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公开(公告)号：US09751801B2
公开(公告)日：2017-09-05
申请号：US13738163
申请日：2013-01-10
Applicant: Guardian Industries Corp.
Inventor： Marcus Frank , Anton Dietrich , Greg Miller , Richard Blacker , Muhammad Imran , Jean-Marc Lemmer
CPC classification number: C03C17/3626 , C03C17/06 , C03C17/36 , C03C17/3639 , C03C17/3652 , C03C17/366 , Y10T156/10 , Y10T428/12549 , Y10T428/12597
Abstract: Certain example embodiments relate to a coated article including at least one infrared (IR) reflecting layer of a material such as silver or the like in a low-E coating, and methods of making the same. In certain cases, at least one layer of the coating is of or includes nickel and/or titanium (e.g., NixTiyOz). The provision of a layer including nickel titanium and/or an oxide thereof may permit a layer to be used that has good adhesion to the IR reflecting layer, and reduced absorption of visible light (resulting in a coated article with a higher visible transmission). When a layer including nickel titanium oxide is provided directly over and/or under the IR reflecting layer (e.g., as a barrier layer), this may result in improved chemical and mechanical durability. Thus, visible transmission may be improved if desired, without compromising durability; or, durability may simply be increased.
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公开(公告)号：US09434643B2
公开(公告)日：2016-09-06
申请号：US14794897
申请日：2015-07-09
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Bernd Disteldorf , Marcus Frank , Richard Blacker
CPC classification number: C03C17/3642 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/22 , C03C2217/256 , C03C2217/261 , C03C2217/281 , C03C2217/73 , C03C2218/154 , C22C19/055 , C22C19/056 , C22C19/057 , E06B3/66 , E06B3/6612 , E06B3/663 , E06B3/67 , E06B3/673 , E06B9/24 , E06B2009/2417 , G02B5/0808 , G02B5/208 , Y10T29/49826 , Y10T428/12549
Abstract: Certain example embodiments relate to Ni-inclusive ternary alloy being provided as a barrier layer for protecting an IR reflecting layer comprising silver or the like. The provision of a barrier layer comprising nickel, chromium, and/or molybdenum and/or oxides thereof may improve corrosion resistance, as well as chemical and mechanical durability. In certain examples, more than one barrier layer may be used on at least one side of the layer comprising silver. In still further examples, a NixCryMoz-based layer may be used as the functional layer, rather than or in addition to as a barrier layer, in a coating.
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公开(公告)号：US09403345B2
公开(公告)日：2016-08-02
申请号：US14854282
申请日：2015-09-15
Applicant: Guardian Industries Corp.
Inventor： Jingyu Lao , Philip J. Lingle , Brent Boyce , Bernd Disteldorf , Richard Blacker
CPC classification number: E06B9/24 , B32B17/06 , B32B2255/20 , B32B2255/28 , B32B2307/304 , B32B2307/412 , B32B2307/416 , C03C17/2453 , C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3634 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/21 , C03C2217/211 , C03C2217/212 , C03C2217/216 , C03C2217/219 , C03C2217/256 , C03C2217/281 , C03C2217/70 , C03C2218/154 , C03C2218/156 , C23C14/0652 , C23C14/086 , E06B3/6715 , E06B2009/2417 , Y10T428/265
Abstract: An IG window unit includes a coating supported by a glass substrate. The coating includes at least the following: a dielectric layer comprising silicon nitride; a dielectric layer comprising an oxide of titanium; another dielectric layer; a layer comprising zinc oxide; an infrared (IR) reflecting layer comprising silver on the glass substrate, located over and directly contacting the layer comprising zinc oxide, wherein the coating includes only one IR reflecting layer; and an overcoat comprising (i) a layer comprising tin oxide and (ii) a layer comprising silicon nitride located over and contacting the layer comprising tin oxide. The IG unit may have an SHGC value of at least 0.65, a visible transmission of at least 70%, and/or an Energy Rating of at least 25.
