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公开(公告)号：US09028567B2
公开(公告)日：2015-05-12
申请号：US13381235
申请日：2010-07-03
CPC分类号： C10G29/22 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C10L1/185 , C10L1/1852 , C10L2270/023 , C10L2290/543 , C10L2290/58 , C10L2290/60 , C10L2300/30
摘要： For producing synthetic fuels, an educt mixture containing steam and oxygenates, such as methanol and/or dimethyl ether, is converted to olefins on a catalyst in a first process stage, and this olefin mixture then is divided in a separating means into a stream rich in C1-C4 hydrocarbons and a stream rich in C5+ hydrocarbons. The stream rich in C5+ hydrocarbons is divided into a stream rich in C5 and C6 hydrocarbons and a stream rich in C7+ hydrocarbons, wherein the stream rich in C5 and C6 hydrocarbons is at least partly subjected to an etherification with methanol. The ethers thus obtained are admixed to the gasoline product stream.
摘要翻译： 为了生产合成燃料，含有蒸汽和含氧化合物（例如甲醇和/或二甲醚）的溶出混合物在第一工艺阶段在催化剂上转化为烯烃，然后将该烯烃混合物分成一种分离装置， 在C1-C4烃和富含C5 +烃的物流中。 富含C5 +烃的物流被分为富含C5和C6烃的物流和富含C7 +烃的物流，其中富含C5和C6烃的物流至少部分地经甲醇醚化。 将如此获得的醚与汽油产物流混合。
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公开(公告)号：US08524970B2
公开(公告)日：2013-09-03
申请号：US12599554
申请日：2008-04-29
申请人： Martin Rothaemel , Uwe Fincke , Holger Dropsch , Henning Buchold
发明人： Martin Rothaemel , Uwe Fincke , Holger Dropsch , Henning Buchold
CPC分类号： C10G50/00 , C07C1/20 , C10G3/49 , C10G3/54 , C10G2400/02 , C10G2400/04 , C10L1/06 , C10L1/08 , Y02P30/20 , C07C11/02
摘要： In a process for producing synthetic fuels from an educt mixture containing hydrogen and oxygenates, such as methanol and/or dimethyl ether, the educt mixture is reacted on a catalyst in a first process stage to obtain a hydrocarbon product containing olefins with preferably 2 to 8 carbon atoms. In a second process stage the hydrocarbon product is oligomerized to long-chain olefins, from which gasoline and Diesel products are obtained. The hydrocarbon product obtained in the first process stage is separated into a liquid phase and a gaseous phase. The gaseous phase is supplied to the second process stage. The liquid phase is separated into a mixture rich in C6− hydrocarbons and a mixture containing C7+ hydrocarbons and aromatics. The mixture rich in C6− hydrocarbons is supplied to the second process stage. The mixture containing C7+ hydrocarbons −+ and aromatics can be admixed to the gasoline product for quality improvement.
摘要翻译： 在由含有氢和含氧化合物如甲醇和/或二甲醚的溶出混合物制备合成燃料的方法中，在第一工艺阶段中，将催化剂混合物在催化剂上反应，以获得含有优选2至8个 碳原子。 在第二个工艺阶段，烃产物被低聚化成长链烯烃，从中获得汽油和柴油产品。 将在第一工艺阶段获得的烃产物分离成液相和气相。 气相被供给到第二处理级。 将液相分离成富含C6-烃的混合物和含有C7 +烃和芳族化合物的混合物。 富含C6-烃的混合物供应到第二个工艺阶段。 含有C7 +烃+和芳族化合物的混合物可以与汽油产品混合，以提高质量。
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公开(公告)号：US20120102829A1
公开(公告)日：2012-05-03
申请号：US13381235
申请日：2010-07-03
CPC分类号： C10G29/22 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C10L1/185 , C10L1/1852 , C10L2270/023 , C10L2290/543 , C10L2290/58 , C10L2290/60 , C10L2300/30
摘要： For producing synthetic fuels, an educt mixture containing steam and oxygenates, such as methanol and/or dimethyl ether, is converted to olefins on a catalyst in a first process stage, and this olefin mixture then is divided in a separating means into a stream rich in C1-C4 hydrocarbons and a stream rich in C5+ hydrcarbons. The stream rich in C5+ hydrocarbons is divided into a stream rich in C5 and C6 hydrocarbons and a stream rich in C7+ hydrocarbons, wherein the stream rich in C5 and C6 hydrocarbons is at least partly subjected to an etherification with methanol. The ethers thus obtained are admixed to the gasoline product stream.
