Process for the Preparation of Polymer of 1-Butene
    2.
    发明申请
    Process for the Preparation of Polymer of 1-Butene 有权
    1-丁烯聚合物的制备方法

    公开(公告)号:US20120041161A1

    公开(公告)日:2012-02-16

    申请号:US13262918

    申请日:2010-03-31

    Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefms of formula CH2═CHZ wherein Z is a C3-C20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefms under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl2 (b) an alkylaluminum co catalyst; and (c) a compound of formula (I) as external donor Wherein: R1, R2, R3 and R4, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R1, R2, R3 and R4 can be joined to form a C5-C20, saturated or unsaturated ring.

    Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法,其中α-烯烃选自式为CH2 = CHZ的乙烯,丙烯或α-烯烃,其中Z为C 3 -C 20烷基, 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下,包括:(a)固体组分,其包含Ti化合物和负载在MgCl 2上的内电子给体化合物(b)烷基铝助催化剂 ; 和(c)作为外部给体的式(I)化合物,其中R 1,R 2,R 3和R 4彼此相同或不同,是氢原子或任选含有属于第13-17族的杂原子的C 1 -C 20烃基 的元素周期表; 或两个R 1,R 2,R 3和R 4可以连接形成C 5 -C 20饱和或不饱和环。

    Automotive interior element
    3.
    发明授权
    Automotive interior element 有权
    汽车内饰件

    公开(公告)号:US08829113B2

    公开(公告)日:2014-09-09

    申请号:US13877562

    申请日:2011-10-12

    Abstract: Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 μgC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.

    Abstract translation: 包含(重量%)的聚丙烯组合物的汽车内部元件:A)60%至90%的丙烯均聚物,其具有:i)多分散指数(P.I.)值为3.5至10.0; ii)25℃不溶于二甲苯的馏分,高于90%; 和iii)50至200g / 10min的MFR L(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg负荷); B)从10%到40%; 的丙烯与30%至60%的乙烯衍生单元的共聚物; 所述组合物具有在25℃下可溶于二甲苯的级分的特性粘度,为2.5至4.0dl / g; 根据VDA 227(C-emission)测量的MFR L(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg负荷)为15至100g / 10分钟,并且所有三个碳排放值 )低于30.0μgC/ g; 其中在前反应器丙烯组合物中测量碳排放值。

    Process for the preparation of polymer of 1-butene
    4.
    发明授权
    Process for the preparation of polymer of 1-butene 失效
    1-丁烯聚合物的制备方法

    公开(公告)号:US08598285B2

    公开(公告)日:2013-12-03

    申请号:US13384191

    申请日:2010-07-02

    Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH2═CHZ wherein Z is a C3-C20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor.

    Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法,其中α-烯烃选自式CH 2 = CHZ的乙烯,丙烯或α-烯烃,其中Z为C 3 -C 20烷基,其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下,包括:(a)固体组分,其包含Ti化合物和负载在MgCl 2(b)烷基铝助催化剂上的内电子给体化合物; 和(c)作为外给体的式(I)化合物。

    AUTOMOTIVE INTERIOR ELEMENT
    5.
    发明申请
    AUTOMOTIVE INTERIOR ELEMENT 有权
    汽车内部元件

    公开(公告)号:US20130211011A1

    公开(公告)日:2013-08-15

    申请号:US13877562

    申请日:2011-10-12

    Abstract: Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 μgC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.

    Abstract translation: 包含(重量%)的聚丙烯组合物的汽车内部元件:A)60%至90%的丙烯均聚物,其具有:i)多分散指数(P.I.)值为3.5至10.0; ii)25℃不溶于二甲苯的馏分,高于90%; 和iii)50至200g / 10min的MFR L(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg负荷); B)从10%到40%; 的丙烯与30%至60%的乙烯衍生单元的共聚物; 所述组合物具有在25℃下可溶于二甲苯的级分的特性粘度,为2.5至4.0dl / g; 根据VDA 227(C-emission)测量的MFR L(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg负荷)为15至100g / 10分钟,并且所有三个碳排放值 )低于30.0ug / g; 其中在前反应器丙烯组合物中测量碳排放值。

    Process for the preparation of polymer of 1-butene
    8.
    发明授权
    Process for the preparation of polymer of 1-butene 有权
    1-丁烯聚合物的制备方法

    公开(公告)号:US08227563B2

    公开(公告)日:2012-07-24

    申请号:US13262918

    申请日:2010-03-31

    Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH2═CHZ wherein Z is a C3-C20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor Wherein: R1, R2, R3 and R4, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R1, R2, R3 and R4 can be joined to form a C5-C20, saturated or unsaturated ring.

    Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法,其中α-烯烃选自式为CH2 = CHZ的乙烯,丙烯或α-烯烃,其中Z为C 3 -C 20烷基, 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下,包括:(a)固体组分,其包含Ti化合物和负载在MgCl 2上的内部电子给体化合物(b)烷基铝助催化剂; 和(c)作为外部给体的式(I)化合物,其中R 1,R 2,R 3和R 4彼此相同或不同,是氢原子或任选含有属于第13-17族的杂原子的C 1 -C 20烃基 的元素周期表; 或两个R 1,R 2,R 3和R 4可以连接形成C 5 -C 20饱和或不饱和环。

    PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE
    9.
    发明申请
    PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE 失效
    制备1-BOTENE聚合物的方法

    公开(公告)号:US20120116032A1

    公开(公告)日:2012-05-10

    申请号:US13384191

    申请日:2010-07-02

    Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH2═CHZ wherein Z is a C3-C20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor

    Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法,其中α-烯烃选自式为CH2 = CHZ的乙烯,丙烯或α-烯烃,其中Z为C 3 -C 20烷基, 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下,包括:(a)固体组分,其包含Ti化合物和负载在MgCl 2(b)烷基铝助催化剂上的内电子给体化合物; 和(c)作为外给体的式(I)化合物

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