Abstract translation: IG窗单元包括由玻璃基板支撑的涂层。 该涂层至少包括以下：包含氮化硅的介电层; 包含钛的氧化物的介电层; 另一介电层; 包含氧化锌的层; 在玻璃基板上包含银的红外线（IR）反射层，位于包含氧化锌的层之上并直接接触，其中该涂层仅包含一个IR反射层; 和外涂层，其包含（i）包含氧化锡的层和（ii）位于其上并与包含氧化锡的层接触的包含氮化硅的层。 IG单元可以具有至少0.65的SHGC值，至少70％的可见透射率和/或至少25的能量等级。
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公开(公告)号：US20140287254A1
公开(公告)日：2014-09-25
申请号：US14299341
申请日：2014-06-09
Inventor： Mohd Fadzli Anwar Hassan , Richard Blacker , Guowen Ding , Muhammad Imran , Jingyu Lao , Minh Huu Le , Yiwei Lu , Zhi-Wen Wen Sun
CPC classification number: C03C17/366 , C03C17/2453 , C03C17/36 , C03C17/3618 , C03C17/3642 , C23C14/08 , C23C28/32 , C23C28/345 , H01B3/10
Abstract: A transparent dielectric composition comprising tin, oxygen and one of aluminum or magnesium with preferably higher than 15% by weight of aluminum or magnesium offers improved thermal stability over tin oxide with respect to appearance and optical properties under high temperature processes. For example, upon a heat treatment at temperatures higher than 500 C, changes in color and index of refraction of the present transparent dielectric composition are noticeably less than those of tin oxide films of comparable thickness. The transparent dielectric composition can be used in high transmittance, low emissivity coated panels, providing thermal stability so that there are no significant changes in the coating optical and structural properties, such as visible transmission, IR reflectance, microscopic morphological properties, color appearance, and haze characteristics, of the as-coated and heated treated products.
Abstract translation: 包含锡，氧和铝或镁中的一种优选高于15重量％的铝或镁的透明电介质组合物相对于在高温过程下的外观和光学性质提供了比氧化锡更好的热稳定性。 例如，当在高于500℃的温度下进行热处理时，本发明透明电介质组合物的颜色变化和折射率显着小于具有相当厚度的氧化锡膜的变化。 透明电介质组合物可用于高透光率，低发射率涂层面板，提供热稳定性，使得涂层的光学和结构性能如可见透射率，IR反射率，微观形态特性，颜色外观和 涂层和加热处理产品的雾度特性。
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5.发明申请ANTI-REFLECTION GLASS MADE FROM SOL MADE BY BLENDING TRI-ALKOXYSILANE AND TETRA-ALKOXYSILANE INCLUSIVE SOLS 有权通过混合三烷基硅烷和四烷基铝氧烷包含固体溶胶制成的抗反射玻璃公开(公告)号：US20140272126A1
公开(公告)日：2014-09-18
申请号：US13826288
申请日：2013-03-14
Applicant: GUARDIAN INDUSTRIES CORP.
Inventor： Liang LIANG , Richard Blacker , Nikhil D. Kalyankar , Scott JewHurst
IPC: G02B1/11
CPC classification number: G02B1/111 , C03C17/245 , C03C2217/732 , C03C2218/113
Abstract: Anti-reflection (AR) coating for a glass substrate is prepared by blending at least two different sols to form a coating sol which is used to coat a substrate such as a transparent glass substrate. In certain example embodiments, a method includes forming a first sol formulation including a colloidal solution having a tri-alkoxysilane based binder; forming a second sol formulation including a colloidal solution having a tetra-alkoxysilane based binder; blending the first and second sol formulations to form a coating sol formulation; coating at least a portion of said coating sol formulation onto the glass substrate to form a coating; and heating (e.g., for curing and/or annealing) the glass substrate and the coating thereon. Anti-reflection glasses show improved mechanical strength and higher transmittances (e.g., Tqe % gain).