摘要翻译： 为了生产合成燃料，含有蒸汽和含氧化合物（例如甲醇和/或二甲醚）的溶出混合物在第一工艺阶段在催化剂上转化为烯烃，然后将该烯烃混合物分成一种分离装置， 在C1-C4烃和富含C5 +氢碳的物流中。 富含C5 +烃的物流被分为富含C5和C6烃的物流和富含C7 +烃的物流，其中富含C5和C6烃的物流至少部分地经甲醇醚化。 将如此获得的醚与汽油产物流混合。
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公开(公告)号：US20110288358A1
公开(公告)日：2011-11-24
申请号：US13139008
申请日：2009-11-25
申请人： Henning Buchold , Harald Koempel , Sven Pohl , Martin Rothaemel , Ulrich Wagner
发明人： Henning Buchold , Harald Koempel , Sven Pohl , Martin Rothaemel , Ulrich Wagner
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/40 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： A process for producing a product containing C3H6 and C2H4 includes simultaneous conversion of MeOH and EtOH in an adiabatic sequentially operated reactor containing a plurality of reaction stages. Each of the plurality of reaction stages of the reactor is provided with a fixed bed of a form-selective catalyst. A gaseous feed stream including MeOH, DME and H2O is charged to at least a first of the reaction stages of the reactor with a temperature in a range of 300 to 600° C. at a pressure in a range of 0.1 to 20 bar[a]. EtOH is fed into at least, one of the reaction stages of the reactor.
摘要翻译： 用于生产含有C 3 H 6和C 2 H 4的产物的方法包括在包含多个反应级的绝热的顺序操作的反应器中同时转化MeOH和EtOH。 反应器的多个反应阶段中的每一个都具有形式选择催化剂的固定床。 将包含MeOH，DME和H 2 O的气态进料流加入到反应器的至少第一个反应阶段，温度范围为300-600℃，压力范围为0.1-20巴[ ]。 将EtOH加入到反应器的至少一个反应级中。
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公开(公告)号：US09085500B2
公开(公告)日：2015-07-21
申请号：US13139008
申请日：2009-11-25
申请人： Henning Buchold , Harald Koempel , Sven Pohl , Martin Rothaemel , Ulrich Wagner
发明人： Henning Buchold , Harald Koempel , Sven Pohl , Martin Rothaemel , Ulrich Wagner
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/40 , Y02P30/42 , C07C11/06 , C07C11/04
摘要： A process for producing a product containing C3H6 and C2H4 includes simultaneous conversion of MeOH and EtOH in an adiabatic sequentially operated reactor containing a plurality of reaction stages. Each of the plurality of reaction stages of the reactor is provided with a fixed bed of a form-selective catalyst. A gaseous feed stream including MeOH, DME and H2O is charged to at least a first of the reaction stages of the reactor with a temperature in a range of 300 to 600° C. at a pressure in a range of 0.1 to 20 bar[a]. EtOH is fed into at least, one of the reaction stages of the reactor.
