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公开(公告)号:US20080142418A1
公开(公告)日:2008-06-19
申请号:US11611642
申请日:2006-12-15
摘要: Membranes comprising functional polyarylether having structural units of formula I are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence CH2X, H, halo, cyano, nitro, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Z is a direct bond, O, S, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.
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公开(公告)号:US07669720B2
公开(公告)日:2010-03-02
申请号:US11611642
申请日:2006-12-15
摘要: Membranes comprising functional polyarylether having structural units of formula I are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence CH2X, H, halo, cyano, nitro, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Z is a direct bond, O, S, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.
摘要翻译: 包含具有式I结构单元的官能聚芳醚的膜可用于血液透析和血液滤过:其中X选自Br,NR4R5,OOCR6,OR7,NR4CONR5R6,NR4COOR5R6及其组合; R 1,R 2和R 3各自独立地为CH 2,H,卤素,氰基,硝基,C 1 -C 12脂族基,C 3 -C 12环脂族基,C 3 -C 12芳族基或其组合; R 4和R 5独立地为H,C 1-10脂族基团,C 3 -C 12环脂族基团,C 3 -C 12芳族基团或其组合; R 6是H,C 2-10脂族基团,C 3 -C 12脂环族基团,C 3 -C 12芳族基团或其组合; R7是OCH2CH2(OCH2CH2)nOH或OOCCH2(OCH2CH2)nCH3; Z是直接键,O,S,SO,SO 2,CO,苯基氧化膦,烯基,炔基,C 1 -C 12脂族基,C 3 -C 12环脂族基,C 3 -C 12芳族基或其组合; a,b和c独立地为1或2; m,n和p独立地为0或1。
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公开(公告)号:US20080203012A1
公开(公告)日:2008-08-28
申请号:US11677848
申请日:2007-02-22
CPC分类号: C08L65/02 , B01D61/025 , B01D61/145 , B01D61/243 , B01D67/0093 , B01D69/02 , B01D69/125 , B01D71/44 , B01D71/52 , B01D71/76 , B01D2323/02 , B01D2323/30 , B01D2323/38 , B01D2325/36 , C08G65/48 , C08G2261/312 , C08L65/00
摘要: A membrane is provided that is formed from a composition. The composition comprises a polyarylene ether polymer or copolymer comprising a zwitterion; or comprises a polyarylene polymer or copolymer comprising a zwitterion.
摘要翻译: 提供由组合物形成的膜。 该组合物包含聚亚芳基醚聚合物或包含两性离子的共聚物; 或包含聚亚芳基聚合物或包含两性离子的共聚物。
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公开(公告)号:US20080207822A1
公开(公告)日:2008-08-28
申请号:US11677851
申请日:2007-02-22
CPC分类号: C08G65/44 , B01D71/52 , C08G65/485 , C08L71/02 , C08L71/12 , C08L2205/05 , C08L2666/22
摘要: Provided is a composition including a polyarylene ether polymer or copolymer comprising a zwitterionic, group. The zwitterionic group can derive from a zwitterionic precursor such as 4-(2-hydroxyethyl)-1-piperazine ethane sulfonic acid and comprises at least one atom of sulfur, phosphorus, or nitrogen. Embodiments also relate to an article, made from the composition, such as a membrane.
摘要翻译: 提供了包含聚亚芳基醚聚合物或包含两性离子基团的共聚物的组合物。 两性离子基团可以衍生自两性离子前体如4-(2-羟乙基)-1-哌嗪乙烷磺酸,并且包含至少一个硫,磷或氮原子。 实施例还涉及由组合物制成的制品,例如膜。
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公开(公告)号:US20080142429A1
公开(公告)日:2008-06-19
申请号:US11611644
申请日:2006-12-15
IPC分类号: B01D63/00 , C07D251/00
摘要: Membranes comprising functional polyarylether having structural units of formula II are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4COR5, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence H, X, halo, cyano, nitro, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Q is a direct bond, O, S, CH2, alkenyl, alkynyl, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; Z is a direct bond, O, S, CH2, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.
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公开(公告)号:US07681741B2
公开(公告)日:2010-03-23
申请号:US11611644
申请日:2006-12-15
摘要: Membranes comprising functional polyarylether having structural units of formula II are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4COR5, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence H, X, halo, cyano, nitro, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-C10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Q is a direct bond, O, S, CH2, alkenyl, alkynyl, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; Z is a direct bond, O, S, CH2, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.
