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11.发明授权公开(公告)号：US09127095B2
公开(公告)日：2015-09-08
申请号：US13517038
申请日：2010-12-17
申请人： Diego Brita , Gianni Collina , Daniele Evangelisti , Anna Fait , Benedetta Gaddi , Giampiero Morini , Pietro Baita , Lorella Marturano , Harry Mavridis
发明人： Diego Brita , Gianni Collina , Daniele Evangelisti , Anna Fait , Benedetta Gaddi , Giampiero Morini , Pietro Baita , Lorella Marturano , Harry Mavridis
IPC分类号： C08F4/76 , C08F4/646 , C08F4/649 , C08F110/02 , C08F10/00
CPC分类号： C08F10/00 , C08F110/02 , C08F2410/03 , C08F4/6543 , C08F4/6545 , C08F4/6494 , C08F2/001 , C08F2500/07 , C08F2500/04 , C08F2500/12 , C08F2500/14 , C08F2500/18 , C08F2500/11
摘要： Catalyst component comprising Mg, Ti, and halogen atoms, and is characterized in that (a) the Ti atoms are present in an amount higher than 4% based on the total weight of the said catalyst component, (b) the amount of Mg and Ti atoms is such that the Mg/Ti molar ratio is higher than 2 and (c) by a X-ray diffraction spectrum, in which, in the range of 2θ diffraction angles between 47° and 52°, at least two diffraction lines are present at diffraction angles 2θ of 48.3±0.2°, and 50.0±0.2°, the most intense diffraction lines being the one at 2θ of 50.0±0.2°, the intensity of the other diffraction line being equal to or lower than the intensity of the most intense diffraction line.
摘要翻译： 包含Mg，Ti和卤素原子的催化剂组分，其特征在于（a）Ti原子以基于所述催化剂组分的总重量高于4％的量存在，（b）Mg和 Ti原子使得Mg / Ti摩尔比高于2，（c）通过X射线衍射光谱，其中在2θ的范围内; 衍射角在47°和52°之间，至少两条衍射线存在于衍射角2°处; 分别为48.3±0.2°和50.0±0.2°，最强烈的衍射线为2°; 为50.0±0.2°，其他衍射线的强度等于或低于最强衍射线的强度。
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公开(公告)号：US08062989B2
公开(公告)日：2011-11-22
申请号：US12308623
申请日：2007-06-01
申请人： Giampiero Morini , Antonio Cristofori , Benedetta Gaddi , Dario Liguori , Joachim T. M. Pater , Gianni Vitale
发明人： Giampiero Morini , Antonio Cristofori , Benedetta Gaddi , Dario Liguori , Joachim T. M. Pater , Gianni Vitale
IPC分类号： C08F4/64
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/651 , C08F2500/18 , C08F2500/12 , C08F210/06 , C08F210/08
摘要： Catalyst precursors comprising Mg, Cl, Ti, and OR groups that are in molar ratios defined by the formula MgClnTip(OR)(2−n)+4p in which n is from 0.3 to less than 1.7, p is lower than 0.6, the molar ratio (OR)/Cl is lower than 4 and R is C1-C15 hydrocarbon groups. The said precursor, just upon activation with organo-Al compounds, are able to advantageously polymerize ethylene and alpha olefins, and that upon reaction with halogenating compounds generate in high yields catalyst components with high polymerization activity particularly in the polymerization of propylene also in combination with 1,3-diethers.
摘要翻译： 包含Mg，Cl，Ti和OR基团的催化剂前体，其摩尔比由式MgClnTip（OR）（2-n）+ 4p定义，其中n为0.3至小于1.7，p低于0.6， 摩尔比（OR）/ Cl低于4，R为C1-C15烃基。 所述前体刚好在有机铝化合物活化后能够有利地聚合乙烯和α-烯烃，并且当与卤化化合物反应时，产生高产率的催化剂组分，具有高聚合活性，特别是在丙烯的聚合中也与 1,3-二醚。
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公开(公告)号：US20100160154A1
公开(公告)日：2010-06-24
申请号：US12308623
申请日：2007-06-01
申请人： Giampiero Morini , Antonio Cristofori , Benedetta Gaddi , Dario Liguori , Joachim T. M. Pater , Gianni Vitale
发明人： Giampiero Morini , Antonio Cristofori , Benedetta Gaddi , Dario Liguori , Joachim T. M. Pater , Gianni Vitale
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/651 , C08F2500/18 , C08F2500/12 , C08F210/06 , C08F210/08
摘要： Catalyst precursors comprising Mg, Cl, Ti, and OR groups that are in molar ratios defined by the formula MgClnTip(OR)(2-n)+4p in which n is from 0.3 to less than 1.7, p is lower than 0.6, the molar ratio (OR)/Cl is lower than 4 and R is C1-C15 hydrocarbon groups. The said precursor, just upon activation with organo-Al compounds, are able to advantageously polymerize ethylene and alpha olefins, and that upon reaction with halogenating compounds generate in high yields catalyst components with high polymerization activity particularly in the polymerization of propylene also in combination with 1,3-diethers.
