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    PRECURSOR DIELECTRIC COMPOSITION WITH THIOSULFATE-CONTAINING POLYMERS
    3.
    发明申请
    PRECURSOR DIELECTRIC COMPOSITION WITH THIOSULFATE-CONTAINING POLYMERS 有权
    含有含硫聚合物聚合物的前驱体电介质组合物

    公开(公告)号：US20150364688A1

    公开(公告)日：2015-12-17

    申请号：US14301385

    申请日：2014-06-11

    Applicant: Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

    Inventor： Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

    IPC: H01L51/00

    CPC classification number: H01L51/052 ,  C08F12/30 ,  C08F220/14 ,  C08F220/18 ,  C08G18/0819 ,  C08G18/381 ,  C08G18/44 ,  C08G18/6633 ,  C08G18/755 ,  C08G18/83 ,  H01L51/0053 ,  H01L51/0541 ,  H01L51/0545 ,  C08F212/14 ,  C08F2220/1858

    Abstract: A precursor dielectric composition comprises: (1) a photocurable or thermally curable thiosulfate-containing polymer that has a Tg of at least 50° C. and comprises: an organic polymer backbone comprising (a) recurring units comprising pendant thiosulfate groups; and organic charge balancing cations, (2) optionally, an electron-accepting photosensitizer component, and (3) one or more organic solvents in which the photocurable or thermally curable thiosulfate-containing polymer is dissolved or dispersed. These precursor dielectric compositions can be applied to various substrates and eventually cured to form dielectric compositions or layers for various types of electronic devices.

    Abstract translation: 前体电介质组合物包含：（1）Tg至少为50℃的可光固化或可热固化的含硫代硫酸盐的聚合物，包括：有机聚合物主链，其包含（a）包含硫代硫酸盐基团的重复单元; 和有机电荷平衡阳离子，（2）任选的电子接受光敏剂组分，和（3）其中溶解或分散有可光固化或可热固化的含硫代硫酸盐的聚合物的一种或多种有机溶剂。 这些前体介电组合物可以施加到各种基底上，并且最终固化以形成用于各种类型的电子器件的电介质组合物或层。

    THIOSULFATE POLYMERS
    4.
    发明申请
    THIOSULFATE POLYMERS 有权
    硫代聚合物

    公开(公告)号：US20140288253A1

    公开(公告)日：2014-09-25

    申请号：US14158897

    申请日：2014-01-20

    Applicant: Mark R. Mis ,  Deepak Shukla

    Inventor： Mark R. Mis ,  Deepak Shukla

    IPC: C08F20/70

    CPC classification number: C08F228/02 ,  C08F20/70 ,  C08F212/14 ,  C08F220/66 ,  C08F222/04 ,  C08F222/40 ,  C08F226/12 ,  C08F232/08 ,  C08F2220/385 ,  C08F2222/402 ,  C08F2222/404 ,  C08F2222/406 ,  C08F2222/408 ,  C09D4/00 ,  C08F220/14 ,  C08F220/34

    Abstract: A thiosulfate polymer includes both an electron-accepting photosensitizer component and thiosulfate groups in the same molecule, arranged in random order along the backbone. The thiosulfate polymer composition can be formulated into compositions and applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.

    Abstract translation: 硫代硫酸盐聚合物包括同一分子中的电子接受光敏剂组分和硫代硫酸盐基团，其沿主链以随机顺序排列。 硫代硫酸盐聚合物组合物可以配制成组合物并施加到各种制品上，或者用于在光热反应后形成预定的聚合物图案以形成交联的二硫键，除去非交联的聚合物和与二硫化物反应性材料的反应。 这样的硫代硫酸盐聚合物组合物也可以用于螯合纳米颗粒形式的金属，并且作为在理发操作中塑造人的头发的方法。

    PHOTOPOLYMERIZABLE COMPOSITIONS FOR ELECTROLESS PLATING METHODS
    6.
    发明申请
    PHOTOPOLYMERIZABLE COMPOSITIONS FOR ELECTROLESS PLATING METHODS 有权
    用于电镀法的光聚合组合物

