摘要:
A process for producing a product containing C3H6 and C2H4 includes simultaneous conversion of MeOH and EtOH in an adiabatic sequentially operated reactor containing a plurality of reaction stages. Each of the plurality of reaction stages of the reactor is provided with a fixed bed of a form-selective catalyst. A gaseous feed stream including MeOH, DME and H2O is charged to at least a first of the reaction stages of the reactor with a temperature in a range of 300 to 600° C. at a pressure in a range of 0.1 to 20 bar[a]. EtOH is fed into at least, one of the reaction stages of the reactor.
摘要翻译:用于生产含有C 3 H 6和C 2 H 4的产物的方法包括在包含多个反应级的绝热的顺序操作的反应器中同时转化MeOH和EtOH。 反应器的多个反应阶段中的每一个都具有形式选择催化剂的固定床。 将包含MeOH,DME和H 2 O的气态进料流加入到反应器的至少第一个反应阶段,温度范围为300-600℃,压力范围为0.1-20巴[ ]。 将EtOH加入到反应器的至少一个反应级中。
摘要:
A process for producing a product containing C3H6 and C2H4 includes simultaneous conversion of MeOH and EtOH in an adiabatic sequentially operated reactor containing a plurality of reaction stages. Each of the plurality of reaction stages of the reactor is provided with a fixed bed of a form-selective catalyst. A gaseous feed stream including MeOH, DME and H2O is charged to at least a first of the reaction stages of the reactor with a temperature in a range of 300 to 600° C. at a pressure in a range of 0.1 to 20 bar[a]. EtOH is fed into at least, one of the reaction stages of the reactor.
摘要翻译:用于生产含有C 3 H 6和C 2 H 4的产物的方法包括在包含多个反应级的绝热的顺序操作的反应器中同时转化MeOH和EtOH。 反应器的多个反应阶段中的每一个都具有形式选择催化剂的固定床。 将包含MeOH,DME和H 2 O的气态进料流加入到反应器的至少第一个反应阶段,温度范围为300-600℃,压力范围为0.1-20巴[ ]。 将EtOH加入到反应器的至少一个反应级中。
摘要:
The invention relates to a method for the production of monomer organic carbonates from a mixture of organic carbonates and carbamates which are obtained by reacting urea, substituted urea, a salt or ester of carbamide acid or one of the N-substituted derivatives thereof with a polyalkylene glycol, polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n represents a number between 2 and 20, or with a completely or partially hydrolysed polyvinyl alcohol of general formula (II), wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q represent a number between 120, or with mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia and the ammonia becomes free or the amine is removed from the reaction mixture by means of a strip gas, whereby said mixture is reacted with an alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed.
摘要:
The invention relates to a method for the production of monomer organic carbonates, wherein urea, substituted urea, a salt or an ester of carbamide acid or one of the N-substituted derivatives thereof is reacted in a first step in a polyalkylene glycol, a polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n is a number between (2) and (20), or in a completely or partially hydrolysed polyvinyl alcohol of general formula (II) wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q are numbers between 1 and 20, or in mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia in order to form a mixture containing carbonates and carbamates, the ammonia becomes free or the amine is removed form the reaction mixture by means of a strip gas. In a second reaction step (transesterification), the mixture containing the carbonates and carbamates is reacted with a monomer alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed. HO—RnOH (I)
摘要翻译:本发明涉及一种制备单体有机碳酸酯的方法,其中脲,取代的脲,脲或其中的一种或多种N-取代的衍生物的脲或其酯之一在第一步骤中在聚亚烷基二醇,聚酯 - 多元醇或通式(I)的聚醚多元醇,其中R表示具有2-12个碳原子的直链或支链亚烷基,n是(2)和(20)之间的数,或者在完全或部分水解的 通式(II)的聚乙烯醇,其中R'表示烷基,芳基或具有1-12个碳原子的酰基,p和q是1至20之间的数字,或所述化合物在存在下的 促进氨分离以形成含有碳酸酯和氨基甲酸酯的混合物的催化剂,氨变得游离,或者通过带状气体从反应混合物中除去胺。 在第二反应步骤(酯交换)中,将含有碳酸酯和氨基甲酸酯的混合物与单体醇或苯酚反应,由此形成单体碳酸酯,并且将式(I)或(II)的聚合物多元醇重整。 <?in-line-formula description =“In-line Formulas”end =“lead”?> H OR nOH(I)<? in-line-formula description =“In-line Formulas”end =“tail”?>
摘要:
The invention relates to a method for the production of monomer organic carbonates, wherein urea, substituted urea, a salt or an ester of carbamide acid or one of the N-substituted derivatives thereof is reacted in a first step in a polyalkylene glycol, a polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n is a number between (2) and (20), or in a completely or partially hydrolysed polyvinyl alcohol of general formula (II) wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q are numbers between 1 and 20, or in mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia in order to form a mixture containing carbonates and carbamates, the ammonia becomes free or the amine is removed form the reaction mixture by means of a strip gas. In a second reaction step (transesterification), the mixture containing the carbonates and carbamates is reacted with a monomer alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed. HO—RnOH (I)
摘要翻译:本发明涉及一种制备单体有机碳酸酯的方法,其中脲,取代的脲,脲或其中的一种或多种N-取代的衍生物的脲或其酯之一在第一步骤中在聚亚烷基二醇,聚酯 - 多元醇或通式(I)的聚醚多元醇,其中R表示具有2-12个碳原子的直链或支链亚烷基,n是(2)和(20)之间的数,或者在完全或部分水解的 通式(II)的聚乙烯醇,其中R'表示烷基,芳基或具有1-12个碳原子的酰基,p和q是1至20之间的数字,或所述化合物在存在下的 促进氨分离以形成含有碳酸酯和氨基甲酸酯的混合物的催化剂,氨变得游离,或者通过带状气体从反应混合物中除去胺。 在第二反应步骤(酯交换)中,将含有碳酸酯和氨基甲酸酯的混合物与单体醇或苯酚反应,由此形成单体碳酸酯,并且将式(I)或(II)的聚合物多元醇重整。 <?in-line-formula description =“In-line Formulas”end =“lead”?> H OR SUB> OH(I)<?in-line-formula description =“In-line Formulas”end =“tail”?>
摘要:
The invention relates to an intermediate product based on the organic carbonates and carbamates mixture and method for the production thereof. The inventive method consists in reacting a carbamide, a substituted carbamide, a carbamic acid salt or ester or one of the N-substituted derivatives thereof in a glycol polyalkylene, polyol polyester or a polyol polyether of general formula (I), wherein R is a linear or branched alkylene group having from 2 to 12 carbon atoms and n is a number ranging from 1 to 20, or in a totally or partly hydrolysed polyvinyl alcohol of general formula (II), wherein R′ is an alkyl, aryl or acyl group having from 1 to 12 carbon atoms p and q are numbers ranging from 1 to 20, or dissolving in the mixture of said compounds with an alkaline catalyst promoting the ammonia separation. The thus free ammonia or an amine produced by the reaction mixture is removed by a stripping gas.
摘要:
A device for detecting at least one property of a fluid medium has at least one sensor housing introducible into the fluid medium, which sensor housing has at least one channel through which the fluid medium flows and which has at least one outlet opening. The fluid medium flows out through the outlet opening after flowing through the channel. The sensor housing has at least one housing body and at least one cover. The outlet opening is situated in the cover. The housing body has at least one collar section, which engages with the outlet opening and which forms at least one part of an edge of the outlet opening.
摘要:
A multi-way valve of a fuel system of a gas turbine is provided. The multi-way valve includes a valve body provided with a cylindrical housing, the wall bounding the housing includes a plurality of openings for supplying and/or removing fluids, wherein a movably supported insert including at least one channel having two additional openings is provided in the housing, whereby two adjoining openings may be fluidically connected to each other.
摘要:
A micromechanical sensor and a method for manufacturing a micromechanical sensor which has at least one membrane are provided. The membrane is made of a first material which is accommodated in a surrounding second material, and the membrane is configured for sensing a medium surrounding it. The membrane is reinforced, at least partly, by a third material at break-sensitive points on the membrane rim. Reinforcement of the membrane rim increases the stability and thus also the service life of the membrane and the sensor.
摘要:
A sensor for detecting a component of a gaseous fluid containing multiple components. The sensor includes a housing, which delimits a measuring chamber and which accommodates a measuring chip having a heatable diaphragm. The housing has at least one opening which allows convective heat transport.