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公开(公告)号：US5232637A
公开(公告)日：1993-08-03
申请号：US822863
申请日：1992-01-21
申请人： David Dasher , E. Robert Fretz, Jr. , Mark S. Friske , Reba S. Herndon , Ronald E. Johnson , David J. Kerko , John W. Nelson , Frederick E. Noll , Anthony R. Olszewski , Nikki J. Russo
发明人： David Dasher , E. Robert Fretz, Jr. , Mark S. Friske , Reba S. Herndon , Ronald E. Johnson , David J. Kerko , John W. Nelson , Frederick E. Noll , Anthony R. Olszewski , Nikki J. Russo
IPC分类号： B29C33/00 , B29C37/00 , B29C39/10 , B29C70/78 , B29D11/00 , B29K105/32 , B29L11/00 , G02B1/04 , G02C7/02
CPC分类号： B29D11/00528 , B29C33/0038 , B29C37/0078 , B29C39/10 , B29C70/78 , B29D11/00009 , B29D11/00413 , B29D11/0073 , B29K2105/0002 , B29K2709/08 , B29K2995/0034 , B29L2011/0041 , Y10S425/808 , Y10T156/1028
摘要： A method of producing a glass-plastic, laminated, ophthalmic lens structure in a continuous operation. A thin, flexible, plastic adhesive layer is applied to a glass element to form a composite body that is inserted in a cylindrical gasket in such manner as to fit snugly and be sealed from the ambient. A monomeric formulation is flowed onto the adhesive layer and cured to form a laminated lens blank.
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公开(公告)号：US4168339A
公开(公告)日：1979-09-18
申请号：US927956
申请日：1978-07-26
IPC分类号： G02C7/10 , B29D11/00 , B32B17/10 , C03C3/11 , C03C3/118 , C03C4/06 , G02B1/00 , G02B1/04 , G02B5/23 , G02F1/17 , B32B7/02 , B32B27/36 , G02B3/00
CPC分类号： B32B17/10486 , B29D11/00634 , C03C3/108 , C03C4/06 , G02B1/04 , G02B1/041 , Y10S428/913 , Y10T428/31507 , Y10T428/31616
摘要： This invention is directed to the production of photochromic glass microsheet which is particularly useful in the fabrication of transparent glass-plastic composite lenses. In such lenses, the photochromic microsheet will either be buried within the plastic or will act as a surface layer thereon. The microsheet consists essentially, in weight percent on the oxide basis as calculated from the batch, of 54-66% SiO.sub.2, 7-15% Al.sub.2 O.sub.3, 10-30% B.sub.2 O.sub.3, 3-15% Na.sub.2 O, 0.4-1.5% PbO, 0.2-0.5% Br, 0.5-1.2% Cl, 0.2-0.5% F, 0.008-0.03% CuO, and >0.03%-1% Ag.
摘要翻译： 本发明涉及制造透明玻璃 - 塑料复合透镜特别有用的光致变色玻璃微片。 在这种透镜中，光致变色微片将被埋在塑料内，或者作为其上的表面层。 该微片基本上以按批次计算的以氧化物为基准的重量百分比为54-66％SiO 2，7-15％Al 2 O 3，10-30％B 2 O 3，3-15％Na 2 O，0.4-1.5％PbO，0.2 -0.5％Br，0.5-1.2％Cl，0.2-0.5％F，0.008-0.03％CuO和> 0.03％-1％Ag。
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公开(公告)号：US4018965A
公开(公告)日：1977-04-19
申请号：US567925
申请日：1975-04-14
CPC分类号： C03C4/06 , C03B17/064 , C03C21/00 , C03C3/091 , Y10S428/913 , Y10S501/90 , Y10T428/315
摘要： Chemically-strengthenable silver halide-containing lithium boroaluminosilicate glass compositions having physical and chemical characteristics required for sheet drawing processes and exhibiting excellent photochromic properties after heat treatment, and also strengthened photochromic drawn sheet glass articles provided therefrom, are described.