Abstract translation: 通过混合至少两种不同的溶胶来制备用于玻璃基板的抗反射（AR）涂层，以形成用于涂覆诸如透明玻璃基板的基板的涂层溶胶。 在某些示例性实施方案中，一种方法包括形成包含具有三烷氧基硅烷基粘合剂的胶体溶液的第一溶胶制剂; 形成包含具有四烷氧基硅烷基粘合剂的胶体溶液的第二溶胶制剂; 混合第一和第二溶胶制剂以形成涂料溶胶制剂; 将所述涂料溶胶制剂的至少一部分涂覆到所述玻璃基板上以形成涂层; 以及加热（例如，用于固化和/或退火）玻璃基板和其上的涂层。 抗反射眼镜显示出改进的机械强度和更高的透光率（例如，Tqe％增益）。
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Patent Agency Ranking
6.发明申请ANTI-REFLECTION GLASS MADE FROM AGED SOL INCLUDING MIXTURE OF TRI-ALKOXYSILANE AND TETRA-ALKOXYSILANE 审中-公开抗反射玻璃由含有三羟甲基纤维素和四羧基硅烷的混合物公开(公告)号：US20140272125A1
公开(公告)日：2014-09-18
申请号：US13826011
申请日：2013-03-14
Applicant: GUARDIAN INDUSTRIES CORP
Inventor： Liang LIANG , Richard Blacker , Nikhil D. Kalyankar , Scott Jewhurst
IPC: C09D5/00
CPC classification number: C09D5/006 , C03C17/002 , C03C17/007 , C03C17/30 , C03C2217/213 , C03C2217/425 , C03C2217/478 , C03C2217/732 , C03C2217/78 , C03C2218/113
Abstract: A method of making a coated article including an anti-reflection coating on a glass substrate, the method comprising: mixing at least a tri-alkoxysilane based binder and a tetra-alkoxysilane based binder with at least silica based nanoparticles and a solvent in forming a coating sol formulation; aging the coating sol formulation at least about two weeks so as to provide an aged coating sol formulation; coating at least a portion of said aged coating sol formulation onto the glass substrate to form a coating; and heating said glass substrate and said coating. Anti-reflection (AR) glasses show improved mechanical strength and higher transmittances (e.g., Tqe % gain).
Abstract translation: 一种制造包括在玻璃基板上的抗反射涂层的涂覆制品的方法，所述方法包括：至少将三烷氧基硅烷基粘合剂和四烷氧基硅烷基粘合剂与至少二氧化硅基纳米颗粒和溶剂混合形成 涂料溶胶配方; 使涂料溶胶制剂老化至少约两周，以提供老化的涂料溶胶制剂; 将所述老化涂层溶胶制剂的至少一部分涂布到玻璃基板上以形成涂层; 并加热所述玻璃基底和所述涂层。 抗反射（AR）眼镜显示出改善的机械强度和更高的透射率（例如，Tqe％增益）。
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7.发明申请公开(公告)号：US20140268349A1
公开(公告)日：2014-09-18
申请号：US13803584
申请日：2013-03-14
Applicant: INTERMOLECULAR INC. , GUARDIAN INDUSTRIES CORP.
Inventor： Nikhil Kalyankar , Richard Blacker , Scott Jewhurst , James Mulligan
IPC: G02B1/11
CPC classification number: G02B5/0294 , G02B1/111 , G02B1/118 , G02B5/0242 , G02B2207/101 , G02B2207/107 , G02B2207/109
Abstract: Embodiments provided herein describe optical coatings, panels having optical coatings thereon, and methods for forming optical coatings and panels. A transparent substrate is provided. An optical coating is formed on the transparent substrate. The optical coating includes a plurality of plate-shaped silicon dioxide particles.
