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公开(公告)号：US07427583B2
公开(公告)日：2008-09-23
申请号：US10497376
申请日：2002-12-20
Applicant: Isabelle Couillet , Trevor Hughes
Inventor： Isabelle Couillet , Trevor Hughes
IPC: C09K8/68
CPC classification number: C09K8/62 , C09K8/68 , C09K2208/30
Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a viscoelastic surfactant and a hydrophobically-modified polymer wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.
Abstract translation: 本发明涉及用于回收烃类的水性粘弹性压裂液。 根据本发明，流体包含粘弹性表面活性剂和疏水改性聚合物，其中疏水改性聚合物的浓度在其重叠浓度c *与其缠结浓度c e之间。
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公开(公告)号：US20110053807A1
公开(公告)日：2011-03-03
申请号：US12550999
申请日：2009-08-31
Applicant: Mohan K.R. Panga , Isabelle Couillet , Carlos Abad
Inventor： Mohan K.R. Panga , Isabelle Couillet , Carlos Abad
CPC classification number: C09K8/08 , C04B28/02 , C04B2103/0052 , C09K8/487 , C09K8/512 , C09K8/685 , C04B24/38
Abstract: The invention discloses a method of controlling fluid loss from a subterranean formation of a well bore. In a first aspect, the method is done by providing a treatment fluid made of an aqueous fluid and a hydrophobic polymer; and introducing the treatment fluid into the wellbore. In a second aspect, the method is done by providing a treatment fluid made of water and a water soluble polymer; providing in the treatment fluid a fluid loss additive having a hydrophobic polymer; using the treatment fluid in a well bore of a subterranean formation; allowing the treatment fluid to establish a permeable filter cake with the water soluble polymer in at least a portion of the well bore; and allowing hydrophobic polymer to enter into the filter cake to reduce permeability of the filter cake.
Abstract translation: 本发明公开了一种控制来自井下地层的流体损失的方法。 在第一方面，该方法通过提供由含水流体和疏水聚合物制成的处理流体来完成; 并将处理流体引入井眼。 在第二方面，该方法通过提供由水和水溶性聚合物制成的处理流体来完成; 在处理流体中提供具有疏水性聚合物的流体损失添加剂; 在地层的井眼中使用处理流体; 允许处理流体在井眼的至少一部分中与水溶性聚合物建立可渗透的滤饼; 并且允许疏水性聚合物进入滤饼以降低滤饼的渗透性。
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13.发明申请MICROEMULSION TO IMPROVE SHALE GAS PRODUCTION BY CONTROLLING WATER IMBIBITION 审中-公开通过控制水污染改善微生物气体生产的微乳液公开(公告)号：US20110021386A1
公开(公告)日：2011-01-27
申请号：US12836082
申请日：2010-07-14
Applicant: Syed A. Ali , Isabelle Couillet , Kevin W. England , Mathew M. Samuel
Inventor： Syed A. Ali , Isabelle Couillet , Kevin W. England , Mathew M. Samuel
IPC: C09K8/68
CPC classification number: C09K8/035 , C09K8/584 , C09K8/602 , C09K8/68 , C09K2208/30 , C10G1/04 , C10G2300/4037 , C10G2300/44 , C10G2300/802
Abstract: The invention provides a method for treating tight gas sand and shale subterranean formations, the method comprising: forming a solvent-surfactant blend by combining a solvent, a surfactant and a co-surfactant; adding a diluent to the solvent-surfactant blend to form a micro emulsion; wherein the wettability of the formation altered from water-wet to gas-wet, and the amount of water imbibed into the formation is reduced.
Abstract translation: 本发明提供了一种处理紧密气砂和页岩地下地层的方法，所述方法包括：通过混合溶剂，表面活性剂和辅助表面活性剂形成溶剂 - 表面活性剂共混物; 向溶剂 - 表面活性剂混合物中加入稀释剂以形成微乳液; 其中地层的润湿性从湿润变为气湿，并且吸入地层的水量减少。
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公开(公告)号：US20080314594A1
公开(公告)日：2008-12-25
申请号：US11767589
申请日：2007-06-25
Applicant: John W. Still , Isabelle Couillet , Bruce A. MacKay , Ryan Hartman
Inventor： John W. Still , Isabelle Couillet , Bruce A. MacKay , Ryan Hartman
IPC: E21B43/27
CPC classification number: C09K8/72
Abstract: The invention provides a method of treating a sandstone-containing subterranean formation penetrated by a wellbore. The method is carried out by forming a slurry of a carrier fluid containing a viscosifying agent and encapsulated particles of a hydrogen fluoride source without settling of the particles. The carrier fluid may be an acid-based carrier fluid. The encapsulated hydrogen fluoride source may be encapsulated with a solid polymer acid precursor. The hydrogen fluoride source is present within the slurry in an amount of about 10% or more by weight of the slurry. The slurry is introduced into the wellbore at a pressure above the fracture pressure of the formation under conditions wherein the hydrogen fluoride source is released.