    公开(公告)号：US20150227041A1

    公开(公告)日：2015-08-13

    申请号：US14174879

    申请日：2014-02-07

    Applicant: Deepak Shukla ,  Mark R. Mis

    Inventor： Deepak Shukla ,  Mark R. Mis

    IPC: G03F7/038

    CPC classification number: G03F7/038 ,  G03F7/0045 ,  G03F7/0047 ,  G03F7/028

    Abstract: A photopolymerizable composition has seven essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron acceptor photosensitizer, (d) an electron donor co-initiator having an oxidation potential of 0.1 V to 3 V vs. SCE, (e) metal particles, and in some embodiments, (f) one or more free radically polymerizable compounds, and (g) one or more free radical photoinitiators. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing and plating systems once various photocured patterns are formed from the photopolymerizable compositions.

    Abstract translation: 可光聚合组合物具有七个基本组分：（a）光聚合环氧材料，（b）光酸产生剂如鎓盐，（c）电子受体光敏剂，（d）电子给体共引发剂，其氧化电位为0.1 V至3V对SCE，（e）金属颗粒，在一些实施方案中，（f）一种或多种可自由基自由基化合物，和（g）一种或多种自由基光引发剂。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上，以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦从光聚合组合物形成各种光固化图案，可以在辊对印刷和电镀系统中进行的化学镀方法。

    Forming patterns using thiosulfate polymer compositions
    7.
    发明授权
    Forming patterns using thiosulfate polymer compositions 有权
    使用硫代硫酸盐聚合物组合物形成图案

    公开(公告)号：US09005878B2

    公开(公告)日：2015-04-14

    申请号：US14158884

    申请日：2014-01-20

    Applicant: Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

    Inventor： Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

    IPC: G03F7/26 ,  G03F7/30

    CPC classification number: G03F7/30 ,  G03F7/0045 ,  G03F7/038 ,  G03F7/405

    Abstract: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles and used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material.

    Abstract translation: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分，作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以应用于各种制品，并且用于在光热反应之后形成预定的聚合物图案以形成交联的二硫键，除去未交联的聚合物和与二硫化物反应性材料的反应。

    THIOSULFATE-CONTAINING POLYMERS ASSOCIATED WITH PHOTOSENSITIZER COMPONENT
    8.
    发明申请
    THIOSULFATE-CONTAINING POLYMERS ASSOCIATED WITH PHOTOSENSITIZER COMPONENT 有权
    与光敏元件相关的含硫聚合物的聚合物

    公开(公告)号：US20150361206A1

    公开(公告)日：2015-12-17

    申请号：US14301380

    申请日：2014-06-11

    Applicant: Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

    Inventor： Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

    IPC: C08F228/02 ,  H01B3/44 ,  C08F222/02 ,  C08F222/40 ,  C08F222/10

    CPC classification number: C08F228/02 ,  C08F220/14 ,  C08F222/02 ,  C08F222/10 ,  C08F222/40 ,  C08F2222/404 ,  H01B3/447 ,  C08F212/14 ,  C08F2220/303 ,  C08F220/36 ,  C08F2220/1858

    Abstract: A photocurable or thermally curable thiosulfate-containing polymer has (a) recurring units and (d) recurring units, shown as either Structure (I) or (II) and Structure (V) below: R represents the organic polymer backbone, G is a single bond or divalent linking group, Q+ is an organic charge balancing cation, M represents a charge balancing cation, and “a” represents at least 0.5 mol % and to 99.5 mol % of (a) recurring units; R″ represents the organic polymer backbone, G″ is a carbonyloxy group, R3 comprises a monovalent linear, branched, or carbocyclic non-aromatic hydrocarbon group having 1 to 18 carbon atoms, or it comprises a phenyl group having one or more such substituents, and “d” represents at least 0.5 mol % and to 99.5 mol % of (d) recurring units. These thiosulfate-containing polymers can be used to made dielectric compositions and gate dielectric layers in various devices.

