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11.发明授权公开(公告)号：US10138158B2
公开(公告)日：2018-11-27
申请号：US15455163
申请日：2017-03-10
Applicant: Guardian Industries Corp.
Inventor： Guowen Ding , Guizhen Zhang , Daniel Schweigert , Daniel Lee , Scott Jewhurst , Cesar Clavero , Minh Le , Brent Boyce
Abstract: A coated article includes a low emissivity (low-E) coating having at least one infrared (IR) reflecting layer of a material such as silver, gold, or the like, and a plurality of high refractive index dielectric layers of or including a nitride of Zr and Al. In certain example embodiments, the high refractive index dielectric layers of or including a nitride of Zr and Al may be amorphous or substantially amorphous so as to allow the low-E coating to better withstand optional heat treatment (HT) such as thermal tempering. In certain example embodiments, the low-E coating may be used in applications such as monolithic or insulating glass (IG) window unit, vehicle windows, of the like.
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公开(公告)号：US09499437B2
公开(公告)日：2016-11-22
申请号：US14690557
申请日：2015-04-20
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Francis Wuillaume , Brent Boyce
CPC classification number: C03C17/3607 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/78 , C03C2218/322 , Y10T428/12549 , Y10T428/265 , Y10T428/31678
Abstract: A coated article is provided so as to include a low-E (low emissivity) coating having an infrared (IR) reflecting layer(s) of or including a material such as silver (Ag), which is provided between a pair of contact layers. The low-E coating includes an overcoat having at least one layer of or including zirconium oxide and/or a substantially metallic layer. The overcoat has been found to improve the durability of the coating without significantly sacrificing desired optical characteristics. Such coated articles may be used in the context of windows.
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公开(公告)号：US09321676B2
公开(公告)日：2016-04-26
申请号：US14702284
申请日：2015-05-01
Applicant: Intermolecular Inc. , Guardian Industries Corp.
Inventor： Mohd Fadzli Anwar Hassan , Brent Boyce , Guowen Ding , Muhammad Imran , Minh Huu Le , Zhi-Wen Wen Sun , Yu Wang , Yongli Xu
CPC classification number: C03C17/23 , C03C17/06 , C03C17/34 , C03C17/36 , C03C17/3626 , C03C17/3644 , C03C17/366 , C03C2217/211 , C03C2217/24 , C30B23/00 , C30B25/00 , G02B5/208 , G02B5/285 , Y10T428/24868 , Y10T428/24975 , Y10T428/265
Abstract: A bi-layer seed layer can exhibit good seed property for an infrared reflective layer, together with improved thermal stability. The bi-layer seed layer can include a thin zinc oxide layer having a desired crystallographic orientation for a silver infrared reflective layer disposed on a bottom layer having a desired thermal stability. The thermal stable layer can include aluminum, magnesium, or bismuth doped tin oxide (AlSnO, MgSnO, or BiSnO), which can have better thermal stability than zinc oxide but poorer lattice matching for serving as a seed layer template for silver (111).
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14.发明授权Coated article with low-E coating including tin oxide inclusive layer(s) with additional metal(s) 有权具有低E涂层的涂层制品，包括含有金属的附加金属氧化锡层，公开(公告)号：US09028983B2
公开(公告)日：2015-05-12
申请号：US14538869
申请日：2014-11-12
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Brent Boyce , Jean-Marc Lemmer , Marcus Frank , Yongli Xu
CPC classification number: C03C17/3618 , C03C17/3417 , C03C17/3429 , C03C17/3435 , C03C17/3626 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C17/3689 , C03C2217/211 , C03C2217/216 , C03C2217/219 , C03C2217/23 , C03C2217/256
Abstract: A coated article includes a coating, such as a low emissivity (low-E) coating, supported by a substrate (e.g., glass substrate). The coating includes at least one dielectric layer including tin oxide that is doped with another metal(s). The coating may also include one or more infrared (IR) reflecting layer(s) of or including material such as silver or the like, for reflecting at least some IR radiation. In certain example embodiments, the coated article may be heat treated (e.g., thermally tempered, heat bent and/or heat strengthened). Coated articles according to certain example embodiments of this invention may be used in the context of windows, including monolithic windows for buildings, IG windows for buildings, etc.
