摘要:
A coating in accordance with the invention has a substantially crystalline first layer with a substantially crystalline second layer provided over the first layer. A breaker layer is provided between the first and second layers and is configured to prevent or at least reduce epitaxial growth of the second layer on the first layer. A color suppression layer may be provided below the first layer. The coating can be provided on a substrate to make a coated article. A method of coating a substrate includes depositing a substantially crystalline first layer over at least a portion of the substrate and depositing a breaker layer over the first layer. The breaker layer is configured to prevent or at least reduce epitaxial growth of a subsequently deposited layer on the first layer.
摘要:
An apparatus for coating a moving substrate which provides means for directing a coating composition vapor toward a substrate surface and moving portions of the vapor in opposite directions. The apparatus of the present invention may have the exhaust means on either side of the vapor directing means spaced at different distances from the vapor directing means, or the exhaust means may be spaced equally from the vapor directing means, but at different distances from the substrate surface. In another embodiment, the apparatus comprises the means to alter the flow volume of the vapor directing means and the two exhaust means such that the flow volume of the first and second exhaust means are not equal, such as by the exhaust means having openings of unequal surface area, wherein the exhaust means may be spaced equally or unequally from the vapor directing means at the same or different distances from the substrate surface. In another embodiment, the apparatus further comprises a structural element bridging the space between the vapor directing means and the exhaust means, which may be spaced equally or unequally from the vapor directing means, and at the same or different distances from the substrate surface.
摘要:
A method for coating a moving substrate provides a coating having a chemical composition which varies continuously from the interface with the substrate to the opposite surface of the coating. The method involves directing a vapor coating composition toward a substrate surface and moving portions of the vapor in opposite directions. A vapor coating mixture may include a tin-containing precursor and a silicon-containing precursor. An accelerant, e.g. a phosphorus-containing precursor, may be used with the metal-containing precursors to increase the deposition rate of the coating. The coating deposited on the substrate has regions of continuously varying weight percent of silicon oxide and tin oxide as the distance from the substrate-coating interface increases, with the surface of the coating farthest from the substrate-coating interface being predominantly tin oxide. The regions of varying composition provide the coating with varying indices of refraction to eliminate iridescence to provide a coated article, particularly a tin oxide coated glass article, with a neutral color.
摘要:
A continuous glass ribbon advances from a float forming chamber past a first heat source and into a coating chamber where a surface of the glass ribbon is provided with a pyrolytic oxide coating as a second heat source heats the opposed surface of the glass ribbon. Thereafter the glass ribbon is advanced into an annealing lehr to relieve residual stress in the glass ribbon. The first heat source reduces the heat loss of the ribbon as it advances into the coating chamber to provide a durable pyrolytic oxide coating on the glass ribbon. The second heat source heats the ribbon to minimize or eliminate glass ribbon warpage.