摘要翻译： 用于生产含有C 3 H 6和C 2 H 4的产物的方法包括在包含多个反应级的绝热的顺序操作的反应器中同时转化MeOH和EtOH。 反应器的多个反应阶段中的每一个都具有形式选择催化剂的固定床。 将包含MeOH，DME和H 2 O的气态进料流加入到反应器的至少第一个反应阶段，温度范围为300-600℃，压力范围为0.1-20巴[ ]。 将EtOH加入到反应器的至少一个反应级中。
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16.发明申请Process and Plant for Producing C2-C4 Olefins from Methanol and/or Dimethyl Ether 有权从甲醇和/或二甲醚生产C2-C4烯烃的工艺和设备公开(公告)号：US20090124841A1
公开(公告)日：2009-05-14
申请号：US12089823
申请日：2006-09-19
CPC分类号： B01D3/143 , C07C1/20 , C07C2529/40 , C10G2300/807 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： In producing C2-C4 olefins, in particular propylene, from an educt mixture containing steam and oxygenates, such as methanol and/or dimethyl ether, the educt mixture is reacted in a reactor on a catalyst to a reaction mixture comprising low-molecular olefins and gasoline hydrocarbons, which in a first separating device is separated into a mixture rich in C5− olefins, a mixture rich in C5+ gasoline hydrocarbons, and an aqueous phase. To increase the yield of propylene the mixture rich in C5+ gasoline hydrocarbons is supplied to a second separating device, in which the aromatics contained in the mixture are separated. The residual stream largely free from aromatics is at least partly recirculated to the reactor.
摘要翻译： 在由含有蒸汽和含氧化合物（例如甲醇和/或二甲醚）的离析混合物生产C 2 -C 4烯烃，特别是丙烯的情况下，将该反应混合物在反应器中在催化剂上反应至包含低分子烯烃和 汽油烃，其在第一分离装置中分离成富含C5-烯烃的混合物，富含C5 +汽油烃的混合物和水相。 为了提高丙烯的收率，将富含C5 +汽油烃的混合物供给第二分离装置，其中混合物中所含的芳烃被分离。 大部分不含芳族化合物的残余物流至少部分地再循环到反应器中。
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公开(公告)号：US07015369B2
公开(公告)日：2006-03-21
申请号：US10296356
申请日：2001-05-22
CPC分类号： C07C11/06 , C07C1/20 , Y02P20/584
摘要： A process for producing propylene from methanol, wherein methanol vapor is reacted on a first catalyst to obtain a first vapor mixture containing dimethyl ether (DME), which is reacted on a form-selective zeolite catalyst disposed as bed in at least two series-connected shaft reactors to produce a product mixture containing propylene.
摘要翻译： 一种从甲醇生产丙烯的方法，其中甲醇蒸汽在第一催化剂上反应，以获得含有二甲醚（DME）的第一蒸气混合物，其在形式选择性沸石催化剂上反应，床形成为至少两个串联连接 轴反应器以产生含有丙烯的产物混合物。
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18.发明授权Device for removing oxygen-containing organic compounds from mixtures of various hydrocarbon compounds 有权用于从各种烃化合物的混合物中除去含氧有机化合物的装置公开(公告)号：US08058498B2
公开(公告)日：2011-11-15
申请号：US11718020
申请日：2004-10-11
IPC分类号： C07C7/08
摘要： Process for removing oxygen-containing organic compounds from mixtures of hydrocarbon compounds, in which a liquid phase (1) containing hydrocarbons and oxygenates is charged to a first column (3), a light fraction is separated as top product (5) by distillation, and that a heavier C4+ fraction is removed from the bottom, the light fraction (5) and a gaseous mixture of hydrocarbons and oxygenates (2) is charged to a second column (7), and separated into a light and a heavy hydrocarbon fraction distillation, and an additional solvent (6) is supplied to the upper part of the second column (7), which dissolves the oxygenates and, the solvent and oxygenates being discharged as bottom product (9) and a hydrocarbon product (8), which is free from oxygenates leaves the top of the column (7). The solvent optionally is wholly or partly regenerated and recirculated to the extractive distillation column.