Abstract translation: 涂覆制品包括由衬底（例如玻璃衬底）支撑的涂层，例如低发射率（低E）涂层。 该涂层包括至少一个包含掺杂有另一种金属的氧化锡的电介质层。 涂层还可以包括用于反射至少一些IR辐射的一种或多种红外（IR）反射层或者包括诸如银等的材料。 在某些示例性实施例中，涂覆的制品可以被热处理（例如热回火，热弯曲和/或热加强）。 根据本发明的某些示例性实施例的涂层制品可以在窗户的上下文中使用，包括建筑物的整体窗口，建筑物的IG窗口等。
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公开(公告)号：US08808864B2
公开(公告)日：2014-08-19
申请号：US13790052
申请日：2013-03-08
Applicant: Guardian Industries Corp.
Inventor： Jingyu Lao , Philip J. Lingle , Brent Boyce , Bernd Disteldorf , Richard Blacker
CPC classification number: E06B9/24 , B32B17/06 , B32B2255/20 , B32B2255/28 , B32B2307/304 , B32B2307/412 , B32B2307/416 , C03C17/2453 , C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3634 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/21 , C03C2217/211 , C03C2217/212 , C03C2217/216 , C03C2217/219 , C03C2217/256 , C03C2217/281 , C03C2217/70 , C03C2218/154 , C03C2218/156 , C23C14/0652 , C23C14/086 , E06B3/6715 , E06B2009/2417 , Y10T428/265
Abstract: An IG window unit includes a coating supported by a glass substrate. The coating includes at least the following on the glass substrate moving from the glass substrate outwardly: at least one dielectric layer; a layer comprising zinc oxide; an infrared (IR) reflecting layer comprising silver; a layer comprising an oxide of Ni and/or Cr; an overcoat comprising a layer comprising tin oxide located over the oxide of Ni and/or Cr and a layer comprising silicon nitride.
Abstract translation: IG窗单元包括由玻璃基板支撑的涂层。 所述涂层至少在玻璃基板上至少包括从玻璃基板向外移动的至少一个：至少一个电介质层; 包含氧化锌的层; 包含银的红外（IR）反射层; 包含Ni和/或Cr的氧化物的层; 包括包含位于Ni和/或Cr的氧化物上的氧化锡的层的外涂层和包含氮化硅的层。
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Patent Agency Ranking
公开(公告)号：US09816316B2
公开(公告)日：2017-11-14
申请号：US15213476
申请日：2016-07-19
Applicant: Guardian Industries Corp.
Inventor： Jingyu Lao , Philip J. Lingle , Brent Boyce , Bernd Disteldorf , Richard Blacker
IPC: B32B15/04 , B32B17/06 , E06B9/24 , C03C17/36 , E06B3/67 , C03C17/245 , C03C17/34 , C23C14/06 , C23C14/08
CPC classification number: E06B9/24 , B32B17/06 , B32B2255/20 , B32B2255/28 , B32B2307/304 , B32B2307/412 , B32B2307/416 , C03C17/2453 , C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3634 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/21 , C03C2217/211 , C03C2217/212 , C03C2217/216 , C03C2217/219 , C03C2217/256 , C03C2217/281 , C03C2217/70 , C03C2218/154 , C03C2218/156 , C23C14/0652 , C23C14/086 , E06B3/6715 , E06B2009/2417 , Y10T428/265
Abstract: A low-E coating supported by a glass substrate, the coating from the glass substrate outwardly including at least the following layers: a dielectric layer of or including silicon nitride; a high index layer having a refractive index of at least 2.1; another dielectric layer of or including silicon nitride; a layer comprising zinc oxide; an infrared (IR) reflecting layer, wherein the coating includes only one IR reflecting layer; and an overcoat including (i) a layer comprising tin oxide and (ii) a layer comprising silicon nitride located over and contacting the layer comprising tin oxide. An IG unit including the coating may have a visible transmission of at least 70%.
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公开(公告)号：US09776915B2
公开(公告)日：2017-10-03
申请号：US15409595
申请日：2017-01-19
Applicant: Guardian Industries Corp.
Inventor： Francis Wuillaume , Brent Boyce
CPC classification number: C03C17/3681 , C03C17/36 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/366 , C03C2217/211 , C03C2217/212 , C03C2217/216 , C03C2217/228 , C03C2217/281 , C03C2218/154 , E06B3/67 , E06B9/24 , E06B2009/2417 , Y10T428/2495
Abstract: An insulating glass (IG) window unit includes first and second substrates, and a low-emissivity (low-E) coating supported by one of the substrates. The low-E coating has two silver based infrared (IR) reflecting layers and allows the IG window unit to realize an increased SHGC to U-value ratio, and an increased thickness ratio of an upper silver based layer of the coating to a bottom silver based layer of the coating. The low-E coating is designed to have a low film-side reflectance, so that for example when the low-E coating is used on surface number three of an IG window unit the IG window unit can realize reduced visible reflectance as viewed from the outside of the building on which the IG window unit is mounted or is to be mounted.
