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公开(公告)号：US4374967A
公开(公告)日：1983-02-22
申请号：US346804
申请日：1982-02-08
申请人： Paul L. Brown , Chi-Long Lee , Myron T. Maxson
发明人： Paul L. Brown , Chi-Long Lee , Myron T. Maxson
CPC分类号： C08L83/04 , C08G77/045 , C08G77/12 , C08G77/20
摘要： This invention relates to a novel low-temperature dielectric silicone gel which is the reaction product of a polyorganosiloxane consisting essentially of Me.sub.2 SiO, MeSiO.sub.1.5, Me.sub.3 SiO.sub.0.5 and Me.sub.2 ViSiO.sub.0.5 ; an organohydrogensiloxane and a platinum catalyst.
摘要翻译： 本发明涉及一种新型的低温电介质硅凝胶，它是基本上由Me2SiO，MeSiO1.5，Me3SiO0.5和Me2ViSiO0.5组成的聚有机硅氧烷的反应产物; 有机氢硅氧烷和铂催化剂。
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公开(公告)号：US3933882A
公开(公告)日：1976-01-20
申请号：US528960
申请日：1974-12-02
申请人： Chi-Long Lee , Myron T. Maxson
发明人： Chi-Long Lee , Myron T. Maxson
CPC分类号： C08G77/38 , C07F7/0879 , C08G77/045 , C08G77/398 , Y02P20/582
摘要： A vaporized mixture of a platinum catalyst in the amount of 0.01 to 2 p.p.m. platinum, an acetylenic alcohol and a siloxane compound having at least three silicon-bonded hydrogen atoms per molecule is passed through a tube such as a stainless steel tube heated at 210.degree.C. to 450.degree.C. to produce an olefinic siloxane compound which is, below 100.degree.C., an inhibitor for the reaction between the acetylenic alcohol and the siloxane compound having at least three silicon-bonded hydrogen atoms in the presence of platinum.
摘要翻译： 铂催化剂的蒸发混合物的量为0.01至2p.p.m。 铂，炔属醇和每分子具有至少三个与硅键合的氢原子的硅氧烷化合物通过诸如加热至210℃至450℃的不锈钢管的管以产生烯属硅氧烷化合物，其为 在100℃以下，在铂存在下，具有至少三个与硅键合的氢原子的炔属醇与硅氧烷化合物之间的反应的抑制剂。
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13.发明授权High consistency organosiloxane compositions comprising fluorinated and non-fluorinated polyorganosiloxanes 失效包含氟化和非氟化聚有机硅氧烷的高稠度有机硅氧烷组合物
公开(公告)号：US5302632A
公开(公告)日：1994-04-12
申请号：US688766
申请日：1991-04-22
申请人： Myron T. Maxson
发明人： Myron T. Maxson
摘要： The compatibility between high consistency fluorinated and non-fluorinated polydiorganosiloxanes is increased, with a resultant increase in the physical-properties of elastomers prepared from mixtures of these polymers, by blending the polymers together with a reinforcing silica filler that is reacted with both fluorinated and non-fluorinated liquid polydiorganosiloxanes as filler treating agents. The high consistency polydiorganosiloxanes contain at least two alkenyl radicals per molecule and are cured by a hydrosilation reaction.
摘要翻译： 高稠度氟化和非氟化聚二有机硅氧烷之间的相容性增加，由这些聚合物的混合物制备的弹性体的物理性质增加，通过将聚合物与与氟化和非氟化聚合物反应的增强二氧化硅填料共混， 氟化液体聚二有机硅氧烷作为填料处理剂。 高稠度聚二有机硅氧烷每分子含有至少两个烯基，并通过硅氢化反应固化。
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14.发明授权High consistency organosiloxane elastomer compositions curable by a platinum-catalyzed hydrosilation reaction 失效通过铂催化硅氢化反应可固化的高稠度有机硅氧烷弹性体组合物
公开(公告)号：US4857564A
公开(公告)日：1989-08-15
申请号：US250583
申请日：1988-09-29
申请人： Myron T. Maxson
发明人： Myron T. Maxson
摘要： The presence of an incompatible liquid, polydiorganosiloxane wherein from 1 to 30 percent of the siloxane units contain an ethylenically unsaturated hydrocarbon radical in high-consistency organosiloxane compositions that cure by a platinum-catalyzed hydrosilation reaction substantially improves the tear strength and elongation of cured elastomers prepared from these compositions.
