摘要:
A styrenic composition including a polar modified styrenic co-polymer resulting from the polymerization of a combined mixture of at least one styrenic monomer and at least one comonomer and a biodegradable component is disclosed. The at least one comonomer includes a polar functional group and the polar modified styrenic co-polymer and the biodegradable component are combined to obtain a styrenic composition having a biodegradable component. Also disclosed is a method of enhancing bio-polymer miscibility in a styrenic based polymer. The polarity of a blend is manipulated by combining a styrenic monomer and a polar co-monomer to form a combined mixture and subjecting the combined mixture to polymerization to obtain a styrenic polymer blend to which a bio-polymer is added.
摘要:
Expanded polystyrene, foamed articles and methods of making the same are described herein. The expanded polystyrene generally includes polystyrene selected from expandable polystyrene and extrusion polystyrene, the polystyrene exhibiting a molecular weight of from about 130,000 Daltons to about 220,000 Daltons; a melt flow index of from about 20 to about 30 and a density of from about 0.1 lb/ft3 to about 10 lb/ft3; and wherein the expanded polystyrene exhibits a density of from about 0.1 lb/ft3 to about 10 lb/ft3.
摘要翻译:膨胀聚苯乙烯,发泡制品及其制备方法在本文中描述。 发泡聚苯乙烯通常包括选自可发性聚苯乙烯和挤出聚苯乙烯的聚苯乙烯,聚苯乙烯的分子量为约130,000道尔顿至约220,000道尔顿; 熔体流动指数为约20至约30,密度为约0.1lb / ft 3至约10lb / ft 3; 并且其中所述发泡聚苯乙烯的密度为约0.1lb / ft 3至约10lb / ft 3。
摘要:
Peroxide initiators are disclosed that can be used at lower temperatures during HIPS production. Enhanced formation of graft polymers between polystyrene and polybutadiene (rubber) can be accomplished by using these lower temperature peroxide initiators that have a 1 hour half-life period at one or more temperatures from 95° C. to less than 111° C. during the pre-inversion stage. “Higher” temperature initiators are used during and/or after inversion. The use of such “low” temperature initiators improves polymerization rates and grafting values, while reducing the swell index and the amount of rubber used, thereby producing improved HIPS more rapidly and at a lower cost. Also disclosed are HIPS compositions and products produced by such “low” temperature initiators as well as a method of producing improved HIPS.
摘要:
A method and apparatus are disclosed for purifying copolymer compounds having monovinyl aromatic blocks and conjugated diene blocks by reducing the residual monomer content of the finished polymer. The method and apparatus includes a combination of heat exchangers and devolatilizers used in conjunction with a copolymerization reactor system.
摘要:
It has been discovered that the melt instability of styrenic polymers, particularly high impact polystyrene (HIPS) can be reduced or eliminated by the blending therewith of a relatively high melt flow index (MFI) material, such as polystyrene homopolymer. Draw resonance of the melt blend can also be reduced by this method, thereby improving melt processing of these materials. A method to measure melt instability of drawn materials is also discussed.
摘要:
Disclosed are blends of polystyrene and at least one of syndiotactic polypropylene, ethylene propylene copolymers, and styrene-butadiene-styrene triblock copolymers. These blends are prepared using solution polymerization and have unique morphologies and desirable physical properties. The blends can also be prepared with graft-promoting or crosslinking agents and rubbers to prepare modified high impact polystyrene.
摘要:
Disclosed are high impact polystyrenes prepared using mixed initiators. The mixed initiators include at least one grafting initiator and one non-grafting initiator. The high impact polystyrenes prepared therewith have a continuous polystyrene phase and dispersed therein particles of rubber predominantly having a honeycomb structure of rubber with polystyrene inclusions.
摘要:
A method comprising extrusion compounding a styrenic polymer and a layered compound to produce a composite, and orienting the composite to produce an oriented composite wherein the layered compound comprises natural clay, synthetic clay, natural colloid, synthetic colloid, natural sol, synthetic sol, natural gel, synthetic gel, natural fumes, synthetic fumes, or combinations thereof. A method of preparing an oriented film comprising extrusion compounding a styrenic polymer and a clay to produce a nanocomposite, casting the nanocomposite into a film, and orienting the film in at least one direction.
摘要:
A method comprising extrusion compounding a styrenic polymer and a layered compound to produce a composite, and orienting the composite to produce an oriented composite wherein the layered compound comprises natural clay, synthetic clay, natural colloid, synthetic colloid, natural sol, synthetic sol, natural gel, synthetic gel, natural fumes, synthetic fumes, or combinations thereof. A method of preparing an oriented film comprising extrusion compounding a styrenic polymer and a clay to produce a nanocomposite, casting the nanocomposite into a film, and orienting the film in at least one direction.
摘要:
Methods and systems for pelletizing high melt flow polystyrene are described herein. The method generally includes providing a polystyrene including a melt flow index of about 16 g/10 min to about 34 g/10 min; extruding a strand of the polystyrene through a die head, wherein a temperature of the polystyrene at the die head is from about 370° to about 430° F.; and moving the strand through a bath, wherein a temperature of the bath is from about 95° to about 145° F.