公开(公告)号：US07182932B2

公开(公告)日：2007-02-27

申请号：US10769359

申请日：2004-01-30

Applicant: Wilson H. Onimus ,  Bernard Cooker ,  Edrick Morales

Inventor： Wilson H. Onimus ,  Bernard Cooker ,  Edrick Morales

IPC: B01J29/89 ,  C07D301/04 ,  C07D301/12

CPC classification number: C07D301/06 ,  B01J29/405 ,  B01J29/44 ,  B01J37/0045 ,  B01J37/0203 ,  B01J37/18 ,  C07D301/12 ,  Y02P20/52

Abstract: A TS-1 catalyst suitable for the production of oxirane compounds is prepared by subjecting conventionally formed TS-1 to a size reduction treatment such as milling such that the average particle size weighted by volume of the TS-1 is reduced to less than 10 microns in diameter and the size reduced TS-1 is spray dried.

Abstract translation: 通过对常规形成的TS-1进行诸如研磨之类的尺寸减小处理使得将TS-1的体积加权的平均粒径减小到小于10微米的方法制备适用于生产环氧乙烷化合物的TS-1催化剂 直径和尺寸减小TS-1被喷雾干燥。

公开(公告)号：US20050171364A1

公开(公告)日：2005-08-04

申请号：US10769359

申请日：2004-01-30

Applicant: Wilson Onimus ,  Bernard Cooker ,  Edrick Morales

Inventor： Wilson Onimus ,  Bernard Cooker ,  Edrick Morales

IPC: B01J23/00 ,  C07D301/06 ,  C07D301/12

CPC classification number: C07D301/06 ,  B01J29/405 ,  B01J29/44 ,  B01J37/0045 ,  B01J37/0203 ,  B01J37/18 ,  C07D301/12 ,  Y02P20/52

Abstract: A TS-1 catalyst suitable for the production of oxirane compounds is prepared by subjecting conventionally formed TS-1 to a size reduction treatment such as milling such that the average particle size weighted by volume of the TS-1 is reduced to less than 10 microns in diameter and the size reduced TS-1 is spray dried.

Abstract translation: 通过对常规形成的TS-1进行诸如研磨之类的尺寸减小处理使得将TS-1的体积加权的平均粒径减小到小于10微米的方法制备适用于生产环氧乙烷化合物的TS-1催化剂 直径和尺寸减小TS-1被喷雾干燥。

公开(公告)号：US5675055A

公开(公告)日：1997-10-07

申请号：US539209

申请日：1995-10-04

Applicant: Thomas I. Evans ,  Bernard Cooker ,  Rajendra S. Albal

Inventor： Thomas I. Evans ,  Bernard Cooker ,  Rajendra S. Albal

IPC: C01D1/04 ,  C01D1/28 ,  C02F1/26 ,  C07C15/46 ,  C07D301/19 ,  C07D301/32 ,  C07D303/04 ,  C07C7/17 ,  C07C7/00

CPC classification number: C07D301/19 ,  C02F1/26 ,  C07C15/46 ,  C07D301/32

Abstract: The waste organics containing caustic stream from a propylene oxide/styrene monomer process is preferably first concentrated by distillation and then contacted with strong acid such as sulfuric acid and an organic solvent, the admixture is phase separated and an aqueous sodium containing phase reduced in organics is separated from an organic solvent phase reduced in sodium.

Abstract translation: 含有来自环氧丙烷/苯乙烯单体方法的苛性碱的废物优选首先通过蒸馏浓缩，然后与强酸如硫酸和有机溶剂接触，混合物相分离，有机物中还原的含钠水相是 与钠中有机溶剂相分离。

公开(公告)号：US07232783B2

公开(公告)日：2007-06-19

申请号：US11173350

申请日：2005-07-02

Applicant: Bernard Cooker ,  Roger A. Grey ,  Edrick Morales

Inventor： Bernard Cooker ,  Roger A. Grey ,  Edrick Morales

IPC: B01J21/00

CPC classification number: C07D301/08 ,  B01J23/38 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  Y02P20/52

Abstract: A process is provided for the production of a noble metal on TS-1 catalyst useful for the production of propylene oxide wherein TS-1 from hydrothermal crystallization has noble metal dispersed thereon, the resulting material is spray dried and template used in the crystallization is removed, the resulting product is treated with hydrogen to form active catalyst for propylene oxide production.

Abstract translation: 提供了一种在用于生产环氧丙烷的TS-1催化剂上生产贵金属的方法，其中来自水热结晶的TS-1分散有贵金属，所得材料被喷雾干燥并除去结晶中使用的模板 ，所得产物用氢气处理以形成用于环氧丙烷生产的活性催化剂。

公开(公告)号：US20050187395A1

公开(公告)日：2005-08-25

申请号：US11087776

申请日：2005-03-23

Applicant: Bernard Cooker ,  Wilson Onimus ,  Jennifer Jewson ,  Ralph Dessau

Inventor： Bernard Cooker ,  Wilson Onimus ,  Jennifer Jewson ,  Ralph Dessau

IPC: B01J29/89 ,  B01J35/02 ,  C01B37/00 ,  C07D301/12

CPC classification number: B01J29/89 ,  B01J35/023 ,  C01B37/005 ,  C07D301/12

Abstract: Large crystals of titanium silicalite or intergrowths of intergrown smaller crystals, having a mean particle size greater than 2 μm, have been found catalytically effective at commercially reasonable rates for the epoxidation of olefins in the presence of hydrogen peroxide. Crystals synthesized with a silica source having a low sodium content exhibit high levels of production and selectivity. The crystals have a low attrition rate and are easily filterable from a product stream.

