公开(公告)号：US20150253661A1

公开(公告)日：2015-09-10

申请号：US14197293

申请日：2014-03-05

Applicant: Deepak Shukla ,  Mark R. Mis

Inventor： Deepak Shukla ,  Mark R. Mis

IPC: G03F7/038 ,  G03F7/16

CPC classification number: G03F7/038 ,  G03F7/0045 ,  G03F7/0047 ,  G03F7/028 ,  G03F7/16

Abstract: A photopolymerizable composition has five essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and (d) metal particles. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing systems once various photocured patterns are formed from the photopolymerizable compositions.

Abstract translation: 可光聚合组合物具有五个基本组分：（a）可光聚合的环氧材料，（b）光酸产生剂如鎓盐，（c）电子给体光敏剂，其氧化电位至少为0.4V且至多并包括3V 与SCE，（d）金属颗粒。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上，以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦可光聚合组合物形成各种光固化图案，就可以在卷对卷印刷系统中进行的化学镀方法。

公开(公告)号：US20150011699A1

公开(公告)日：2015-01-08

申请号：US14494712

申请日：2014-09-24

Applicant: Deepak Shukla ,  Dianne Marie Meyer ,  Mark R. Mis ,  Matthew Dirmyer

Inventor： Deepak Shukla ,  Dianne Marie Meyer ,  Mark R. Mis ,  Matthew Dirmyer

IPC: H01B3/44 ,  C08F22/10

CPC classification number: H01B3/447 ,  C08F8/42 ,  C08F220/14 ,  C08F230/04 ,  C08K5/0091 ,  C08K5/56 ,  C08L33/04 ,  C08L67/02 ,  C08F220/24 ,  C08F220/20

Abstract: Organic polymeric bi-metallic alkoxide or aryloxide composites are used as dielectric materials in various devices with improved properties such as improved mobility. These composites comprise a poly(meth)acrylate or polyester having metal coordination sites, and the same or different bi-metallic alkoxide or aryloxide molecules that are coordinated with the organic polymer. The bi-metallic alkoxide or aryloxide molecules can be represented by Structure (I) shown herein. Such composites are generally soluble at room temperature in various organic solvents and be provided in homogeneous organic solvent solutions that can be suitably applied to a substrate to form dielectric materials.

Abstract translation: 有机聚合双金属醇盐或芳氧化物复合材料被用作具有改进的性能如改进的流动性的各种装置中的介电材料。 这些复合材料包含具有金属配位点的聚（甲基）丙烯酸酯或聚酯，以及与有机聚合物配位的相同或不同的双金属醇盐或芳氧化物分子。 双金属醇盐或芳氧化物分子可以由本文所示的结构（I）表示。 这种复合材料通常在室温下在各种有机溶剂中是可溶的，并且可以在均匀的有机溶剂溶液中提供，其可以适当地施加到基底上以形成电介质材料。

公开(公告)号：US20140287365A1

公开(公告)日：2014-09-25

申请号：US14158884

申请日：2014-01-20

Applicant: Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

Inventor： Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

IPC: G03F7/30

CPC classification number: G03F7/30 ,  G03F7/0045 ,  G03F7/038 ,  G03F7/405

Abstract: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles and used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material.

Abstract translation: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分，作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以应用于各种制品，并且用于在光热反应之后形成预定的聚合物图案以形成交联的二硫键，除去未交联的聚合物和与二硫化物反应性材料的反应。

公开(公告)号：US20140128551A1

公开(公告)日：2014-05-08

申请号：US13671854

申请日：2012-11-08

Applicant: Deepak Shukla ,  Dianne M. Meyer ,  Mark R. Mis ,  Matthew Dirmyer

Inventor： Deepak Shukla ,  Dianne M. Meyer ,  Mark R. Mis ,  Matthew Dirmyer

IPC: C08F226/06 ,  C08F22/10

CPC classification number: C08F230/04

Abstract: Organic polymeric multi-metallic alkoxide or aryloxide composites are used as dielectric materials in various devices with improved properties such as improved mobility. These composites comprise an organic polymer comprising metal coordination sites, and multi-metallic alkoxide or aryloxide molecules that are coordinated with the organic polymer, the multi-metallic alkoxide or aryloxide molecules being represented by: (M)n(OR)x wherein at least one M is a metal selected from Group 2 of the Periodic Table and at least one other M is a metal selected from any of Groups 3 to 12 and Rows 4 and 5 of the Periodic Table, n is an integer of at least 2, R represents the same or different alkyl or aryl groups, and x is an integer of at least 2.