摘要翻译： 将含有烃和含氧物的液相（1）装入第一塔（3）的烃化合物的混合物中除去含氧有机化合物的方法，通过蒸馏将轻馏分作为顶部产物（5）分离， 并且从底部除去较重的C4 +馏分，将轻馏分（5）和烃和含氧化合物的气体混合物（2）装入第二塔（7）中，并分离成轻馏分和重质烃馏分 ，并且另外的溶剂（6）被供应到第二塔（7）的上部，其溶解含氧化合物，溶剂和氧化物作为底部产物（9）排出，烃产物（8）是 不含氧合物离开柱的顶部（7）。 溶剂任选地完全或部分再生并再循环到萃取蒸馏塔。
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公开(公告)号：US20100305376A1
公开(公告)日：2010-12-02
申请号：US12599554
申请日：2008-04-29
申请人： Martin Rothaemel , Uwe Fincke , Holger Dropsch , Henning Buchold
发明人： Martin Rothaemel , Uwe Fincke , Holger Dropsch , Henning Buchold
CPC分类号： C10G50/00 , C07C1/20 , C10G3/49 , C10G3/54 , C10G2400/02 , C10G2400/04 , C10L1/06 , C10L1/08 , Y02P30/20 , C07C11/02
摘要： In a process for producing synthetic fuels from an educt mixture containing hydrogen and oxygenates, such as methanol and/or dimethyl ether, the educt mixture is reacted on a catalyst in a first process stage to obtain a hydrocarbon product containing olefins with preferably 2 to 8 carbon atoms. In a second process stage the hydrocarbon product is oligomerized to long-chain olefins, from which gasoline and Diesel products are obtained. The hydrocarbon product obtained in the first process stage is separated into a liquid phase and a gaseous phase. The gaseous phase is supplied to the second process stage. The liquid phase is separated into a mixture rich in C6− hydrocarbons and a mixture containing C7+ hydrocarbons and aromatics. The mixture rich in C6− hydrocarbons is supplied to the second process stage. The mixture containing C7+ hydrocarbons −+ and aromatics can be admixed to the gasoline product for quality improvement.
摘要翻译： 在由含有氢和含氧化合物如甲醇和/或二甲醚的溶出混合物制备合成燃料的方法中，在第一工艺阶段中，将催化剂混合物在催化剂上反应，以获得含有优选2至8个 碳原子。 在第二个工艺阶段，烃产物被低聚化成长链烯烃，从中获得汽油和柴油产品。 将在第一工艺阶段获得的烃产物分离成液相和气相。 气相被供给到第二处理级。 将液相分离成富含C6-烃的混合物和含有C7 +烃和芳族化合物的混合物。 富含C6-烃的混合物供应到第二个工艺阶段。 含有C7 +烃+和芳族化合物的混合物可以与汽油产品混合，以提高质量。
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公开(公告)号：US20100206771A1
公开(公告)日：2010-08-19
申请号：US12678566
申请日：2008-09-06
申请人： Martin Rothaemel , Harald Kömpel , H. Bach , W. Liebner
发明人： Martin Rothaemel , Harald Kömpel , H. Bach , W. Liebner
CPC分类号： C07C1/20 , C07C11/02 , C07C2529/40 , C10G2400/20
摘要： For the production of hydrocarbons, in particular C2-C4 olefins, using a combined plant with a steam cracker and at least one reactor for converting an educt mixture which includes steam and at least one oxygenate, the respective intermediate product streams of the steam cracker and of the reactor are at least partly combined. To increase the yield of valuable products, a shape-selective zeolite material is used as catalyst in the reactor for oxygenate conversion and at least a part of the product streams obtained downstream of the combined plant is recirculated to the steam cracker and/or the reactor.
摘要翻译： 为了生产碳氢化合物，特别是C2-C4烯烃，使用具有蒸汽裂化装置的组合装置和用于转化包括蒸汽和至少一种含氧化合物的溶剂混合物的至少一个反应器，蒸汽裂化装置的各个中间产物流和 的反应器至少部分组合。 为了提高有价值产品的产率，在反应器中使用形状选择性沸石材料作为催化剂，用于含氧化合物的转化，并且在组合设备下游获得的至少一部分产物流再循环到蒸汽裂化器和/或反应器 。
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