Abstract translation: 本发明提供了一种处理由井筒渗透的含砂岩的地层的方法。 该方法通过在不沉降颗粒的情况下形成含有增粘剂和包封的氟化氢源的颗粒的载体流体的浆液来进行。 载体流体可以是酸基载体流体。 封装的氟化氢源可以用固体聚合物酸前体包封。 氟化氢源以浆料的重量计约10％或更多的量存在于浆料内。 在释放氟化氢源的条件下，将浆料以高于地层断裂压力的压力引入井筒。
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15.发明授权公开(公告)号：US08802601B2
公开(公告)日：2014-08-12
申请号：US12046221
申请日：2008-03-11
Applicant: Michael J. Fuller , Isabelle Couillet , Ryan Hartman
Inventor： Michael J. Fuller , Isabelle Couillet , Ryan Hartman
IPC: C09K8/86
CPC classification number: C09K8/74
Abstract: A method of treating a sandstone-containing formation penetrated by a wellbore is carried out by forming a treatment fluid comprising an aqueous fluid containing a hydrogen fluoride source and an amorphous silica precipitation inhibitor. The treatment fluid is introduced into the formation through the wellbore at a pressure below the fracture pressure of the formation to facilitate dissolution of formation materials, optionally as a single stage. The amorphous silica inhibitor may be a polycarboxylate and/or polycarboxylic acid, an organosilane or a phosphonate compound. The amorphous silica inhibitor may be capable of inhibiting precipitation of amorphous silica so that the treatment fluid contains at least about 500 ppm of silicon after at least about 100 minutes subsequent to the treatment fluid being introduced into the formation.
Abstract translation: 通过形成包含含有氟化氢源和无定形二氧化硅沉淀抑制剂的含水流体的处理流体来进行处理由井筒渗透的含砂岩地层的方法。 处理流体在低于地层断裂压力的压力下通过井筒被引入地层，以便于地层材料的溶解，任选地作为单一阶段。 无定形二氧化硅抑制剂可以是聚羧酸盐和/或多元羧酸，有机硅烷或膦酸盐化合物。 无定形二氧化硅抑制剂可以能够抑制无定形二氧化硅的沉淀，使得处理流体在处理流体被引入地层中至少约100分钟后含有至少约500ppm的硅。
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Patent Agency Ranking
公开(公告)号：US08143197B2
公开(公告)日：2012-03-27
申请号：US12176097
申请日：2008-07-18
Applicant: Isabelle Couillet , Trevor Hughes
Inventor： Isabelle Couillet , Trevor Hughes
CPC classification number: C09K8/62 , C09K8/68 , C09K2208/30
Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a cleavable viscoelastic surfactant and a hydrophobically-modified polymer, wherein the cleavable surfactant comprises a head group and a hydrophobic tail of at least 18 carbon atoms connected through a degradable acetal, amide, ether or ester bond and wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.
Abstract translation: 本发明涉及用于回收烃类的水性粘弹性压裂液。 根据本发明，流体包含可切割粘弹性表面活性剂和疏水改性的聚合物，其中可切割表面活性剂包含通过可降解的缩醛，酰胺，醚或酯键连接的头基和至少18个碳原子的疏水尾， 其中疏水改性聚合物的浓度在其重叠浓度c *与其缠结浓度ce之间。
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17.发明申请公开(公告)号：US20090233819A1
公开(公告)日：2009-09-17
申请号：US12046221
申请日：2008-03-11
Applicant: Michael J. Fuller , Isabelle Couillet , Ryan Hartman
Inventor： Michael J. Fuller , Isabelle Couillet , Ryan Hartman
CPC classification number: C09K8/74
Abstract: A method of treating a sandstone-containing formation penetrated by a wellbore is carried out by forming a treatment fluid comprising an aqueous fluid containing a hydrogen fluoride source and an amorphous silica precipitation inhibitor. The treatment fluid is introduced into the formation through the wellbore at a pressure below the fracture pressure of the formation to facilitate dissolution of formation materials, optionally as a single stage. The amorphous silica inhibitor may be a polycarboxylate and/or polycarboxylic acid, an organosilane or a phosphonate compound. The amorphous silica inhibitor may be capable of inhibiting precipitation of amorphous silica so that the treatment fluid contains at least about 500 ppm of silicon after at least about 100 minutes subsequent to the treatment fluid being introduced into the formation.