摘要翻译： 包含Mg，Cl，Ti和OR基团的催化剂前体，其摩尔比由式MgClnTip（OR）（2-n）+ 4p定义，其中n为0.3至小于1.7，p低于0.6， 摩尔比（OR）/ Cl低于4，R为C1-C15烃基。 所述前体刚好在有机铝化合物活化后能够有利地聚合乙烯和α-烯烃，并且当与卤化化合物反应时，产生高产率的催化剂组分，具有高聚合活性，特别是在丙烯的聚合中也与 1,3-二醚。
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公开(公告)号：US08829113B2
公开(公告)日：2014-09-09
申请号：US13877562
申请日：2011-10-12
申请人： Benedetta Gaddi , Marco Ciarafoni , Mara Destro , Ofelia Fusco , Paola Massari , Ines Mingozzi
发明人： Benedetta Gaddi , Marco Ciarafoni , Mara Destro , Ofelia Fusco , Paola Massari , Ines Mingozzi
IPC分类号： C08F8/00 , C08L23/06 , C08L23/10 , C08L23/12 , C08L23/14 , C08F210/06 , C08L23/16 , C08L23/08
CPC分类号： C08L23/12 , C08F210/06 , C08L23/0815 , C08L23/14 , C08L23/16 , C08L2205/02 , C08L2666/06 , C08F2/001 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F4/651
摘要： Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 μgC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.
摘要翻译： 包含（重量％）的聚丙烯组合物的汽车内部元件：A）60％至90％的丙烯均聚物，其具有：i）多分散指数（P.I.）值为3.5至10.0; ii）25℃不溶于二甲苯的馏分，高于90％; 和iii）50至200g / 10min的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）; B）从10％到40％; 的丙烯与30％至60％的乙烯衍生单元的共聚物; 所述组合物具有在25℃下可溶于二甲苯的级分的特性粘度，为2.5至4.0dl / g; 根据VDA 227（C-emission）测量的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）为15至100g / 10分钟，并且所有三个碳排放值 ）低于30.0μgC/ g; 其中在前反应器丙烯组合物中测量碳排放值。
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公开(公告)号：US20130211011A1
公开(公告)日：2013-08-15
申请号：US13877562
申请日：2011-10-12
申请人： Benedetta Gaddi , Marco Ciarafoni , Mara Destro , Ofelia Fusco , Paola Massari , Ines Mingozzi
发明人： Benedetta Gaddi , Marco Ciarafoni , Mara Destro , Ofelia Fusco , Paola Massari , Ines Mingozzi
CPC分类号： C08L23/12 , C08F210/06 , C08L23/0815 , C08L23/14 , C08L23/16 , C08L2205/02 , C08L2666/06 , C08F2/001 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F4/651
摘要： Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 μgC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.
摘要翻译： 包含（重量％）的聚丙烯组合物的汽车内部元件：A）60％至90％的丙烯均聚物，其具有：i）多分散指数（P.I.）值为3.5至10.0; ii）25℃不溶于二甲苯的馏分，高于90％; 和iii）50至200g / 10min的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）; B）从10％到40％; 的丙烯与30％至60％的乙烯衍生单元的共聚物; 所述组合物具有在25℃下可溶于二甲苯的级分的特性粘度，为2.5至4.0dl / g; 根据VDA 227（C-emission）测量的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg负荷）为15至100g / 10分钟，并且所有三个碳排放值 ）低于30.0ug / g; 其中在前反应器丙烯组合物中测量碳排放值。
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16.发明申请公开(公告)号：US20140046011A1
公开(公告)日：2014-02-13
申请号：US14112199
申请日：2012-04-13
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F10/00 , C08F110/06 , C08F4/022 , C08F4/6545
摘要： Process for the preparation of solid particles of a magnesium-chloride alcohol adduct comprising (a) forming an emulsion between a MgCl2 alcohol adduct in molten form and a liquid phase which is immiscible with the said adduct in the presence of a polyalkyl-methacrylate used as a solution having viscosity ranging from 100 to 5000 mm2/s and (b) rapidly cooling the emulsion to solidify the disperse phase and collecting the solid adduct particles.