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公开(公告)号：US09448345B2
公开(公告)日：2016-09-20
申请号：US13725126
申请日：2012-12-21
Applicant: Intermolecular Inc. , Guardian Industries Corp.
Inventor： Mohd Fadzli Anwar Hassan , Brent Boyce , Guowen Ding , Minh Huu Le , Zhi-Wen Wen Sun , Yu Wang , Yongli Xu
CPC classification number: G02B5/208 , C03C17/36 , C03C17/3644 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/40 , G02B5/282
Abstract: A method for making low emissivity panels, including control the composition of a barrier layer formed on a thin conductive silver layer. The barrier structure can include an alloy of a first element having high oxygen affinity with a second element having low oxygen affinity. The first element can include Ta, Nb, Zr, Hf, Mn, Y, Si, and Ti, and the second element can include Ru, Ni, Co, Mo, and W, which can have low oxygen affinity property. The alloy barrier layer can reduce optical absorption in the visible range, can provide color-neutral product, and can improve adhesion to the silver layer.
Abstract translation: 一种制造低发射率面板的方法，包括控制形成在薄导电银层上的阻挡层的组成。 阻挡结构可以包括具有高氧亲和力的第一元素与具有低氧亲合力的第二元素的合金。 第一元素可以包括Ta，Nb，Zr，Hf，Mn，Y，Si和Ti，第二元素可以包括可以具有低氧亲和性的Ru，Ni，Co，Mo和W。 合金阻挡层可以减少可见光范围内的光吸收，可以提供颜色中性的产品，并可以提高对银层的粘附性。
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公开(公告)号：US09302936B2
公开(公告)日：2016-04-05
申请号：US14592970
申请日：2015-01-09
Applicant: Guardian Industries Corp.
Inventor： Francis Wuillaume , Brent Boyce
CPC classification number: C03C17/3681 , C03C17/36 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/366 , C03C2217/211 , C03C2217/212 , C03C2217/216 , C03C2217/228 , C03C2217/281 , C03C2218/154 , E06B3/67 , E06B9/24 , E06B2009/2417 , Y10T428/2495
Abstract: An insulating glass (IG) window unit includes first and second substrates, and a low-emissivity (low-E) coating supported by one of the substrates. The low-E coating has two silver based infrared (IR) reflecting layers and allows the IG window unit to realize an increased SHGC to U-value ratio, and an increased thickness ratio of an upper silver based layer of the coating to a bottom silver based layer of the coating. The low-E coating is designed to have a low film-side reflectance, so that for example when the low-E coating is used on surface number three of an IG window unit the IG window unit can realize reduced visible reflectance as viewed from the outside of the building on which the IG window unit is mounted or is to be mounted.
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公开(公告)号：US08945714B2
公开(公告)日：2015-02-03
申请号：US14460375
申请日：2014-08-15
Applicant: Guardian Industries Corp.
Inventor： Jingyu Lao , Philip J. Lingle , Brent Boyce , Bernd Disteldorft , Richard Blacker
CPC classification number: E06B9/24 , B32B17/06 , B32B2255/20 , B32B2255/28 , B32B2307/304 , B32B2307/412 , B32B2307/416 , C03C17/2453 , C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3634 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/21 , C03C2217/211 , C03C2217/212 , C03C2217/216 , C03C2217/219 , C03C2217/256 , C03C2217/281 , C03C2217/70 , C03C2218/154 , C03C2218/156 , C23C14/0652 , C23C14/086 , E06B3/6715 , E06B2009/2417 , Y10T428/265
Abstract: Example embodiments of this invention relate to a coated article including an infrared (IR) reflecting layer of a material such as silver or the like, for use in an insulating glass (IG) window unit for example. In certain example embodiments, the coating is a single-silver type coating, and includes an overcoat including an uppermost layer of or including silicon nitride and a layer of or including tin oxide immediately under and contacting the silicon nitride based overcoat. In certain example embodiments, the thicknesses of the silicon nitride based overcoat and the tin oxide based layer are balanced (e.g., substantially equal, or equal plus/minus about 10%). It has surprisingly been found that such balancing results in an improvement in thermal cycling performance and improved mechanical durability. In certain example embodiments, the coating may realize surprisingly good substantially neutral film side reflective coloration, and may achieve an improved visible transmission, SHGC ratio and low U-values. Moreover, in certain example embodiments, stress in the overcoat of the coating may be reduced by reducing nitrogen gas flow (N2 ml/kW) and cathode power during a sputter-deposition process, thereby further improving thermal cycling performance.
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