摘要翻译： 描述了具有拉伸工艺所需的物理和化学特性并且在热处理后表现出优异的光致变色特性的化学强化的含卤化硼的锂硼硅酸盐玻璃组合物，以及由其提供的增强的光致变色拉伸玻璃制品。
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公开(公告)号：US3957499A
公开(公告)日：1976-05-18
申请号：US522494
申请日：1974-11-11
CPC分类号： C03C4/06 , Y10S501/90
摘要： Photochromic glasses having index of refraction values (n.sub.D) in the range from 1.52-1.54, compositions comprising, in weight percent, about 49-60% SiO.sub.2, 2-9% Al.sub.2 O.sub.3, 15-18% B.sub.2 O.sub.3, 6-12% Na.sub.2 O, 9-18% ZrO.sub.2, 0.5-0.9% Ag, 0.5-0.8% Cl, 0.010-0.030% CuO, 0.5-1% PbO, and 1-2% F, and rapid fading characteristics such that at least about 65% of the optical density gained during darkening is lost within a five-minute fading interval, are disclosed.
摘要翻译： 折射率值（nD）在1.52-1.54范围内的光致变色玻璃，组合物包含重量百分比为约49-60％SiO 2，2-9％Al 2 O 3，15-18％B 2 O 3，6-12％Na 2 O， 9-18％ZrO 2，0.5-0.9％Ag，0.5-0.8％Cl，0.010-0.030％CuO，0.5-1％PbO和1-2％F，以及快速褪色特性，使得至少约65％ 公开了在5分钟的衰落间隔期间在变暗期间获得的光密度损失。
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公开(公告)号：US06363748B1
公开(公告)日：2002-04-02
申请号：US09714083
申请日：2000-11-16
IPC分类号： C03C1900
CPC分类号： G02C7/102
摘要： An ophthalmic, protective, filter lens, and a method of producing such lens, the lens having a ratio of Z and Y tristimulus values between 0.25-0.40, a dominant wavelength between 570-580 nm. on a color mixture diagram, a sharp transmission drop between 450-500 nm. and a transmission not over 30% between 400-450 nm. The lens is produced by firing a silver halide-containing, photochromic glass lens in a hydrogen-containing atmosphere within a temperature range of 465° C. to 495° C. for less than 20 minutes.
摘要翻译： 一种眼科，保护性的滤光镜，以及这种透镜的制造方法，该透镜的Z和Y三刺激值之比在0.25-0.40之间，主波长在570-580nm之间。 在彩色混合图上，在450-500nm之间的急剧变化下降。 在400-450nm之间的透射率不超过30％。 通过在含氢气氛中在465℃至495℃的温度范围内烧制含卤化银的光致变色玻璃透镜不到20分钟来制造透镜。
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公开(公告)号：US06197711B1
公开(公告)日：2001-03-06
申请号：US09299445
申请日：1999-04-26
IPC分类号： C03C406
CPC分类号： G02C7/102
摘要： An ophthalmic, protective, filter lens, and a method of producing such lens, the lens having a ratio of Z and Y tristimulus values between 0.25-0.40, a dominant wavelength between 570-580 nm. on a color mixture diagram, a sharp transmission drop between 450-500 nm. and a transmission not over 30% between 400-450 nm.
摘要翻译： 一种眼科，保护性的滤光镜，以及这种透镜的制造方法，该透镜的Z和Y三刺激值之比在0.25-0.40之间，主波长在570-580nm之间。 在彩色混合图上，在450-500nm之间的急剧变化下降。 在400-450nm之间的透射率不超过30％。
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公开(公告)号：US6165922A
公开(公告)日：2000-12-26
申请号：US391744
申请日：1999-09-08
摘要： A fixed tint, photochromic glasses and sunglass lenses produced therefrom. The glasses have R.sub.2 O--Al.sub.2 O.sub.3 --B.sub.2 O.sub.3 --SiO.sub.2 base compositions, contain silver chloride and bromide contents as photochromic constituents and 0.22-0.38% NiO and 0.034-0.060% CoO, both by weight percent, as glass colorants, the NiO:CoO ratio being in the range of 5.5-7.2:1.
