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公开(公告)号:US09029431B2
公开(公告)日:2015-05-12
申请号:US13686943
申请日:2012-11-28
申请人: Mridula Nair , Tamara K. Jones , Mark R. Mis
发明人: Mridula Nair , Tamara K. Jones , Mark R. Mis
CPC分类号: C08J9/283 , C08J2201/05 , C08J2325/14 , C08J2333/08 , C08J2367/02 , C08J2367/04 , C08J2375/04
摘要: Porous particles can be prepared using an evaporative limited coalescence process in which one or more discrete cavities are stabilized within the continuous polymeric solid phase of the porous particles. The one or more discrete cavities have inner walls and are dispersed within the continuous polymeric solid phase. The porous particles further comprise a cavity stabilizing hydrocolloid on the inner walls of the one or more discrete cavities, and an amphiphilic (low HLB) block copolymer that is disposed at the interface of the discrete cavities and the continuous polymeric solid phase.
摘要翻译: 多孔颗粒可以使用蒸发有限聚结方法制备,其中一个或多个离散的空腔在多孔颗粒的连续聚合固相中稳定。 一个或多个离散空腔具有内壁并且分散在连续的聚合物固相中。 多孔颗粒还包括在一个或多个离散空腔的内壁上的恒定水解胶体的空腔和设置在离散空腔和连续聚合物固相的界面处的两亲(低HLB)嵌段共聚物。
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公开(公告)号:US20140148523A1
公开(公告)日:2014-05-29
申请号:US13686943
申请日:2012-11-28
申请人: Mridula Nair , Tamara K. Jones , Mark R. Mis
发明人: Mridula Nair , Tamara K. Jones , Mark R. Mis
IPC分类号: C08J9/28
CPC分类号: C08J9/283 , C08J2201/05 , C08J2325/14 , C08J2333/08 , C08J2367/02 , C08J2367/04 , C08J2375/04
摘要: Porous particles can be prepared using an evaporative limited coalescence process in which one or more discrete cavities are stabilized within the continuous polymeric solid phase of the porous particles. The one or more discrete cavities have inner walls and are dispersed within the continuous polymeric solid phase. The porous particles further comprise a cavity stabilizing hydrocolloid on the inner walls of the one or more discrete cavities, and an amphiphilic (low HLB) block copolymer that is disposed at the interface of the discrete cavities and the continuous polymeric solid phase.
摘要翻译: 多孔颗粒可以使用蒸发有限聚结方法制备,其中一个或多个离散的空腔在多孔颗粒的连续聚合固相中稳定。 一个或多个离散空腔具有内壁并且分散在连续的聚合物固相中。 多孔颗粒还包括在一个或多个离散空腔的内壁上的恒定水解胶体的空腔和设置在离散空腔和连续聚合物固相的界面处的两亲(低HLB)嵌段共聚物。
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公开(公告)号:US09109221B2
公开(公告)日:2015-08-18
申请号:US13686946
申请日:2012-11-28
申请人: Mark R. Mis , Mridula Nair , Douglas R. Robello
发明人: Mark R. Mis , Mridula Nair , Douglas R. Robello
摘要: Semi-permeable particle can be used to facilitate chemical reactions such as catalytic reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less and have a mode particle size of at least 1 μm. The semi-permeable particles have multiple discrete cavities containing an aqueous solution or suspension of an organic catalytic material. The semi-permeable particles are also impermeable to the organic catalytic materials so they are retained within the multiple discrete cavities, and the semi-permeable particles can be reused multiple times for the same or different chemical reaction.
摘要翻译: 半渗透颗粒可用于促进化学反应,如催化反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的,并且模式粒径至少为1μm。 半渗透颗粒具有多个离散腔,其含有有机催化材料的水溶液或悬浮液。 半渗透颗粒对于有机催化材料也是不可渗透的,因此它们被保留在多个分立的空腔内,并且半渗透颗粒可以多次重复用于相同或不同的化学反应。
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公开(公告)号:US20140147885A1
公开(公告)日:2014-05-29
申请号:US13686946
申请日:2012-11-28
申请人: Mark R. Mis , Mridula Nair , Douglas R. Robello
发明人: Mark R. Mis , Mridula Nair , Douglas R. Robello
IPC分类号: C12N11/04
摘要: Semi-permeable particle can be used to facilitate chemical reactions such as catalytic reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less and have a mode particle size of at least 1 μm. The semi-permeable particles have multiple discrete cavities containing an aqueous solution or suspension of an organic catalytic material. The semi-permeable particles are also impermeable to the organic catalytic materials so they are retained within the multiple discrete cavities, and the semi-permeable particles can be reused multiple times for the same or different chemical reaction.