Abstract translation: 已经发现，在双氧水存在下，以商业上合理的速率对烯烃的环氧化催化有效的大晶体的钛硅沸石或共生的较小结晶的共生长的平均粒径大于2μm。 用具有低钠含量的二氧化硅源合成的晶体表现出高水平的生产和选择性。 该晶体具有低的磨耗率，并且易于从产品流中过滤。

公开(公告)号：US06281369B1

公开(公告)日：2001-08-28

申请号：US09731565

申请日：2000-12-07

Applicant: Bernard Cooker ,  Jennifer D. Jewson ,  Wilson H. Onimus

Inventor： Bernard Cooker ,  Jennifer D. Jewson ,  Wilson H. Onimus

IPC: C07D30106

CPC classification number: C07D301/06 ,  C07D301/08

Abstract: The stability of a noble metal/titanium zeolite catalyst is improved by elevated temperature calcination with an oxygen containing gas; the catalyst is useful in epoxidation involving the reaction of olefin, oxygen and hydrogen.

Abstract translation: 贵金属/钛沸石催化剂的稳定性通过用含氧气体进行高温煅烧而提高; 该催化剂可用于涉及烯烃，氧和氢的反应的环氧化。

公开(公告)号：US5965480A

公开(公告)日：1999-10-12

申请号：US35005

申请日：1998-03-05

Applicant: Bernard Cooker ,  Anne M. Gaffney ,  Jennifer D. Jewson ,  Wilson H. Onimus

Inventor： Bernard Cooker ,  Anne M. Gaffney ,  Jennifer D. Jewson ,  Wilson H. Onimus

IPC: B01J27/138 ,  B01J23/66 ,  B01J27/10 ,  B01J27/232 ,  C07B61/00 ,  C07D301/10 ,  C07D303/04 ,  B01J23/48 ,  B01J23/50

CPC classification number: C07D301/10 ,  B01J23/66 ,  B01J27/10 ,  B01J27/232

Abstract: Direct oxidation of propylene to propylene oxide is accomplished using alkaline earth metal compound-supported silver catalysts containing an inorganic chloride promoter and a potassium promoter derived from a potassium salt containing a nitrogen oxyanion or precursor thereof.

Abstract translation: 丙烯到环氧丙烷的直接氧化是使用含有无机氯催化剂的碱土金属化合物负载的银催化剂和源自含有氮氧阴离子或其前体的钾盐的钾促进剂来实现的。

公开(公告)号：US20110098491A1

公开(公告)日：2011-04-28

申请号：US12589775

申请日：2009-10-28

Applicant: Bernard Cooker ,  Bi Le-Khac

Inventor： Bernard Cooker ,  Bi Le-Khac

IPC: C07D301/06 ,  C07D301/04

CPC classification number: C07D301/06 ,  C07D301/04

Abstract: The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of an alkanoic acid and a catalyst comprising a noble metal and a titanium zeolite, wherein the catalyst has not been reduced prior to epoxidation. This process surprisingly gives significantly improved productivity and reduced formation of unwanted propane compared to processes that do not use the alkanoic acid modifier.

Abstract translation: 本发明是在链烷酸和包含贵金属和钛沸石的催化剂存在下用氢和氧环氧化烯烃的方法，其中催化剂在环氧化之前没有还原。 与不使用链烷酸改性剂的方法相比，该方法令人惊奇地提供了显着提高的生产率并减少了不想要的丙烷的形成。

公开(公告)号：US07476770B2

公开(公告)日：2009-01-13

申请号：US11888600

申请日：2007-08-01

Applicant: Jay F. Miller ,  Bernard Cooker ,  Robert N. Cochran ,  Peter J. Whitman

Inventor： Jay F. Miller ,  Bernard Cooker ,  Robert N. Cochran ,  Peter J. Whitman

IPC: C07C27/00 ,  C07D301/02 ,  C07D301/12

CPC classification number: C07D303/04 ,  B01J23/06 ,  B01J23/60 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07D301/06

Abstract: The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.

Abstract translation: 本发明是一种包含钛或钒沸石，粘合剂和氧化锌的催化剂，其中催化剂正在制备沸石，粘合剂源和氧化锌源的含水混合物，并使混合物快速干燥。 该催化剂可用于烯烃环氧化。

公开(公告)号：US20070276166A1

公开(公告)日：2007-11-29

申请号：US11888600

申请日：2007-08-01

Applicant: Jay Miller ,  Bernard Cooker ,  Robert Cochran ,  Peter Whitman

Inventor： Jay Miller ,  Bernard Cooker ,  Robert Cochran ,  Peter Whitman

IPC: B01J29/04 ,  C07C27/00

CPC classification number: C07D303/04 ,  B01J23/06 ,  B01J23/60 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07D301/06

Abstract: The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.