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公开(公告)号：US4169864A
公开(公告)日：1979-10-02
申请号：US888906
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substitutents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
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12.发明授权Process for making codimers of norbornadiene and alkynes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和炔烃的共聚物的方法
公开(公告)号：US4110409A
公开(公告)日：1978-08-29
申请号：US842812
申请日：1977-10-17
CPC分类号： C07C13/68 , C07C2/42 , C07C5/03 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
摘要翻译： 降冰片二烯和炔烃在钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝的均相催化体系存在下进行催化同步化。 此外，公开了降冰片二烯和含有至少三个碳的炔烃的新型共聚物。 氢化后，得到的共混物可用作这种燃料的高能燃料或稀释剂。
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13.发明授权Hydrocarbon oxidations catalyzed by azide-activated metal coordination complexes 失效由叠氮化物活化的金属配位络合物催化的烃氧化反应
公开(公告)号：US5093491A
公开(公告)日：1992-03-03
申请号：US466163
申请日：1990-01-17
CPC分类号： C07C45/36 , B01J27/24 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , B01J2531/025 , B01J2531/62 , B01J2531/72 , C07C2101/14
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively on high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.
摘要翻译： 碳氢化合物，特别是较低分子量的烷烃和环烷烃可以容易地用空气或O 2氧化，以高产率选择性地形成醇，酮等产物，当用作催化剂时，高活性的叠氮化物活化的金属配位体 具有结构
的复合物，其中M是过渡金属; “”是配体; X为叠氮化物。 本发明还涉及某些新型叠氮化物活化金属配位络合物催化剂本身。 -
14.发明授权Hydrocarbon oxidations catalyzed by iron coordination complexes containing a halogenated ligand 失效由含有卤化配体的铁配位络合物催化的烃氧化反应
公开(公告)号：US4900871A
公开(公告)日：1990-02-13
申请号：US66666
申请日：1987-06-26
IPC分类号： C07B61/00 , B01J27/24 , B01J31/18 , B01J31/22 , C07C27/00 , C07C27/12 , C07C29/50 , C07C31/02 , C07C31/10 , C07C31/12 , C07C45/00 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C49/08 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C67/00
CPC分类号： B01J31/183 , B01J27/24 , B01J31/1805 , B01J31/1815 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , B01J2531/025 , B01J2531/62 , B01J2531/72 , B01J2531/842
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively high yields when there is employed as the catalyst a coordination complex containing an iron center and a halogenated ligand having the structure ##STR1## where Fe is iron; " .circle. " is a ligand; X is a halogen substituent of the ligand; and A is an anion.
摘要翻译： 当使用含有铁中心和配位络合物的配位络合物作为催化剂时，烃，特别是低分子量烷烃和环烷烃可容易地被空气或O 2氧化以形成诸如醇，酮等的产物。 卤化配体具有结构
，其中Fe是铁; “＆cir＆”是配体; X是配体的卤素取代基; 而A是阴离子。 -
公开(公告)号：US4803187A
公开(公告)日：1989-02-07
申请号：US76570
申请日：1987-07-20
IPC分类号： C01B21/097 , B01J23/28 , B01J23/34 , B01J23/88 , B01J27/187 , B01J27/188 , B01J27/198 , B01J27/199 , B01J27/24 , B01J37/00 , C01B25/00 , C07B61/00 , C07C27/00 , C07C27/12 , C07C29/50 , C07C31/02 , C07C31/10 , C07C31/12 , C07C45/00 , C07C45/33 , C07C49/04 , C07C49/08 , C07C67/00 , B01J27/14
CPC分类号： B01J27/199 , B01J23/002 , B01J27/188 , C01G39/006 , C01G41/006 , C01G49/009 , C07C29/50 , C07C45/33 , B01J2523/00
摘要： Heteropolyacids or polyoxoanions promoted with azide, such as K.sub.6 PW.sub.11 VO.sub.40 N.sub.3, useful in the liquid phase oxidation of alkanes.