Abstract translation: 有机聚合多金属醇盐或芳氧化物复合材料用作具有改进性能的各种装置中的介电材料，例如改进的流动性。 这些复合材料包括包含金属配位点的有机聚合物和与有机聚合物配位的多金属醇盐或芳氧化物分子，多金属醇盐或芳氧化物分子由以下表示：（M）n（OR）x，其中至少 一个M是选自元素周期表第2族的金属，并且至少一个其它M是选自元素周期表第3至12族和第4和5族中的任一个的金属，n是至少2的整数，R 表示相同或不同的烷基或芳基，x为至少2的整数。

公开(公告)号：US20130285061A1

公开(公告)日：2013-10-31

申请号：US13455398

申请日：2012-04-25

Applicant: Deepak Shukla ,  Douqlas R. Robello ,  Mark R. Mis ,  Wendy G. Ahearn ,  Dianne M. Meyer

Inventor： Deepak Shukla ,  Douqlas R. Robello ,  Mark R. Mis ,  Wendy G. Ahearn ,  Dianne M. Meyer

IPC: H01L29/786 ,  C08G63/00 ,  C08K5/06 ,  C08F220/10 ,  H01L21/336 ,  H01L21/20

CPC classification number: H01L51/052 ,  H01L51/0541 ,  H01L51/0545

Abstract: An organic film-forming polymer has a Tg of at least 70° C. and comprises a backbone comprising recurring units of Structure (A) shown in this application. These organic film-forming polymers can be used as dielectric materials in various devices with improved properties such as improved mobility.

Abstract translation: 有机成膜聚合物的Tg至少为70℃，并且包含一种骨架，其包含本申请中所示的结构（A）的重复单元。 这些有机成膜聚合物可以用作各种具有改进性能的改进性能的器件中的介电材料。

公开(公告)号：US09029431B2

公开(公告)日：2015-05-12

申请号：US13686943

申请日：2012-11-28

Applicant: Mridula Nair ,  Tamara K. Jones ,  Mark R. Mis

Inventor： Mridula Nair ,  Tamara K. Jones ,  Mark R. Mis

IPC: C08J9/00 ,  C08J9/28

CPC classification number: C08J9/283 ,  C08J2201/05 ,  C08J2325/14 ,  C08J2333/08 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2375/04

Abstract: Porous particles can be prepared using an evaporative limited coalescence process in which one or more discrete cavities are stabilized within the continuous polymeric solid phase of the porous particles. The one or more discrete cavities have inner walls and are dispersed within the continuous polymeric solid phase. The porous particles further comprise a cavity stabilizing hydrocolloid on the inner walls of the one or more discrete cavities, and an amphiphilic (low HLB) block copolymer that is disposed at the interface of the discrete cavities and the continuous polymeric solid phase.

Abstract translation: 多孔颗粒可以使用蒸发有限聚结方法制备，其中一个或多个离散的空腔在多孔颗粒的连续聚合固相中稳定。 一个或多个离散空腔具有内壁并且分散在连续的聚合物固相中。 多孔颗粒还包括在一个或多个离散空腔的内壁上的恒定水解胶体的空腔和设置在离散空腔和连续聚合物固相的界面处的两亲（低HLB）嵌段共聚物。

公开(公告)号：US20100035176A1

公开(公告)日：2010-02-11

申请号：US12189239

申请日：2008-08-11

Applicant: Douglas R. Robello ,  Mark R. Mis

Inventor： Douglas R. Robello ,  Mark R. Mis

IPC: G03F7/00

CPC classification number: G11B7/244 ,  G11B7/245 ,  G11B7/246

Abstract: An imaging element is used to provide images based on the difference in index of refraction caused by imaging actinic radiation. Imaging provides desired results by the creation or elimination of light scattering in a two-phase imaging medium in which at least one phase contains a material that is capable of having a refractive index change in response to imaging actinic radiation. For example, if the refractive indices of the two phases are initially matched, imaging can cause a mismatch in imaged regions. Alternatively, the refractive indices of the two phases can be initially mismatched and imaging can create a match of refractive indices in imaged regions. An image can be produced using a controlled amount of imaging actinic radiation without any chemical processing or heating.