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15.发明授权Method for preparing vinyl terminated fluorine-containing polydiorganosiloxane 失效制备乙烯基封端的含氟聚二有机硅氧烷的方法
公开(公告)号：US4683277A
公开(公告)日：1987-07-28
申请号：US881304
申请日：1986-07-02
申请人： Myron T. Maxson
发明人： Myron T. Maxson
摘要： Liquid diorganovinylsiloxy terminated polydiorganosiloxanes wherein at least 50 percent of the hydrocarbon radicals bonded to silicon contain at least one perfluorinated carbon atom are prepared by polymerizing the corresponding diorganocyclosiloxane(s) at a temperature of from 25.degree. to 150.degree. C. under superatmospheric pressure and in the presence of a controlled amount of water and a catalytically effective amount of ammonia. The resultant silanol terminated polydiorganosiloxane is reacted with a hexaorganodisilazane containing a vinyl radical bonded to each of the two silicon atoms.
摘要翻译： 其中至少50％与硅键合的烃基含有至少一个全氟化碳原子的液体二有机乙烯基硅氧烷封端的聚二有机硅氧烷是通过在超大气压下在25℃至150℃的温度下聚合相应的二有机环硅氧烷而制备的， 存在受控量的水和催化有效量的氨。 所得硅烷醇封端的聚二有机硅氧烷与含有键合到两个硅原子中的每一个的乙烯基的六有机二硅氮烷反应。
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公开(公告)号：US4732931A
公开(公告)日：1988-03-22
申请号：US917329
申请日：1986-10-09
申请人： Myron T. Maxson
发明人： Myron T. Maxson
摘要： The curable compositions of this invention comprise a solubilized vinyl-containing fluorosilicone gum, a curing agent for the gum, a platinum-containing hydrosilation catalyst, a treated reinforcing silica filler, and a volatile solvent for the gum and curing agent. The organosilicon compound used to treat the silica filler is critical to obtaining a homogeneous curable composition free of agglomerated particles, and is a hydroxyl terminated polydiorganosiloxane containing silicon-bonded fluorocarbon radicals.
摘要翻译： 本发明的可固化组合物包含溶解的含乙烯基氟硅酮胶，用于胶的固化剂，含铂硅氢化催化剂，处理过的增强二氧化硅填料和用于胶和固化剂的挥发性溶剂。 用于处理二氧化硅填料的有机硅化合物对于获得不含聚集颗粒的均匀的可固化组合物是关键的，并且是含有硅键合的氟烃基团的羟基封端的聚二有机硅氧烷。
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公开(公告)号：US4719275A
公开(公告)日：1988-01-12
申请号：US881303
申请日：1986-07-02
摘要： Polyorganosiloxane gels exhibiting a resistance to discoloration and hardening at temperatures of 100.degree. C. and above can be prepared by the reaction of a polydiorganosiloxane containing silicon-bonded fluorinated hydrocarbon radicals with an organohydrogensiloxane containing at least three silicon-bonded hydrogen atoms per molecule in the presence of a platinium containing catalyst. The resistance to heat induced hardening and discoloration is achieved by preparing the polydiorganosiloxane by the ammonia catalyzed polymerization of at least one cyclic fluorine-containing diorganosiloxane followed by reaction of the resultant silanol terminated polymer with a hexaorganodisilazane containing a vinyl radical bonded to each of the two silicon atoms.The reactants preferably contain 3,3,3-trifluoropropyl radicals to achieve a resistance to softening and/or solubilization of the cured gel in the presence of hydrocarbon fuels.