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公开(公告)号：US4190611A
公开(公告)日：1980-02-26
申请号：US933230
申请日：1978-08-14
CPC分类号： C07C2/42 , C07C2103/90 , C07C2531/14 , C07C2531/22 , C07C2531/24 , Y10S149/12
摘要： Norbornadiene and nobornene are catalytically codimerized to the saturated exo-exo hexacyclic dimer of norbornadiene. Used is a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Resulting dimer can be used as a component of high energy fuel.
摘要翻译： 降冰片二烯的饱和外 - 外六环二聚体被催化同分异构。 使用由钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝组成的三组分均相催化体系。 所得二聚体可用作高能燃料的组分。
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公开(公告)号：US4190610A
公开(公告)日：1980-02-26
申请号：US933228
申请日：1978-08-14
CPC分类号： D21H17/23 , C07C2/42 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24 , Y10S149/12
摘要： Catalytic codimerization of norbornadiene and 1,3-pentadiene yields an olefinic codimer which, after hydrogenation, has utility as a high energy missile fuel or a diluent for a higher viscous missile fuel. Used is a three-component homogeneous catalytic system, consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphina ethane and an alkyl aluminum chloride.
摘要翻译： 降冰片二烯和1,3-戊二烯的催化同分异构产生烯烃共聚体，其在氢化之后可用作高能导弹燃料或用于较高粘性导弹燃料的稀释剂。 使用的是三组分均相催化体系，由钴或钴乙酰丙酮化合物，1,2-双二苯基膦乙烷和烷基氯化铝组成。
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公开(公告)号：US4098835A
公开(公告)日：1978-07-04
申请号：US829301
申请日：1977-08-31
CPC分类号： C07C2/42 , C07C2103/64 , C07C2531/14 , C07C2531/22
摘要： Processes for preparing vinyl nortricyclane (I) and its hydrogenated derivative, ethyl nortricyclane (II) are disclosed. The nortricyclane (II) can be used as a high energy fuel or a fuel diluent. Process involves codimerization of norbornadiene and ethylene in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride to yield the vinyl nortricyclane (I). The latter can be hydrogenated to ethylnortricyclane.
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19.发明授权Hydrocarbon oxidations catalyzed by azide-activated metal coordination complexes 失效由叠氮化物活化的金属配位络合物催化的烃氧化反应
公开(公告)号：US4895682A
公开(公告)日：1990-01-23
申请号：US246
申请日：1987-01-02
CPC分类号： B01J31/1815 , B01J27/24 , B01J31/1805 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , B01J2531/025 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , C07C2101/14
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidixed with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively in high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.
摘要翻译： 碳氢化合物，特别是较低分子量的烷烃和环烷烃可以容易地与空气或O 2一起氧化，以高产率选择性地形成醇，酮等产物，当用作催化剂高活性叠氮化物活化金属配位体 具有结构
的复合物，其中M是过渡金属; “”是配体; X为叠氮化物。 本发明还涉及某些新型叠氮化物活化金属配位络合物催化剂本身。 -
20.发明授权Hydrocarbon oxidations catalyzed by nitride-activated metal coordination complexes 失效由氮化物活化的金属配位络合物催化的烃氧化
公开(公告)号：US4895680A
公开(公告)日：1990-01-23
申请号：US000247
申请日：1987-01-02
CPC分类号： B01J31/1815 , B01J27/24 , B01J31/1805 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C12C11/02 , B01J2531/025 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , C07C2101/14
摘要： Hydrocarbon, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like in high yields when there is employed as the catalyst a highly active nitride-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is a nitride. Certain dimeric forms of the above catalyst are also employed herein. It has also been discovered that Group IV through VIII transition metal nitrides are also highly effective oxidation catalysts for lower molecular weight hydrocarbons such as alkanes.
摘要翻译： 当使用高活性氮化物活化的金属配位络合物作为催化剂时，烃，特别是低分子量烷烃和环烷烃可以容易地用空气或O 2氧化形成醇，酮等产物， 具有结构
，其中M是过渡金属; “”是配体; X是氮化物。 上述催化剂的某些二聚体形式也用于本文。 还发现，IV族至VIII族过渡金属氮化物也是用于低分子量烃如烷烃的高效氧化催化剂。
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