公开(公告)号：US07847055B2

公开(公告)日：2010-12-07

申请号：US11791520

申请日：2005-11-22

申请人： Kei Saitoh ,  Atsushi Ishio ,  Takeshi Unohara

发明人： Kei Saitoh ,  Atsushi Ishio ,  Takeshi Unohara

IPC分类号： C08G75/14 ,  C08G75/00 ,  C08G75/02

CPC分类号： D01D5/08 ,  C08G75/0204 ,  D01F6/765

摘要： A polyphenylene sulfide resin treated by thermal oxidation has a generated gas amount of 0.23 wt % or less when the resin is heated and melted in vacuum at 320° C. for 2 hours; a residual amount of 3.0 wt % or less as a residue when the resin is dissolved in an amount corresponding to 20 times the weight of the resin, of 1-chloronaphthalene at 250° C. for 5 minutes and, as the 1-chloronaphthalene solution, pressure-filtered in a still hot state by a PTFE membrane filter with a pore size of 1 μm or less; and a melt flow rate (measured at a temperature of 315.5° C. and at a load of 5000 g according to ASTM D-1238-70) of more than 100 g/10 min to 500 g/10 min.

摘要翻译： 当通过热氧化处理的聚苯硫醚树脂在320℃真空加热和熔融2小时时的发生气体量为0.23重量％或更少; 当树脂以相当于树脂重量的20倍的量溶解的残留物的残留量为3.0重量％以下的残留量为1-氯萘，在250℃下保持5分钟，作为1-氯萘溶液 通过孔径1μm以下的PTFE膜过滤器在静止状态下进行过滤; 和熔体流动速率（根据ASTM D-1238-70在315.5℃的温度和5000g的负荷下测量）大于100g / 10min至500g / 10min。

公开(公告)号：US20070265375A1

公开(公告)日：2007-11-15

申请号：US11662907

申请日：2005-07-08

申请人： Atsushi Ishio ,  Kei Saitoh ,  Sadayuki Kobayashi

发明人： Atsushi Ishio ,  Kei Saitoh ,  Sadayuki Kobayashi

IPC分类号： C08L81/02 ,  C08L77/00

CPC分类号： C08L81/02 ,  C08L77/00 ,  C08L2666/20

摘要： A polyphenylene sulfide resin composition including 99 to 60 wt % of a polyphenylene sulfide resin (a) and 1 to 40 wt % of a polyamide resin (b), wherein the polyphenylene sulfide resin (a) forms a sea phase while the polyamide resin (b) forms an island phase, and that the number average dispersed particle size of the polyamide resin (b) is less than 500 nm; and a polyphenylene sulfide resin composition, wherein a compound having one or more types of groups selected from epoxy group, amino group and isocyanate group is added by 0.1 to 10 parts by weight per 100 parts by weight in total of the polyphenylene sulfide resin (a) and the polyamide resin (b), as a compatibilizing agent (c).

摘要翻译： 1.一种聚苯硫醚树脂组合物，其中，所述聚苯硫醚树脂（a）为99〜60重量％，聚酰胺树脂（b）为1〜40重量％，聚酰胺树脂（a） b）形成岛相，并且聚酰胺树脂（b）的数均分散粒径小于500nm; 和聚苯硫醚树脂组合物，其中具有一个或多个选自环氧基，氨基和异氰酸酯基团的基团的化合物的加入量相对于聚苯硫醚树脂的总量为100重量份（a ）和聚酰胺树脂（b）作为相容剂（c）。

公开(公告)号：US09074096B2

公开(公告)日：2015-07-07

申请号：US14114360

申请日：2012-06-22

申请人： Kazuya Okubo ,  Atsushi Ishio ,  Yuki Ota

发明人： Kazuya Okubo ,  Atsushi Ishio ,  Yuki Ota

IPC分类号： H01L23/29 ,  C08L81/04 ,  C08K3/00 ,  C08K5/13 ,  C08K5/20 ,  C08K5/49 ,  C08L81/02 ,  C08L23/02

CPC分类号： C08L81/04 ,  C08K3/00 ,  C08K5/13 ,  C08K5/20 ,  C08K5/49 ,  C08L23/02 ,  C08L81/02

摘要： The invention provides a polyphenylene sulfide resin composition including: 1 to 100 parts by weight of an olefin elastomer (B); and 0.01 to 10 parts by weight of a carboxylic acid amide wax mixture (C), relative to 100 parts by weight of a polyphenylene sulfide resin (A), wherein the carboxylic acid amide wax mixture (C) is obtained by adding 0.01 to 5 parts by weight of an antioxidant to 100 parts by weight of a carboxylic acid amide wax produced by reaction of a higher aliphatic monocarboxylic acid, a polybasic acid and a diamine.

