the formula I in which R1 is C1- to C5-alkyl or 2-(2-hydroxyethoxy)ethyl, by reacting diethanolamine (DEOA) of the formula II with a primary amine of the formula H2N—R1 (III) in the presence of hydrogen and a catalyst molding, where the reaction is carried out in the liquid phase at an absolute pressure in the range from 150 to 250 bar and the amination is carried out by means of a catalyst molding, the precursor of which can be prepared according to a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide is provided, (ii) pulverulent metallic copper and/or copper flakes and optionally graphite is added to the oxidic material, (iii) the mixture resulting from step ii is shaped to give a molding, where the oxidic material is obtainable by simultaneous or successive precipitation of the component copper oxide, of the component aluminum oxide and of the component lanthanum oxide and subsequent drying and calcination and, after the shaping according to step iii, the catalyst molding is calcined again.

    Abstract translation: 通过使式II的二乙醇胺（DEOA）与式Ⅰ的伯胺反应制备其中R 1为C 1 -C 5 - 烷基或2-（2-羟基乙氧基）乙基的式I的单-N-烷基哌嗪的方法 在氢气和催化剂模塑的存在下，式H2N-R1（III），其中反应在150-250巴的绝对压力下在液相中进行，并且胺化通过 催化剂成型，其前体可以根据其中（i）包含氧化铜，氧化铝和氧化镧的氧化物质的方法制备，（ii）加入粉末状金属铜和/或铜片以及任选的石墨 （iii）由步骤ii得到的混合物成型为得到模制品，其中氧化材料可通过组分氧化铜，组分氧化铝和组分氧化镧同时或连续沉淀获得，以及 苏 随后干燥和煅烧，并且在根据步骤iii成形之后，再次煅烧催化剂成型。

    Method for depleting 2-methoxyethanol (MOE)
    18.
    发明授权
    Method for depleting 2-methoxyethanol (MOE) 有权

    公开(公告)号：US11214555B2

    公开(公告)日：2022-01-04

    申请号：US16971660

    申请日：2019-02-11

    Applicant: BASF SE

    Inventor： Eva Koch ,  Oliver Bussmann ,  Joachim Pfeffinger ,  Joerg Pastre ,  Johann-Peter Melder

    IPC: C07D295/023 ,  C07D295/027 ,  C07C41/42

    Abstract: A process for the depletion of 2-methoxyethanol (MOE) from a mixture comprising predominantly morpholine (MO) (crude morpholine), wherein crude morpholine is distilled in a distillation column in the presence of an alkali metal compound of the general formula M+[RO−] (M+ is alkali metal cation and R is hydrogen (H), methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, sec-butyl or tert-butyl), where MO and a compound of the general formula R—OH are distilled off and an alkali metal methoxyethoxide of the general formula M+[MeOEtO−] is obtained in the bottom of the column.

    Method for producing ethyleneamines
    19.
    发明授权
    Method for producing ethyleneamines 有权

    公开(公告)号：US11214535B2

    公开(公告)日：2022-01-04

    申请号：US16619987

    申请日：2018-05-24

    Applicant: BASF SE

    Inventor： Regine Helga Bebensee ,  Thomas Heidemann ,  Barbara Becker ,  Eva Koch ,  Hermann Luyken ,  Johann-Peter Melder

    IPC: C07C215/08 ,  B01J23/46 ,  B01J23/75 ,  B01J8/24 ,  B01J8/18 ,  B01J21/02 ,  B01J21/06

    Abstract: The invention relates to processes for preparing alkanolamines and ethyleneamines in the liquid phase, by reacting ethylene glycol and/or monoethanolamine with ammonia in the presence of an amination catalyst comprising one or more active metals selected from Sn and the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements, wherein the amination catalyst is obtained by reductive calcination of a catalyst precursor. The catalyst precursor here is preferably prepared by contacting a conventional or catalytic support material with one or more soluble compounds of the active metals and optionally one or more soluble compounds of added catalyst elements. The present invention further relates to a process for preparing an amination catalyst comprising one or more active metals selected from Sn and the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements, the amination catalyst being obtained by reductive calcination of a catalyst precursor, wherein the reactor in which the catalyst precursor is reductively calcined is connected to a denox plant, and to the use of a denox plant in the preparation of amination catalysts.

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