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1.发明授权Process for making codimers of norbornadiene and phenylacetylenes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和苯乙炔的共聚物的方法
公开(公告)号：US4132742A
公开(公告)日：1979-01-02
申请号：US842813
申请日：1977-10-17
CPC分类号： C07C2/42 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substituents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
摘要翻译： 降冰片二烯和苯乙炔及其氢化衍生物（II）的新型共聚物（I）及其氢化衍生物（II），其具有以下结构：其中R是氢，苯基或具有烷基取代基的苯基，R 1是具有烷基取代基的苯基或苯基 并公开了制备两者的方法。 Codimer（II）可用作这种燃料的高能燃料或稀释剂。 制备编码（I）的方法包括使降冰片二烯和苯基乙炔或二苯基乙炔与钴或钴乙酰丙酮化合物的催化剂体系，1,2-双二苯基膦基乙烷和烷基氯化铝反应。
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公开(公告)号：US4100216A
公开(公告)日：1978-07-11
申请号：US819445
申请日：1977-07-27
CPC分类号： C07C2/42
摘要： Norbornadiene and isoprene are catalytically codimerized to an olefinic codimer. Used is a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. The codimer upon hydrogenation forms .beta.-methyltetramethylene nortricyclane having utility as a diluent for a high energy hydrocarbon missile fuel.
摘要翻译： 降冰片二烯和异戊二烯被催化同分异构化成烯属共聚体。 使用由钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝组成的三组分均相催化体系。 加氢时的同分子化形式可用作高能烃类导弹燃料的稀释剂的β-甲基四亚甲基核桃素。
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公开(公告)号：US4201731A
公开(公告)日：1980-05-06
申请号：US933229
申请日：1978-08-14
CPC分类号： C10L1/04 , B01J31/0267 , B01J31/143 , B01J31/2234 , B01J31/2404 , C07C13/68 , C07C2/42 , B01J2531/845 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24 , Y10S149/12
摘要： Norbornadiene and 1,3-pentadiene are catalytically codimerized to an olefinic codimer using a three-component homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, triphenylphosphine and an alkyl aluminum chloride. The codimer, after hydrogenation, has utility as a high energy missile fuel or a diluent for a higher viscous missile fuel.
摘要翻译： 降冰片二烯和1,3-戊二烯使用钴或钴乙酰丙酮化合物的三组分均相催化体系，三苯基膦和烷基氯化铝催化同分异构化成烯属共聚体。 氢化后的同系物可用作高能导弹燃料或用于较高粘度的导弹燃料的稀释剂。
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公开(公告)号：US4169864A
公开(公告)日：1979-10-02
申请号：US888906
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substitutents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
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5.发明授权Process for making codimers of norbornadiene and alkynes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和炔烃的共聚物的方法
公开(公告)号：US4110409A
公开(公告)日：1978-08-29
申请号：US842812
申请日：1977-10-17
CPC分类号： C07C13/68 , C07C2/42 , C07C5/03 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
摘要翻译： 降冰片二烯和炔烃在钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝的均相催化体系存在下进行催化同步化。 此外，公开了降冰片二烯和含有至少三个碳的炔烃的新型共聚物。 氢化后，得到的共混物可用作这种燃料的高能燃料或稀释剂。
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公开(公告)号：US4190611A
公开(公告)日：1980-02-26
申请号：US933230
申请日：1978-08-14
CPC分类号： C07C2/42 , C07C2103/90 , C07C2531/14 , C07C2531/22 , C07C2531/24 , Y10S149/12
摘要： Norbornadiene and nobornene are catalytically codimerized to the saturated exo-exo hexacyclic dimer of norbornadiene. Used is a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Resulting dimer can be used as a component of high energy fuel.
摘要翻译： 降冰片二烯的饱和外 - 外六环二聚体被催化同分异构。 使用由钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝组成的三组分均相催化体系。 所得二聚体可用作高能燃料的组分。
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公开(公告)号：US4190610A
公开(公告)日：1980-02-26
申请号：US933228
申请日：1978-08-14
CPC分类号： D21H17/23 , C07C2/42 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24 , Y10S149/12
摘要： Catalytic codimerization of norbornadiene and 1,3-pentadiene yields an olefinic codimer which, after hydrogenation, has utility as a high energy missile fuel or a diluent for a higher viscous missile fuel. Used is a three-component homogeneous catalytic system, consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphina ethane and an alkyl aluminum chloride.
摘要翻译： 降冰片二烯和1,3-戊二烯的催化同分异构产生烯烃共聚体，其在氢化之后可用作高能导弹燃料或用于较高粘性导弹燃料的稀释剂。 使用的是三组分均相催化体系，由钴或钴乙酰丙酮化合物，1,2-双二苯基膦乙烷和烷基氯化铝组成。
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公开(公告)号：US4098835A
公开(公告)日：1978-07-04
申请号：US829301
申请日：1977-08-31
CPC分类号： C07C2/42 , C07C2103/64 , C07C2531/14 , C07C2531/22
摘要： Processes for preparing vinyl nortricyclane (I) and its hydrogenated derivative, ethyl nortricyclane (II) are disclosed. The nortricyclane (II) can be used as a high energy fuel or a fuel diluent. Process involves codimerization of norbornadiene and ethylene in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride to yield the vinyl nortricyclane (I). The latter can be hydrogenated to ethylnortricyclane.
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公开(公告)号：US4169863A
公开(公告)日：1979-10-02
申请号：US888905
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl alluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
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公开(公告)号：US5817881A
公开(公告)日：1998-10-06
申请号：US902931
申请日：1997-07-30
IPC分类号： B01J23/881 , B01J27/188 , C07C29/50 , C07C45/33
CPC分类号： C07C29/50 , B01J23/881 , B01J27/188 , C07C45/33
摘要： Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z �(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-eThe M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.
摘要翻译： 烷烃在空气或氧气中使用下式的铁取代的聚氧阴离子（POA）催化氧化：He-z [（n-C4H9）4N] z（XM11M'O39）-e M'（例如铁（III）/ 铁（II））还原电位受中心原子X和骨架金属M的选择以及四丁基铵基团的数量的影响。 已经发现Fe（III）/ Fe（II）还原电位的降低与增加的氧化活性相关。
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