摘要翻译: 半渗透颗粒可用于促进化学反应,如催化反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的,并且模式粒径至少为1μm。 半渗透颗粒具有多个离散腔,其含有有机催化材料的水溶液或悬浮液。 半渗透颗粒对于有机催化材料也是不可渗透的,因此它们被保留在多个分立的空腔内,并且半渗透颗粒可以多次重复用于相同或不同的化学反应。
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公开(公告)号:US20140148330A1
公开(公告)日:2014-05-29
申请号:US13686941
申请日:2012-11-28
申请人: Douglas R. Robello , Mridula Nair , Mark R. Mis , Matthew Dirmyer
发明人: Douglas R. Robello , Mridula Nair , Mark R. Mis , Matthew Dirmyer
IPC分类号: B01J31/06 , C07C67/303 , C07C29/17
CPC分类号: B01J31/06 , B01J23/42 , B01J23/44 , B01J23/70 , B01J23/755 , B01J35/0013 , B01J35/023 , B01J37/0203 , B01J37/0211 , B01J37/0213 , B01J2231/645 , C07C29/17 , C07C29/172 , C07C67/303 , C07C33/035 , C07C31/207 , C07C69/28
摘要: Semi-permeable particle can be used to facilitate chemical reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less, have a mode particle size of at least 1 μm, and comprise nanoparticles of catalytically active metallic materials disposed within at least some of multiple discrete cavities in the continuous polymeric phase. The nanoparticles of catalytically active metallic materials (a) comprise one or more elements selected from Groups 8, 9, 10, and 11 of the Periodic Table, and (b) have an effective diameter of at least 1 nm and up to and including 200 nm.
摘要翻译: 半渗透颗粒可用于促进化学反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的,具有至少1μm的模式粒度,并且包含催化活性金属材料的纳米颗粒,其设置在连续的多个离散空腔的至少一些中 聚合物相。 催化活性金属材料的纳米颗粒(a)包含选自元素周期表第8,9,10和11族的一种或多种元素,和(b)具有至少1nm的有效直径和至多并包括200 nm。
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公开(公告)号:US09637581B2
公开(公告)日:2017-05-02
申请号:US14301380
申请日:2014-06-11
申请人: Deepak Shukla , Kevin M. Donovan , Mark R. Mis
发明人: Deepak Shukla , Kevin M. Donovan , Mark R. Mis
IPC分类号: C08F228/02 , C08F222/10 , C08F222/40 , C08F222/02 , H01B3/44 , C08F220/14
CPC分类号: C08F228/02 , C08F220/14 , C08F222/02 , C08F222/10 , C08F222/40 , C08F2222/404 , H01B3/447 , C08F212/14 , C08F2220/303 , C08F220/36 , C08F2220/1858
摘要: A photocurable or thermally curable thiosulfate-containing polymer has (a) recurring units and (d) recurring units, shown as either Structure (I) or (II) and Structure (V) below: R represents the organic polymer backbone, G is a single bond or divalent linking group, Q+ is an organic charge balancing cation, M represents a charge balancing cation, and “a” represents at least 0.5 mol % and to 99.5 mol % of (a) recurring units; R″ represents the organic polymer backbone, G″ is a carbonyloxy group, R3 comprises a monovalent linear, branched, or carbocyclic non-aromatic hydrocarbon group having 1 to 18 carbon atoms, or it comprises a phenyl group having one or more such substituents, and “d” represents at least 0.5 mol % and to 99.5 mol % of (d) recurring units. These thiosulfate-containing polymers can be used to made dielectric compositions and gate dielectric layers in various devices.
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公开(公告)号:US20150364688A1
公开(公告)日:2015-12-17
申请号:US14301385
申请日:2014-06-11
申请人: Deepak Shukla , Kevin M. Donovan , Mark R. Mis
发明人: Deepak Shukla , Kevin M. Donovan , Mark R. Mis
IPC分类号: H01L51/00
CPC分类号: H01L51/052 , C08F12/30 , C08F220/14 , C08F220/18 , C08G18/0819 , C08G18/381 , C08G18/44 , C08G18/6633 , C08G18/755 , C08G18/83 , H01L51/0053 , H01L51/0541 , H01L51/0545 , C08F212/14 , C08F2220/1858
摘要: A precursor dielectric composition comprises: (1) a photocurable or thermally curable thiosulfate-containing polymer that has a Tg of at least 50° C. and comprises: an organic polymer backbone comprising (a) recurring units comprising pendant thiosulfate groups; and organic charge balancing cations, (2) optionally, an electron-accepting photosensitizer component, and (3) one or more organic solvents in which the photocurable or thermally curable thiosulfate-containing polymer is dissolved or dispersed. These precursor dielectric compositions can be applied to various substrates and eventually cured to form dielectric compositions or layers for various types of electronic devices.