摘要翻译： 由其制成的固定色调，光致变色眼镜和太阳镜。 该玻璃具有R2O-Al2O3-B2O3-SiO2基础组合物，其中含有氯化银和溴化物含量作为光致变色组分，并且以重量百分数为0.22-0.38％NiO和0.034-0.060％CoO作为玻璃着色剂，NiO:CoO比为 在5.5-7.2：1的范围内。
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公开(公告)号：US5729381A
公开(公告)日：1998-03-17
申请号：US555652
申请日：1995-11-13
申请人： Thomas G. Havens , David J. Kerko , JoAnn Morrell
发明人： Thomas G. Havens , David J. Kerko , JoAnn Morrell
CPC分类号： C03C23/00 , C03C14/006 , C03C3/11 , C03C3/118 , C03C4/085 , C03C2214/08 , C03C2214/16 , Y10T428/24942
摘要： This invention is directed to the production of cuprous halide- or a cuprous-cadmium halide-containing glass articles which are essentially completely opaque to ultraviolet radiation and can be essentially completely opaque to radiation within the region of wavelengths of up to 550 nm, but are transparent to visible radiations having a wavelength longer than the radiation within the region of opacity. The method involves exposing the glass articles to a hydrogen gas-containing atmosphere at a temperature between about 375.degree.-500.degree. C. for a period of at least 18 hours to develop an integral reduced layer in at least one surface of the article having a depth effective to prevent the transmission of ultraviolet radiation and radiation having a wavelength up to 550 nm through the article.
摘要翻译： 本发明涉及生产用于紫外线辐射基本上完全不透明的卤化亚铜或含卤化镉卤化物的玻璃制品，并且可以对波长高达550nm的区域内的辐射基本上完全不透明，但是 对于具有比不透明度区域内的辐射更长的波长的可见光辐射是透明的。 该方法包括在约375-500℃的温度下将玻璃制品暴露于含氢气的气氛中至少18小时的时间，以在制品的至少一个表面上形成整体的还原层，其具有 深度有效地防止紫外线辐射和波长高达550nm的辐射穿过物品。
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公开(公告)号：US4979976A
公开(公告)日：1990-12-25
申请号：US509350
申请日：1990-04-16
申请人： Thomas G. Havens , David J. Kerko
发明人： Thomas G. Havens , David J. Kerko
CPC分类号： C03C4/06
摘要： This invention is directed to a method for making tinted photochromic glass articles having an integral reduced surface layer exhibiting color, the glass utilizing silver halide crystals as the photochromic agent. The method generally comprises heat treating the glass article in a heating chamber in an atmosphere of flowing hydrogen at temperatures below 500.degree. C. The specific steps of the inventive method comprise:(a) initially flowing hydrogen gas into said heat treating chamber at a sufficiently rapid rate to essentially instantaneously fill said chamber with the gas;(b) immediately thereafter decreasing the flow of said the hydrogen gas to permit careful control of the rate at which reduction takes place in the glass surface; and(c) continuing that gas flow for a sufficient length of time to produce an integral reduced surface layer on both front and back surfaces of the article having a combined depth effective to exhibit a color, but not of such individual depth as to prevent the passage of ultraviolet radiation through the front surface of the article.
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公开(公告)号：US4786305A
公开(公告)日：1988-11-22
申请号：US80903
申请日：1987-08-03
申请人： Edith M. Ball , Patricia A. Drake , David J. Kerko
发明人： Edith M. Ball , Patricia A. Drake , David J. Kerko
CPC分类号： C03C4/06 , C03B32/00 , C03B35/202
摘要： This invention is directed to a method for heat treating a sheet of a potentially photochromic glass to cause the growth of silver halide crystals therein which impart photochromic properties thereto, wherein the heat treated sheet will be essentially free from thermal deformation and surface defects, and the photochromic properties exhibited therein will be essentially uniform across the area of the sheet. The method involves first placing a sheet of potentially photochromic glass on top of a sheet of carrier glass that exhibits a softening point at least 50.degree. C. higher than the temperature at which the potentially photochromic glass will be heat treated, and thereafter subjecting the stacked sheets to the heat treatment temperature desired for growing silver halide crystals in the glass.
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