摘要翻译： 在100℃以上的温度下表现出抗变色和硬化的聚有机硅氧烷凝胶可以通过含有硅键合的氟化烃基的聚二有机硅氧烷与每分子含有至少三个与硅键合的氢原子的有机氢硅氧烷 含铂催化剂的存在。 通过用至少一种环状含氟二有机硅氧烷的氨催化聚合制备聚二有机硅氧烷，然后将所得到的硅烷醇封端聚合物与含有与二者结合的乙烯基的六有机二硅氮烷反应来制备耐热引起的硬化和变色 硅原子。 反应物优选含有3,3,3-三氟丙基，以在烃燃料存在下实现固化凝胶的软化和/或溶解性。
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公开(公告)号：US4173560A
公开(公告)日：1979-11-06
申请号：US904048
申请日：1978-05-08
CPC分类号： C09C1/3081 , C08K9/06 , C01P2006/12 , C01P2006/14 , C01P2006/80 , C01P2006/90
摘要： Reinforcing silica treated with short chain linear amidosiloxane of the formula ##STR1## provides a useful reinforcing filler for silicone elastomers. Silicone elastomer bases manufactured using this treated silica can be cured by organic peroxides or the combination of organohydrogensiloxane and platinum catalyst. When the later curing system is used, the cured products exhibit considerable retention of physical properties upon exposure to elevated temperatures for a significant period of time.
摘要翻译： 用式“IMAGE”的短链线性酰胺硅氧烷处理的增强二氧化硅为有机硅弹性体提供了有用的增强填料。 使用该处理过的二氧化硅制造的硅酮弹性体基质可以通过有机过氧化物或有机氢硅氧烷和铂催化剂的组合来固化。 当使用后续的固化体系时，固化产物在高温下暴露相当长的一段时间后，其物理性质保持相当大的保留。
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19.发明授权Fluorinated polydiorganosiloxane base composition and method for preparation 失效氟化聚二有机硅氧烷基础组合物及其制备方法
公开(公告)号：US5569698A
公开(公告)日：1996-10-29
申请号：US557403
申请日：1995-11-13
申请人： Myron T. Maxson
发明人： Myron T. Maxson
摘要： A method for making a fluorinated polydiorganosiloxane base composition and the composition prepared thereby. The base composition can be addition cured using a platinum-metal group catalyst and an organohydrogensiloxane crosslinker to form a fluorosilicone elastomer having improved resiliency and compression set properties.
摘要翻译： 制备氟化聚二有机硅氧烷基础组合物的方法及其制备的组合物。 可以使用铂 - 金属基催化剂和有机氢硅氧烷交联剂将基础组合物加成固化，以形成具有改进的弹性和压缩永久变形特性的氟硅酮弹性体。
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公开(公告)号：US4785066A
公开(公告)日：1988-11-15
申请号：US144209
申请日：1988-01-15
申请人： Myron T. Maxson
发明人： Myron T. Maxson
摘要： Certain liquid polydiorganosiloxanes wherein each molecule contains at least one sequence of 2 or more vinyl radicals bonded to non-terminal silicon atoms extend the working time at 25.degree. C. of organosiloxane compositions that cure by a platinum catalyzed hydrosilation reaction without adversely affecting the cure rate of the composition at temperatures of about 100.degree. C. and above. The polydiorganosiloxane is prepared by the acid-catalyzed polymerization of the corresponding cyclic polydiorganosiloxanes in the presence of a chain-terminating organosilicon reactant.
摘要翻译： 某些液体聚二有机硅氧烷，其中每个分子含有至少一个与非末端硅原子键合的2个或更多个乙烯基的序列，延长了在25℃下通过铂催化硅氢化反应固化而不会影响固化速率的有机硅氧烷组合物的工作时间 的组合物在约100℃以上的温度下进行。 聚二有机硅氧烷通过相应的环状聚二有机硅氧烷在链终止的有机硅反应物的存在下的酸催化聚合制备。
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