摘要翻译: 包含具有式II结构单元的官能聚芳醚的膜可用于血液透析和血液滤过:其中X选自Br,NR4R5,OOCR6,OR7,NR4COR5,NR4CONR5R6,NR4COOR5R6及其组合; R 1,R 2和R 3各自独立地为H,X,卤素,氰基,硝基,C 1 -C 12脂族基,C 3 -C 12脂环族基,C 3 -C 12芳族基或其组合; R 4和R 5独立地为H,C 1 -C 10脂族基,C 3 -C 12脂环族基,C 3 -C 12芳族基或其组合; R 6是H,C 2-10脂族基团,C 3 -C 12脂环族基团,C 3 -C 12芳族基团或其组合; R7是OCH2CH2(OCH2CH2)nOH或OOCCH2(OCH2CH2)nCH3; Q是直接键合,O,S,CH 2,烯基,炔基,C 1 -C 12脂族基,C 3 -C 12脂环族基,C 3 -C 12芳族基或其组合; Z是直接键,O,S,CH 2,SO,SO 2,CO,苯基氧化烯,烯基,炔基,C 1 -C 12脂族基,C 3 -C 12脂环族基,C 3 -C 12芳族基或其组合; a,b和c独立地为1或2; m,n和p独立地为0或1。
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公开(公告)号:US20080312349A1
公开(公告)日:2008-12-18
申请号:US11677861
申请日:2007-02-22
IPC分类号: C08J5/22
CPC分类号: C08J9/28 , B01D61/025 , B01D61/145 , B01D67/0009 , B01D67/0093 , B01D69/08 , B01D71/28 , B01D71/52 , B01D71/66 , B01D71/68 , B01D71/82 , B01D2323/30 , B01D2323/38 , B01D2325/18 , B01D2325/20 , C08G61/10 , C08G65/485 , C08G2261/143 , C08G2261/312 , C08G2261/516 , C08G2261/72 , C08G2261/722 , C08J7/12 , C08J2365/00 , C08J2371/12 , C08L65/00 , D01F6/66 , D01F6/76
摘要: A process is provided that includes attaching a zwitterion to a polymer or a copolymer, wherein the polymer or copolymer comprises a polyarylene ether or a polyarylene.
摘要翻译: 提供了一种方法,其包括将两性离子连接到聚合物或共聚物上,其中聚合物或共聚物包含聚亚芳基醚或聚亚芳基。
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公开(公告)号:US07959808B2
公开(公告)日:2011-06-14
申请号:US12262643
申请日:2008-10-31
申请人: Gary William Yeager , Liming Yu , Daniel Steiger , Yanshi Zhang
发明人: Gary William Yeager , Liming Yu , Daniel Steiger , Yanshi Zhang
CPC分类号: B01D71/68 , B01D2323/02 , B01D2325/36 , C08L39/08 , C08L81/06 , C08L2666/04
摘要: The present invention relates to methods and apparatuses for water filtration comprising contacting a water stream with a membrane comprising a polysulfone having structural units of Formula I wherein X is OH, NR1R2, or OR3; R1 and R2 are independently at each occurrence hydrogen, a C1-C5000 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical, a polypeptide, a combination thereof, or R1 and R2 taken together form a 5- or 6-membered aliphatic ring or a 5-membered aromatic ring; R3 is a C1-C20 aliphatic radical, C3-C12 cycloaliphatic radical, C3-C12 aromatic radical, or a combination thereof; B′ and C′ are independently at each occurrence a nitro group, C1-C20 aliphatic radical, C3-C12 cycloaliphatic radical, C3-C12 aromatic radical, or a combination thereof; and q and r are independently at each occurrence 0 to 4. The present invention also relates to a method and apparatus for gas separation, the method comprising contacting a gas stream with a membrane comprising a polysulfone having structural units of Formula I.
摘要翻译: 本发明涉及水过滤的方法和装置,包括使水流与包含具有式I结构单元的聚砜的膜接触,其中X是OH,NR1R2或OR3; R1和R2各自独立地为氢,C1-C5000脂族基团,C3-C12脂环族基团,C3-C12芳族基团,多肽,其组合,或者R 1和R 2一起形成5-或6 脂族环或5元芳环; R3是C1-C20脂族基团,C3-C12脂环族基团,C3-C12芳族基团或其组合; B'和C'在每次出现时独立地为硝基,C 1 -C 20脂族基,C 3 -C 12脂环族基,C 3 -C 12芳族基或其组合; 并且q和r在每次出现时独立地为0至4.本发明还涉及一种用于气体分离的方法和装置,所述方法包括使气流与包含具有式I结构单元的聚砜的膜接触。
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9.
公开(公告)号:US20100044314A1
公开(公告)日:2010-02-25
申请号:US12197374
申请日:2008-08-25
申请人: Yanshi Zhang , Gary William Yeager , Hongyi Zhou , Daniel Steiger
发明人: Yanshi Zhang , Gary William Yeager , Hongyi Zhou , Daniel Steiger
CPC分类号: B01D71/68 , B01D71/82 , B01D2323/30 , B01D2325/18 , C08G75/20 , C08G75/23 , Y10T428/249958
摘要: A method for making a polysulfone having zwitterionic functionality comprising reacting a piperazine amine functionalized polysulfone with sultone is described as are blends with other polymers. Membranes containing polysulfones having zwitterionic functionality are also provided. Membranes thus formed are used in hemodialysis, hemofiltration, and water purification.
摘要翻译: 描述了制备具有两性离子官能团的聚砜的方法,包括使哌嗪胺官能化聚砜与磺内酯反应,是与其它聚合物的混合物。 还提供了含有具有两性离子官能团的聚砜的膜。 如此形成的膜用于血液透析,血液滤过和水净化。
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公开(公告)号:US20100041837A1
公开(公告)日:2010-02-18
申请号:US12191211
申请日:2008-08-13
IPC分类号: C08G75/23
CPC分类号: C08G65/40 , C08G65/4031 , C08G65/4093 , C08G75/23
摘要: A method for making a polyarylether having amide functionality includes reacting a dihydroxyaromatic compound having amide functionality with a dihaloaromatic sulfone or dinitroaromatic sulfone in the presence of a base. Polyarylethers having amide functionality and blends are also provided.
摘要翻译: 制备具有酰胺官能团的聚芳醚的方法包括在碱的存在下使具有酰胺官能团的二羟基芳族化合物与二卤代芳族砜或二硝基芳香砜反应。 还提供了具有酰胺官能度和共混物的聚芳醚醚。
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