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58 条记录 (耗时 0.027 秒)

    Polyethersulfone compositions
    12.
    发明授权
    Polyethersulfone compositions 失效
    聚醚砜组合物

    公开(公告)号：US07393914B2

    公开(公告)日：2008-07-01

    申请号：US11193552

    申请日：2005-07-29

    申请人： David Roger Moore ,  Hongyi Zhou ,  Daniel Steiger ,  Joyce Hung ,  Daniel Joseph Brunelle ,  Hongwei Liu ,  Marianne Elisabeth Harmon

    发明人： David Roger Moore ,  Hongyi Zhou ,  Daniel Steiger ,  Joyce Hung ,  Daniel Joseph Brunelle ,  Hongwei Liu ,  Marianne Elisabeth Harmon

    IPC分类号： C08G75/00 ,  C08G8/02

    CPC分类号： G11B7/22 ,  G11B7/1356 ,  G11B7/1362 ,  G11B2007/0006

    摘要： Novel polyethersulfone compositions have been discovered which incorporate structural subunits derived from sulfonated bis(halophenyl)sulfones, dihydroxy terphenyls, and/or bis(hydroxyphenyl)pyridines. The sulfonated polyethersulfones show promise as materials for use in polymer electrolyte membranes (PEMs) in fuel cells owing to their high proton conductivities (0.02-0.07 S/cm at 20° C. and 100 percent humidity). In addition, a novel unsulfonated thermoplastic polyethersulfone comprising structural subunits derived from a non-sulfonated bis(halophenyl)sulfone bis4-fluorophenyl)sulfone and 4,4′-dihydroxyphenyl-2,6-pyridine (CAS No. 171820-16-9) is disclosed.

    摘要翻译： 已经发现新的聚醚砜组合物掺入衍生自磺化双（卤代苯基）砜，二羟基三联苯和/或双（羟基苯基）吡啶的结构亚单位。 磺化聚醚砜由于其高质子电导率（在20℃和100％湿度下为0.02-0.07S / cm），在燃料电池中用作聚合物电解质膜（PEM）的材料显示出希望。 另外，包含衍生自非磺化双（卤代苯基）砜双-4-氟苯基）砜和4,4'-二羟基苯基-2,6-吡啶（CAS号171820-16-9）的结构亚单位的新型未磺化热塑性聚醚砜， 被披露。

    Polyarylether membranes
    14.
    发明授权
    Polyarylether membranes 有权
    聚芳醚膜

    公开(公告)号：US07964697B2

    公开(公告)日：2011-06-21

    申请号：US12191252

    申请日：2008-08-13

    申请人： Gary William Yeager ,  Daniel Steiger ,  Yanshi Zhang

    发明人： Gary William Yeager ,  Daniel Steiger ,  Yanshi Zhang

    IPC分类号： C08G6/00

    CPC分类号： B01D71/68 ,  B01D71/52

    摘要： A membrane including a polyarylether having amide functionality. The polyarylether having amide functionality includes units from at least one of structure I or structure II: R1 and R2 are separate groups or are covalently connected to form a cyclic moiety; R1 and R2 are each, independently, hydrogen, C1-20 alkyl, C3-C30 aryl or a substituted C3-30 aryl; R3, R4, R5, R6, R7 and R8 are each, independently, a nitro group, C1-C12 alkyl, C3-C30 aryl or a combination; Y is hydrogen, C1-20 alkyl or C3-C30 aryl; k is from about 0 to about 10; a, b, c, d, e and f are each, independently, 0, 1, 2, 3 or 4; and m and n are each, independently, 0 or 1.

    摘要翻译： 包括具有酰胺官能团的聚芳醚的膜。 具有酰胺官能团的聚芳醚包括来自结构I或结构II中的至少一个的单元：R 1和R 2是分开的基团或共价连接以形成环状部分; R 1和R 2各自独立地为氢，C 1-20烷基，C 3 -C 30芳基或取代的C 3-30芳基; R 3，R 4，R 5，R 6，R 7和R 8各自独立地为硝基，C 1 -C 12烷基，C 3 -C 30芳基或其组合; Y是氢，C 1-20烷基或C 3 -C 30芳基; k为约0至约10; a，b，c，d，e和f各自独立地为0,1,2,3或4; m和n各自独立地为0或1。

    FUNCTIONAL POLYARYLETHERS
    18.
    发明申请
    FUNCTIONAL POLYARYLETHERS 失效

    公开(公告)号：US20080142429A1

    公开(公告)日：2008-06-19

    申请号：US11611644

    申请日：2006-12-15

    申请人： Yanshi Zhang ,  Daniel Steiger ,  Joseph Anthony Suriano ,  Gary William Yeager

    发明人： Yanshi Zhang ,  Daniel Steiger ,  Joseph Anthony Suriano ,  Gary William Yeager

    IPC分类号： B01D63/00 ,  C07D251/00

    CPC分类号： B01D71/52 ,  B01D69/08 ,  B01D2325/34 ,  C08G65/40 ,  C08G65/48 ,  C08G75/23

    摘要： Membranes comprising functional polyarylether having structural units of formula II are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4COR5, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence H, X, halo, cyano, nitro, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Q is a direct bond, O, S, CH2, alkenyl, alkynyl, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; Z is a direct bond, O, S, CH2, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.

    Polyethersulfone composition, method of making and articles therefrom
    20.
    发明申请
    Polyethersulfone composition, method of making and articles therefrom 有权
    聚醚砜组合物，制造方法和制品

    公开(公告)号：US20060167216A1

    公开(公告)日：2006-07-27

    申请号：US11388710

    申请日：2006-03-24

    申请人： Donald Johnson ,  Daniel Steiger ,  Daniel Brunelle ,  Sean Armstrong

    发明人： Donald Johnson ,  Daniel Steiger ,  Daniel Brunelle ,  Sean Armstrong

    IPC分类号： C08G75/00

    CPC分类号： C08G65/40 ,  C08G75/23 ,  C08L71/10 ,  C08L81/06

    摘要： A polyethersulfone composition is disclosed which comprises structural units derived from bisphenol-A and 4,4′-biphenol, the structural units derived from 4,4′-biphenol being present in an amount corresponding to greater than 65 mole percent based on total moles of structural units derived from diphenolic monomers, wherein the polyethersulfone has a weight average molecular weight (Mw) of at least 54,000 grams per mole as measured by gel permeation chromatography. The polyethersulfone compositions of the invention display outstanding impact strength as measured using ASTM D256. Surprisingly, the polyethersulfone compositions of the invention show enhanced impact strength relative to known polyethersulfones such as RADEL R, a commercially available polyethersulfone engineering thermoplastic comprised of structural units derived from a dihalodiarylsulfone and 4,4′-biphenol and having a Notched Izod impact strength of about 700 Joules per meter.

    摘要翻译： 公开了一种聚醚砜组合物，其包含衍生自双酚A和4,4'-联苯酚的结构单元，衍生自4,4'-联苯酚的结构单元的存在量相当于基于总共摩尔数 衍生自二元酚单体的结构单元，其中聚醚砜的重均分子量（M max）为每摩尔至少54,000克，通过凝胶渗透色谱测定。 本发明的聚醚砜组合物显示出优异的冲击强度，使用ASTM D256测量。 令人惊奇的是，本发明的聚醚砜组合物相对于已知的聚醚砜如RADEL R显示出增强的冲击强度，RADEL R是由二卤代芳基砜和4,4'-联苯酚衍生的结构单元的市售聚醚砜工程热塑性塑料，其具有缺口伊佐德冲击强度 约700焦耳/米。