Abstract translation: 通过形成包含含有氟化氢源和无定形二氧化硅沉淀抑制剂的含水流体的处理流体来进行处理由井筒渗透的含砂岩地层的方法。 处理流体在低于地层断裂压力的压力下通过井筒被引入地层，以便于地层材料的溶解，任选地作为单一阶段。 无定形二氧化硅抑制剂可以是聚羧酸盐和/或多元羧酸，有机硅烷或膦酸盐化合物。 无定形二氧化硅抑制剂可以能够抑制无定形二氧化硅的沉淀，使得处理流体在处理流体被引入地层中至少约100分钟后含有至少约500ppm的硅。
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18.发明授权Methods for controlling the fluid loss properties of viscoelastic surfactant based fluids 有权用于控制基于粘弹性表面活性剂的流体的流体损失特性的方法公开(公告)号：US07081439B2
公开(公告)日：2006-07-25
申请号：US10707011
申请日：2003-11-13
Applicant: Philip Sullivan , Yenny Christanti , Isabelle Couillet , Stephen Davies , Trevor Hughes , Alexander Wilson
Inventor： Philip Sullivan , Yenny Christanti , Isabelle Couillet , Stephen Davies , Trevor Hughes , Alexander Wilson
IPC: C09K8/00
CPC classification number: C09K8/845 , C09K8/602 , C09K8/665 , C09K8/68 , C09K2208/10 , C09K2208/30 , E21B33/138
Abstract: Disclosed are methods of treating subterranean formations by first providing a suspension of colloidal particles prior to the injection of viscoelastic based treatment fluid, and injecting the treatment fluid into a well. The colloidal particles reduce fluid loss into the formation. According to a second embodiment, the treating fluid includes a hydrophobically-modified polymer, said hydrophobically-modified polymer being present at a concentration between approximately its overlap concentration c* and approximately its entanglement concentration ce. The method is particularly useful for fracturing operations in medium to high permeability formations.
Abstract translation: 公开的是通过首先在注入基于粘弹性的处理流体之前提供胶体颗粒的悬浮液并将处理流体注入井中来处理地下地层的方法。 胶体颗粒将液体流失减少到地层中。 根据第二实施方案，处理流体包括疏水改性的聚合物，所述疏水改性的聚合物以大约其重叠浓度c *与其约束的缠结浓度c e之间的浓度存在。 该方法特别适用于中高渗透性地层的压裂作业。
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公开(公告)号：US20050107503A1
公开(公告)日：2005-05-19
申请号：US10497376
申请日：2002-12-20
Applicant: Isabelle Couillet , Trevor Hughes
Inventor： Isabelle Couillet , Trevor Hughes
CPC classification number: C09K8/62 , C09K8/68 , C09K2208/30
Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a viscoelastic surfactant and a hydrophobically-modified polymer wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.
Abstract translation: 本发明涉及用于回收烃类的水性粘弹性压裂液。 根据本发明，流体包含粘弹性表面活性剂和疏水改性聚合物，其中疏水改性聚合物的浓度在其重叠浓度c *与其缠结浓度c e之间。
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20.发明申请Methods For Controlling The Fluid Loss Properties Of Viscoelastic Surfactants Based Fluids 有权用于控制基于粘弹性表面活性剂的流体的流体损失特性的方法公开(公告)号：US20050107265A1
公开(公告)日：2005-05-19
申请号：US10707011
申请日：2003-11-13
Applicant: Philip Sullivan , Yenny Christanti , Isabelle Couillet , Stephen Davies , Trevor Hughes , Alexander Wilson
Inventor： Philip Sullivan , Yenny Christanti , Isabelle Couillet , Stephen Davies , Trevor Hughes , Alexander Wilson
CPC classification number: C09K8/845 , C09K8/602 , C09K8/665 , C09K8/68 , C09K2208/10 , C09K2208/30 , E21B33/138
Abstract: It is proposed a method of treating a subterranean formation including providing a suspension of colloidal particles prior to the injection of a treating fluid based on an aqueous fluid comprising a thickening amount of a viscoelastic surfactant. The colloidal particles help to reduce fluid losses into the formation. According to a second embodiment, the treating fluid includes a hydrophobically-modified polymer, said hydrophobically-modified polymer being present at a concentration between approximately its overlap concentration c* and approximately its entanglement concentration ce. The method is particularly useful for fracturing operation in medium to high permeability formation.
Abstract translation: 提出了一种处理地下地层的方法，包括在基于包含增稠量的粘弹性表面活性剂的水性流体注入处理流体之前提供胶体颗粒的悬浮液。 胶体颗粒有助于减少进入地层的流体损失。 根据第二实施方案，处理流体包括疏水改性的聚合物，所述疏水改性的聚合物以大约其重叠浓度c *与其约束的缠结浓度c e之间的浓度存在。 该方法特别适用于中高渗透性地层的压裂作业。
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