摘要翻译： 用于制备氯化镁醇加合物的固体颗粒的方法，其包括（a）在熔融形式的MgCl 2醇加合物与在所述加合物中不混溶的液相之间形成乳液，所述液相在聚甲基丙烯酸烷基酯存在下用作 粘度范围为100-5000mm 2 / s的溶液和（b）快速冷却乳液以固化分散相并收集固体加合物颗粒。
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17.发明申请公开(公告)号：US20130197172A1
公开(公告)日：2013-08-01
申请号：US13876806
申请日：2011-09-29
IPC分类号： C08F4/10
CPC分类号： C08F4/10 , C08F10/00 , C08F10/06 , C08F110/06 , C08F2500/24 , C08F4/6548 , C08F4/651 , C08F4/6543 , C08F4/6574
摘要： Adducts comprising a MgCl2, an alcohol ROH in which R is a Cl—ClO hydrocarbon group, present in a molar ratio with MgCl2 ranging from 0.5 to 5 and less than 15% wt, based on the total weight of the adduct, of a metal salt of an aliphatic carboxylic acid having from 8 to 22 carbon atoms.
摘要翻译： 以MgCl 2，其中R为Cl-ClO烃基的醇ROH的加合物与MgCl 2的摩尔比为0.5-5，小于15重量％，基于加合物的总重量，金属 具有8至22个碳原子的脂族羧酸盐。
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公开(公告)号：US09862781B2
公开(公告)日：2018-01-09
申请号：US14236486
申请日：2012-08-01
CPC分类号： C08F4/6494 , C08F10/00 , C08F4/6545 , C08F4/651 , C08F110/06 , C08F2500/17
摘要： Solid adducts comprising MgCl2 and an alcohol ROH in which R is a C1-C20 hydrocarbon group, in which the amount of alcohol ranges from higher than 42% to 60% by weight and the porosity determined with Hg method due to pores up to 1 μm and expressed in cm3/g, is such that the value of its ratio with the amount of alcohol in percentage falls above the straight line defined by the equation y=−0.0158x+1.03 in which y is the porosity of the adduct and x is the alcohol percentage by weight.
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19.发明授权Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 有权二氯化镁 - 醇加合物和由其获得的催化剂组分公开(公告)号：US08940653B2
公开(公告)日：2015-01-27
申请号：US13876806
申请日：2011-09-29
IPC分类号： B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F2/00 , C08F4/10 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F4/10 , C08F10/00 , C08F10/06 , C08F110/06 , C08F2500/24 , C08F4/6548 , C08F4/651 , C08F4/6543 , C08F4/6574
摘要： Adducts comprising a MgCl2, an alcohol ROH in which R is a C1-C10 hydrocarbon group, present in a molar ratio with MgCl2 ranging from 0.5 to 5 and less than 15% wt, based on the total weight of the adduct, of a metal salt of an aliphatic carboxylic acid having from 8 to 22 carbon atoms.
摘要翻译： 与MgCl 2，醇ROH（其中R为C1-C10烃基）的加合物与MgCl 2的摩尔比为0.5-5且小于15重量％，基于加合物的总重量，金属 具有8至22个碳原子的脂族羧酸盐。
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公开(公告)号：US20120329963A1
公开(公告)日：2012-12-27
申请号：US13582230
申请日：2011-03-01
申请人： Diego Brita , Gianni Collina , Daniele Evangelisti , Benedetta Gaddi , Maria Carbonara , Paolo Vincenzi
发明人： Diego Brita , Gianni Collina , Daniele Evangelisti , Benedetta Gaddi , Maria Carbonara , Paolo Vincenzi
CPC分类号： C08F10/00 , C08F110/02 , C08F4/022 , C08F4/6543 , C08F2500/12 , C08F2500/18 , C08F4/651
摘要： The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.
摘要翻译： 本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物的聚合的催化剂组分，其中R是具有1-12个碳原子的烷基，环烷基或芳基，包括Ti，Mg，卤素和属于 1,2-二醚作为内电子给体化合物。 本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。
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