摘要翻译: 前体电介质组合物包含:(1)Tg至少为50℃的可光固化或可热固化的含硫代硫酸盐的聚合物,包括:有机聚合物主链,其包含(a)包含硫代硫酸盐基团的重复单元; 和有机电荷平衡阳离子,(2)任选的电子接受光敏剂组分,和(3)其中溶解或分散有可光固化或可热固化的含硫代硫酸盐的聚合物的一种或多种有机溶剂。 这些前体介电组合物可以施加到各种基底上,并且最终固化以形成用于各种类型的电子器件的电介质组合物或层。
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公开(公告)号:US20140288253A1
公开(公告)日:2014-09-25
申请号:US14158897
申请日:2014-01-20
申请人: Mark R. Mis , Deepak Shukla
发明人: Mark R. Mis , Deepak Shukla
IPC分类号: C08F20/70
CPC分类号: C08F228/02 , C08F20/70 , C08F212/14 , C08F220/66 , C08F222/04 , C08F222/40 , C08F226/12 , C08F232/08 , C08F2220/385 , C08F2222/402 , C08F2222/404 , C08F2222/406 , C08F2222/408 , C09D4/00 , C08F220/14 , C08F220/34
摘要: A thiosulfate polymer includes both an electron-accepting photosensitizer component and thiosulfate groups in the same molecule, arranged in random order along the backbone. The thiosulfate polymer composition can be formulated into compositions and applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.
摘要翻译: 硫代硫酸盐聚合物包括同一分子中的电子接受光敏剂组分和硫代硫酸盐基团,其沿主链以随机顺序排列。 硫代硫酸盐聚合物组合物可以配制成组合物并施加到各种制品上,或者用于在光热反应后形成预定的聚合物图案以形成交联的二硫键,除去非交联的聚合物和与二硫化物反应性材料的反应。 这样的硫代硫酸盐聚合物组合物也可以用于螯合纳米颗粒形式的金属,并且作为在理发操作中塑造人的头发的方法。
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公开(公告)号:US20140287349A1
公开(公告)日:2014-09-25
申请号:US14158883
申请日:2014-01-20
申请人: Deepak Shukla , Mark R. Mis , Dianne Marie Meyer
发明人: Deepak Shukla , Mark R. Mis , Dianne Marie Meyer
IPC分类号: G03F7/038
CPC分类号: G03F7/038 , A61K8/81 , A61K8/8147 , A61Q5/04 , A61Q5/06 , C08F2/50 , C08F20/70 , C08F212/04 , C08F212/14 , C08F220/66 , C08F222/04 , C08F222/40 , C08F226/12 , C08F228/02 , C08F232/08 , C08F2222/402 , C08F2222/404 , C08F2222/406 , C08F2222/408 , C09D4/00 , G03F7/0045 , Y02P20/582 , C08F8/34 , C08F220/14 , C08F2220/365
摘要: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.
摘要翻译: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分,作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以应用于各种制品,或者用于在光热反应之后形成预定的聚合物图案以形成交联的二硫键,除去非交联聚合物和与二硫化物反应性材料的反应。 这样的硫代硫酸盐聚合物组合物也可以用于螯合纳米颗粒形式的金属,并且作为在理发操作中塑造人的头发的方法。
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公开(公告)号:US20100035176A1
公开(公告)日:2010-02-11
申请号:US12189239
申请日:2008-08-11
申请人: Douglas R. Robello , Mark R. Mis
发明人: Douglas R. Robello , Mark R. Mis
IPC分类号: G03F7/00
摘要: An imaging element is used to provide images based on the difference in index of refraction caused by imaging actinic radiation. Imaging provides desired results by the creation or elimination of light scattering in a two-phase imaging medium in which at least one phase contains a material that is capable of having a refractive index change in response to imaging actinic radiation. For example, if the refractive indices of the two phases are initially matched, imaging can cause a mismatch in imaged regions. Alternatively, the refractive indices of the two phases can be initially mismatched and imaging can create a match of refractive indices in imaged regions. An image can be produced using a controlled amount of imaging actinic radiation without any chemical processing or heating.
摘要翻译: 成像元件用于基于由成像光化辐射引起的折射率差异来提供图像。 成像通过在两相成像介质中产生或消除光散射来提供期望的结果,其中至少一相包含能够响应于成像光化辐射而具有折射率变化的材料。 例如,如果两相的折射率初始匹配,则成像可能导致成像区域中的失配。 或者,两相的折射率可以最初不匹配,并且成像可以在成像区域中产生折射率的匹配。 可以使用受控量的成像光化辐射而不进行任何化学处理或加热来产生图像。
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