    Abstract translation: 可光固化或热固化的含硫代硫酸盐的聚合物具有（a）重复单元和（d）如结构（I）或（II）和结构（V）所示的重复单元：R表示有机聚合物主链，G为 单键或二价连接基团，Q +是有机电荷平衡阳离子，M表示电荷平衡阳离子，“a”表示（a）重复单元的至少0.5摩尔％至99.5摩尔％ R“表示有机聚合物主链，G”是羰氧基，R3包括具有1至18个碳原子的一价直链，支链或碳环非芳族烃基，或其包含具有一个或多个这样的取代基的苯基， 和“d”表示（d）重复单元的至少0.5摩尔％至99.5摩尔％。 这些含硫代硫酸盐的聚合物可以用于制备各种装置中的电介质组合物和栅极电介质层。

    Photopolymerizable compositions for electroless plating methods
    9.
    发明授权
    Photopolymerizable compositions for electroless plating methods 有权
    用于化学镀方法的光聚合组合物

    公开(公告)号：US09207533B2

    公开(公告)日：2015-12-08

    申请号：US14174879

    申请日：2014-02-07

    Applicant: Deepak Shukla ,  Mark R. Mis

    Inventor： Deepak Shukla ,  Mark R. Mis

    IPC: G03F7/004 ,  G03F7/038 ,  G03F7/028

    CPC classification number: G03F7/038 ,  G03F7/0045 ,  G03F7/0047 ,  G03F7/028

    Abstract: A photopolymerizable composition has seven essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron acceptor photosensitizer, (d) an electron donor co-initiator having an oxidation potential of 0.1 V to 3 V vs. SCE, (e) metal particles, and in some embodiments, (f) one or more free radically polymerizable compounds, and (g) one or more free radical photoinitiators. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing and plating systems once various photocured patterns are formed from the photopolymerizable compositions.

    Abstract translation: 可光聚合组合物具有七个基本组分：（a）可光聚合的环氧材料，（b）光酸产生剂如鎓盐，（c）电子受体光敏剂，（d）电子给体共引发剂，其氧化电位为0.1 V至3V对SCE，（e）金属颗粒，在一些实施方案中，（f）一种或多种可自由基自由基化合物，和（g）一种或多种自由基光引发剂。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上，以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦从光聚合组合物形成各种光固化图案，可以在辊对印刷和电镀系统中进行的化学镀方法。

    Photopolymerizable compositions for electroless plating methods
    10.
    发明授权
    Photopolymerizable compositions for electroless plating methods 有权
    用于化学镀方法的光聚合组合物

    公开(公告)号：US09188861B2

    公开(公告)日：2015-11-17

    申请号：US14197293

    申请日：2014-03-05

    Applicant: Deepak Shukla ,  Mark R. Mis

    Inventor： Deepak Shukla ,  Mark R. Mis

    IPC: G03F7/004 ,  G03F7/038 ,  G03F7/16

    CPC classification number: G03F7/038 ,  G03F7/0045 ,  G03F7/0047 ,  G03F7/028 ,  G03F7/16

    Abstract: A photopolymerizable composition has five essential components: (a) a photopolymerizable epoxy material, (b) a photoacid generator such as an onium salt, (c) electron donor photosensitizer having an oxidation potential of at least 0.4 V and up to and including 3 V vs. SCE, and (d) metal particles. This photopolymerizable composition can be applied or printed onto one or both sides of various substrates to form articles that can be used to form electrically conductive materials. Methods for using the photopolymerizable compositions include electroless plating methods that can be carried out in roll-to-roll printing systems once various photocured patterns are formed from the photopolymerizable compositions.

    Abstract translation: 可光聚合组合物具有五个基本组分：（a）可光聚合的环氧材料，（b）光酸产生剂如鎓盐，（c）电子给体光敏剂，其氧化电位至少为0.4V且至多并包括3V 与SCE，（d）金属颗粒。 该可光聚合组合物可以施加或印刷在各种基材的一面或两面上以形成可用于形成导电材料的制品。 使用可光聚合组合物的方法包括一旦可光聚合组合物形成各种光固化图案，就可以在卷对卷印刷系统中进行的化学镀方法。

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