Abstract translation: 本文提供的实施例描述了光学涂层，其上具有光学涂层的面板以及用于形成光学涂层和面板的方法。 提供透明基板。 在透明基板上形成光学涂层。 光学涂层包括多个板状二氧化硅颗粒。
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8.发明授权Coated article with low-E coating having zinc stannate based layer between IR reflecting layers for reduced mottling and corresponding methods 有权具有低E涂层的涂层制品，其具有在用于减少斑驳的IR反射层之间的锡酸锡基层和相应的方法公开(公告)号：US08440310B2
公开(公告)日：2013-05-14
申请号：US13623324
申请日：2012-09-20
Applicant: Guardian Industries Corp.
Inventor： Jose Ferreira , Pierrot Pallotta , Richard Blacker , Muhammad Imran
IPC: B32B17/06
CPC classification number: B60J1/00 , B32B17/10036 , B32B17/10174 , B32B17/10761 , C03B23/023 , C03B23/025 , C03B23/0302 , C03B40/033 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/366 , C03C17/3681 , Y10T428/24628
Abstract: A coated article is provided which may be heat treated (e.g., thermally tempered) and/or heat bent in certain example instances. In certain example embodiments, a zinc stannate based layer is provided between a tin oxide based layer and a silicon nitride based layer, and this has been found to significantly reduce undesirable mottling damage upon heat treatment/bending. This results in significantly improved bendability of the coated article in applications such as vehicle windshields and the like.
Abstract translation: 提供了一种涂覆制品，其可以在某些示例情况下进行热处理（例如热回火）和/或热弯曲。 在某些示例性实施方案中，基于锡氧化物的层和基于氮化硅的层提供了基于锡酸锌的层，并且已经发现，这可以显着减少热处理/弯曲时的不希望的斑点损伤。 这导致涂覆制品在车辆挡风玻璃等应用中的弯曲性显着提高。
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公开(公告)号：US09802860B2
公开(公告)日：2017-10-31
申请号：US14029900
申请日：2013-09-18
Applicant: Guardian Industries Corp.
Inventor： Marcus Frank , Anton Dietrich , Greg Miller , Richard Blacker , Muhammad Imran , Jean-Marc Lemmer
CPC classification number: C03C17/3626 , C03C17/06 , C03C17/36 , C03C17/3639 , C03C17/3652 , C03C17/366 , Y10T156/10 , Y10T428/12549 , Y10T428/12597
Abstract: Certain example embodiments relate to a coated article including at least one infrared (IR) reflecting layer of a material such as silver or the like in a low-E coating, and methods of making the same. In certain cases, at least one layer of the coating is of or includes nickel and/or titanium (e.g., NixTiyOz). The provision of a layer including nickel titanium and/or an oxide thereof may permit a layer to be used that has good adhesion to the IR reflecting layer, and reduced absorption of visible light (resulting in a coated article with a higher visible transmission). When a layer including nickel titanium oxide is provided directly over and/or under the IR reflecting layer (e.g., as a barrier layer), this may result in improved chemical and mechanical durability. Thus, visible transmission may be improved if desired, without compromising durability; or, durability may simply be increased.
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公开(公告)号：US09789750B2
公开(公告)日：2017-10-17
申请号：US13862878
申请日：2013-04-15
Applicant: Guardian Industries Corp.
Inventor： Jose Ferreira , Pierrot Pallotta , Richard Blacker , Muhammad Imran
IPC: B60J1/00 , B32B17/10 , C03B23/023 , C03B23/025 , C03B23/03 , C03B40/033 , C03C17/36
CPC classification number: B60J1/00 , B32B17/10036 , B32B17/10174 , B32B17/10761 , C03B23/023 , C03B23/025 , C03B23/0302 , C03B40/033 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/366 , C03C17/3681 , Y10T428/24628
Abstract: A coated article is provided which may be heat treated (e.g., thermally tempered) and/or heat bent in certain example instances. In certain example embodiments, a zinc stannate based layer is provided between a tin oxide based layer and a silicon nitride based layer, and this has been found to significantly reduce undesirable mottling damage upon heat treatment/bending. This results in significantly improved bendability of the coated article in applications such as vehicle windshields and the like.
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