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    PROCESSES FOR PREPARING CARBON FIBERS USING GASEOUS SULFUR TRIOXIDE
    11.
    发明申请
    PROCESSES FOR PREPARING CARBON FIBERS USING GASEOUS SULFUR TRIOXIDE 有权
    使用三硫化钼制备碳纤维的方法

    公开(公告)号：US20150167201A1

    公开(公告)日：2015-06-18

    申请号：US14413457

    申请日：2013-07-03

    Applicant: Dow Global Technologies LLC

    Inventor： Bryan E. Barton ,  Zenon Lysenko ,  Mark T. Bernius ,  Eric J. Hukkanen

    IPC: D01F9/21

    CPC classification number: D01F9/21 ,  D01F9/14 ,  D01F9/20

    Abstract: Disclosed herein are processes for preparing carbonized polymers, such as carbon fibers, comprising: sulfonating a polymer with a sulfonating agent that comprises SO3 gas to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of said solvent is at least 95° C.; and carbonizing the resulting product by heating it to a temperature of 500-3000° C.

    Abstract translation: 本文公开了制备碳化聚合物如碳纤维的方法，其包括：用包含SO 3气体的磺化剂磺化聚合物以形成磺化聚合物; 用加热的溶剂处理磺化聚合物，其中所述溶剂的温度为至少95℃。 并将所得产物加热至500-3000℃的温度进行碳化。

    HYPERBRANCHED ETHYLENE-BASED OILS AND GREASES
    13.
    发明申请
    HYPERBRANCHED ETHYLENE-BASED OILS AND GREASES 有权
    超乙烯基乙烯和油脂

    公开(公告)号：US20160122259A1

    公开(公告)日：2016-05-05

    申请号：US14893732

    申请日：2014-06-24

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Daniel J. Arriola ,  Brad C. Bailey ,  Jerzy Klosin ,  Zenon Lysenko ,  Gordon R. Roof ,  Austin J. Smith

    IPC: C07C2/34 ,  C07C5/03 ,  C07C11/21

    CPC classification number: C07C2/34 ,  B01J31/00 ,  C07C2531/22 ,  C08F10/00 ,  C10M105/00 ,  C10M107/02 ,  C10M107/04 ,  C10M107/10 ,  C10M2203/02 ,  C10M2205/0225 ,  C10M2205/0285 ,  C10N2220/028 ,  C10N2250/10 ,  C10N2270/00 ,  C07C11/02 ,  C08F10/02 ,  C08F4/64193 ,  C08F110/02 ,  C08F2500/02

    Abstract: A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.

    Abstract translation: 制备相对便宜的实用流体的方法包括在连续供给的反混合反应器区域中将乙烯和配位插入催化剂和任选的α-烯烃在一起使得超支化低聚物和支链低聚物的混合物 形成了。 超支化低聚物每个低聚物分子平均具有至少1.5个次甲基碳，每千个总碳中至少有40个次甲基碳，至少40％的次甲基碳源自乙烯，平均碳数 每个分子为25至100，并且至少25％的超支化低聚物分子具有乙烯基并且可以与支化低聚物分离，其具有每分子平均碳数高达20个。配位插入催化剂 其特征在于具有高达20的乙烯/辛烯反应性比和至多20个单体单元的动力链长度。

    HYPERBRANCHED OLEFIN OIL-BASED DIELECTRIC FLUID
    14.
    发明申请
    HYPERBRANCHED OLEFIN OIL-BASED DIELECTRIC FLUID 有权
    超薄烯烃油基介质流体

    公开(公告)号：US20140330056A1

    公开(公告)日：2014-11-06

    申请号：US14362420

    申请日：2012-11-28

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Jerzy Klosin ,  Zenon Lysenko ,  Suh Joon Han

    IPC: H01B3/22

    CPC classification number: H01B3/22 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F4/64193 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F110/14

    Abstract: The present invention generally relates to a dielectric composition which is a poly-α-olefin or poly(co-ethylene-α-ol-efin) having a backbone weight average molecular weight less than 10,000 daltons. The dielectric composition uses a metal-ligand complex as a precatalyst and exhibits a hyperbranched structure that enables low viscosity, and therefore good flow characteristics, combined with high fire point due to ability to increase molecular weight via branching rather than backbone growth. Other desirable properties include lowered pour point due to crystallization disruption, and desirable thermal oxidative stability.

    Abstract translation: 本发明一般涉及具有骨架重均分子量小于10,000道尔顿的聚-α-烯烃或聚（共 - 乙烯-α-醇 - 烯烃）的电介质组合物。 电介质组合物使用金属 - 配体络合物作为预催化剂，并且表现出超支化结构，其能够通过分支而不是主链生长增加分子量的能力而实现低粘度，因此具有良好的流动特性以及高火点。 其它所需的性质包括由于结晶破坏引起的降低的倾点和所需的热氧化稳定性。

    SYNTHETIC ESTER-BASED DIELECTRIC FLUID COMPOSITIONS FOR ENHANCED THERMAL MANAGEMENT
    15.
    发明申请
    SYNTHETIC ESTER-BASED DIELECTRIC FLUID COMPOSITIONS FOR ENHANCED THERMAL MANAGEMENT 有权
    基于合成酯的介电流体组合物，用于增强热管理

    公开(公告)号：US20140252281A1

    公开(公告)日：2014-09-11

    申请号：US14348360

    申请日：2012-09-26

    Applicant: Dow Global Technologies LLC

    Inventor： Suh Joon Han ,  Dirk B. Zinkweg ,  Zenon Lysenko

    IPC: H01B3/24 ,  H01B3/20

    CPC classification number: H01B3/24 ,  H01B3/20

    Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized methyl-12-carboxy methyl stearate having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein methyl-12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form the hydroxy methyl ester, followed by reaction with a linear or branched C4-C20 carboxylic acid selected from free acid chlorides, fatty acids, carboxylic acid anhydrides, and combinations thereof. The second step serves to end-cap the hydroxyl groups, thereby producing the functionalized methyl-12-carboxy methyl stearate compound that exhibits improved thermoxidative stability and low temperature flowability, as well as increased fire point.

    Abstract translation: 用于电气设备的介电流体组合物包括官能化的甲基-12-羧甲基硬脂酸酯，其具有包括倾点小于-30℃和高于250℃的点的所需性质。其可以通过以下方法制备：其中甲基 -12-羟基甲基硬脂酸酯通过与C 3 -C 20醇反应来酯交换以形成羟甲基酯，然后与选自游离酰氯，脂肪酸，羧酸酐的直链或支链C 4 -C 20羧酸反应，和 其组合。 第二步用于封端羟基，从而产生表现出改善的热氧稳定性和低温流动性以及增加的火点的官能化甲基-12-羧甲基硬脂酸酯化合物。

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