Abstract translation: 成像元件用于基于由成像光化辐射引起的折射率差异来提供图像。 成像通过在两相成像介质中产生或消除光散射来提供期望的结果，其中至少一相包含能够响应于成像光化辐射而具有折射率变化的材料。 例如，如果两相的折射率初始匹配，则成像可能导致成像区域中的失配。 或者，两相的折射率可以最初不匹配，并且成像可以在成像区域中产生折射率的匹配。 可以使用受控量的成像光化辐射而不进行任何化学处理或加热来产生图像。

公开(公告)号：US09109221B2

公开(公告)日：2015-08-18

申请号：US13686946

申请日：2012-11-28

Applicant: Mark R. Mis ,  Mridula Nair ,  Douglas R. Robello

Inventor： Mark R. Mis ,  Mridula Nair ,  Douglas R. Robello

IPC: C12N11/04 ,  C12N11/08 ,  C12N11/14

CPC classification number: C12N11/04 ,  C12N11/08 ,  C12N11/14

Abstract: Semi-permeable particle can be used to facilitate chemical reactions such as catalytic reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less and have a mode particle size of at least 1 μm. The semi-permeable particles have multiple discrete cavities containing an aqueous solution or suspension of an organic catalytic material. The semi-permeable particles are also impermeable to the organic catalytic materials so they are retained within the multiple discrete cavities, and the semi-permeable particles can be reused multiple times for the same or different chemical reaction.

Abstract translation: 半渗透颗粒可用于促进化学反应，如催化反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的，并且模式粒径至少为1μm。 半渗透颗粒具有多个离散腔，其含有有机催化材料的水溶液或悬浮液。 半渗透颗粒对于有机催化材料也是不可渗透的，因此它们被保留在多个分立的空腔内，并且半渗透颗粒可以多次重复用于相同或不同的化学反应。

公开(公告)号：US20140147885A1

公开(公告)日：2014-05-29

申请号：US13686946

申请日：2012-11-28

Applicant: Mark R. Mis ,  Mridula Nair ,  Douglas R. Robello

Inventor： Mark R. Mis ,  Mridula Nair ,  Douglas R. Robello

IPC: C12N11/04

CPC classification number: C12N11/04 ,  C12N11/08 ,  C12N11/14

Abstract: Semi-permeable particle can be used to facilitate chemical reactions such as catalytic reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less and have a mode particle size of at least 1 μm. The semi-permeable particles have multiple discrete cavities containing an aqueous solution or suspension of an organic catalytic material. The semi-permeable particles are also impermeable to the organic catalytic materials so they are retained within the multiple discrete cavities, and the semi-permeable particles can be reused multiple times for the same or different chemical reaction.

Abstract translation: 半渗透颗粒可用于促进化学反应，如催化反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的，并且模式粒径至少为1μm。 半渗透颗粒具有多个离散腔，其含有有机催化材料的水溶液或悬浮液。 半渗透颗粒对于有机催化材料也是不可渗透的，因此它们被保留在多个分立的空腔内，并且半渗透颗粒可以多次重复用于相同或不同的化学反应。

公开(公告)号：US07989536B2

公开(公告)日：2011-08-02

申请号：US12240073

申请日：2008-09-29

Applicant: Mark R. Mis ,  Douglas R. Robello ,  Thomas N. Blanton ,  Craig L. Barnes

Inventor： Mark R. Mis ,  Douglas R. Robello ,  Thomas N. Blanton ,  Craig L. Barnes

IPC: C08L25/06

CPC classification number: C08K3/346 ,  C08K9/04 ,  C08L25/06

Abstract: A polymeric nanocomposite comprises a non-polar hyperbranched polystyrene resin. An exfoliated or intercalated onium functionalized clay is dispersed within the resin. Such nanocomposites are more compatible with non-polar polymer matrices used in various articles of manufacture.

Abstract translation: 聚合物纳米复合材料包括非极性超支化聚苯乙烯树脂。 剥离或嵌入的鎓官能化粘土分散在树脂内。 这种纳米复合材料与用于各种制品的非极性聚合物基质更相容。