摘要:
Isocyanurate- and uretdione-group-containing polyaddition product of an isophorone diisocyanate comprising the reaction product of: i) an isophorone diisocyanate which contains isocyanurate groups and uretdione groups; and ii) a diol component selected from the group consisting of a diol, a disecondary diamine, a linear hydroxyl-containing polyester and a mixture thereof, wherein said isophorone diisocyanate comprises not more than 2% by weight of free isophorone diisocyanate and .gtoreq.5 wt. % of isophorone diisocyanate isocyanurate, wherein said isophorone diisocyanate is reacted with said diol component in an NCO/OH ratio of 1:0.5-1:0.95 and/or an NCO/NH ratio of 0.5:1 0.95:1.
摘要:
A blocked highly functional polyisocyanate adduct is described with a melting point of 2 contains 1.1-2 mol of blocking agent per blocked NCO group.
摘要:
The invention relates to light-stabile, reactive two-component PUR paints which cure at room temperature and are comprised of:a) isocyanate prepolymers blocked with certain sterically hindered piperidine derivatives; andb) (cyclo)aliphatic polyamines and/or aminoamides;wherewith 1-1.4 blocked NCO groups are brought to reaction per amino group.
摘要:
Monoblocked diisocyanates which contain little free and diblocked diisocyanate are obtained by a process which involves adding 1 mole of a blocking agent to a diisocyanate which is present in excess and subsequently removing the excess diisocyanate by thin film evaporation. The compounds produced are useful for the production of cataphoresis resins.
摘要:
A process for producing a substantially isocyanurate-free uretidione dimer of isophorone diisocyanate, which is more than 98% decomposable by heat to isophorone diisocyanate, which comprises dimerizing isophorone diisocyanate, optionally in an inert organic solvent, in the presence of a catalyst of the formula X.sub.m P(NR.sub.2).sub.3-m wherein m=0, 1, 2; X=Cl OR of R wherein R is selected from the group consisting of the same or different aklyl radical, aralkyl radical, cycloalkyl radical, substituted cycloalkyl radical and radicals wherein two or more of the aforementioned radicals form a hererocyclic ring together with the nitrogen atom; at temperatures of 0.degree.-80.degree. C., isolating the resulting 1,3-diazacyclobutane-2,4-dione, after 5-70% conversion, without previous inactivation of the catalyst, from the reaction mixture as the residue of a thin film distillation and isolating the catalyst and monomer as the distillate.
摘要:
Urea derivatives containing isocyanatomethyl groups of 3(4), 8(9)-diisocyanatomethyltricyclo [5.2.1.0.sup.2,6 ] decane of the formulaOCN--H.sub.2 C--[R--CH.sub.2 --NH--CO--NH--CH.sub.2 ].sub.n --R--CH.sub.2 --NCO, in which R is ##STR1## and n=1-5.
摘要:
A method for the production of blocked isocyanate- and isocyanurate group-containing compounds which comprises reacting a monomeric cycloaliphatic polyisocyanate to form an intermediate mixture comprising an isocyanurate containing at least two free isocyanate groups; and blocking the intermediate isocyanurate mixture with dimethylketoxime at 50.degree.-120.degree. C., wherein the amount of said dimethylketoxime is such that one equivalent of NCO group reacts with one equivalent of the dimethylketoxime. A mixture containing isocyanurate and blocked isocyanate groups which comprises at least 10% by weight of a cycloaliphatic isocyanurate containing at least two isocyanate groups blocked with dimethylketoxime and a monomeric polyisocyanate blocked with dimethylketoxime in such amounts as necessary to complete 100% by weight of the mixture, and wherein the unblocked NCO-group content of the monomeric polyisocyanate is less than 0.5% by weight.
摘要:
Powdered, heat-hardenable coating materials with high storage stability and a grain size smaller than 0.25 mm based upon hydroxy-group-containing polyesters with melting points between 40.degree. and 120.degree. C., blocked polyisocyanates and optionally catalysts, wherein the coating material contains polyisocyanates blocked with cyclic amidines of the general formula ##STR1## wherein R=equal or different substituents selected from the group consisting of hydrogen, alkyl-, cycloalkyl-, aralkyl-, and alkyl radicals. A method for the production of the above mentioned coating materials and a process for coating substrates with these materials is also disclosed.
摘要:
This invention relates to blocked isocyanates and to a method for making blocked isocyanates by blocking the isocyanate groups of a polyisocyanate, which may be chain extended, with a cyclic amidine compound of the formula ##STR1## where the R's are the same or different substituents inert to isocyanate groups.
摘要:
The disclosure is of a grass-cutting and air-impelling means for a rotary scythe lawn mower comprising at least one rotary cutter body below a coaxial disc furnished with upstanding radial vanes and air suction slots or openings immediately at the rear of the vanes.