摘要翻译： 本发明提供一种聚苯硫醚树脂组合物，其包含：1〜100重量份的烯烃弹性体（B）; 和相对于100重量份聚苯硫醚树脂（A）的羧酸酰胺蜡混合物（C）为0.01〜10重量份，其中，羧酸酰胺蜡混合物（C）通过添加0.01〜5 通过高级脂族一元羧酸，多元酸和二胺反应制得的羧酸酰胺蜡100重量份，将抗氧化剂重量份。

公开(公告)号：US08153732B2

公开(公告)日：2012-04-10

申请号：US13067220

申请日：2011-05-17

申请人： Takuji Higashioji ,  Tetsuya Machida ,  Masatoshi Ohkura ,  Yasuyuki Imanishi ,  Atsushi Ishio ,  Megumi Yamada

发明人： Takuji Higashioji ,  Tetsuya Machida ,  Masatoshi Ohkura ,  Yasuyuki Imanishi ,  Atsushi Ishio ,  Megumi Yamada

IPC分类号： C08L77/00 ,  C08L81/02 ,  C08L79/00

CPC分类号： B32B27/28 ,  B32B27/08 ,  B32B27/281 ,  B32B27/285 ,  B32B27/286 ,  B32B27/34 ,  B32B2270/00 ,  B32B2307/206 ,  B32B2307/518 ,  B32B2307/734 ,  C08J5/18 ,  C08J2381/04 ,  C08L81/02 ,  C08L2666/02

摘要： A biaxially oriented polyphenylene sulfide film contains polyphenylene sulfide and polyether imide, wherein the contents of the polyphenylene sulfide and the polyether imide are 70 to 99 parts by weight and 1 to 30 parts by weight respectively when the total amount of the polyphenylene sulfide and the polyether imide is taken as 100 parts by weight, and further contains a compound having one or more groups selected from an epoxy group, an amino group and an isocyanate group as a compatibilizing agent in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the polyphenylene sulfide and polyether imide in total, and the polyether imide forms a dispersed phase with an average particle diameter of 10 to 500 nm and the biaxially oriented polyphenylene sulfide film exhibits a tensile elongation at break of 110 to 250% in both the longitudinal direction and width direction.

摘要翻译： 双轴取向聚苯硫醚膜含有聚苯硫醚和聚醚酰亚胺，其中聚苯硫醚和聚醚酰亚胺的含量分别为70〜99重量份和1〜30重量份，当聚苯硫醚和聚醚 将酰亚胺作为100重量份，进一步含有相对于100重量份为0.1〜10重量份的具有一个以上选自环氧基，氨基和异氰酸酯基的基团的化合物 的聚苯硫醚和聚醚酰亚胺，聚醚酰亚胺形成平均粒径为10〜500nm的分散相，双轴取向聚苯硫醚膜在拉伸断裂伸长率为110〜250％ 纵向和宽度方向。

公开(公告)号：US20110224384A1

公开(公告)日：2011-09-15

申请号：US13067220

申请日：2011-05-17

申请人： Takuji Higashioji ,  Tetsuya Machida ,  Masatoshi Ohkura ,  Yasuyuki Imanishi ,  Atsushi Ishio ,  Megumi Yamada

发明人： Takuji Higashioji ,  Tetsuya Machida ,  Masatoshi Ohkura ,  Yasuyuki Imanishi ,  Atsushi Ishio ,  Megumi Yamada

IPC分类号： C08L81/04 ,  C08L63/02 ,  C08L79/08

CPC分类号： B32B27/28 ,  B32B27/08 ,  B32B27/281 ,  B32B27/285 ,  B32B27/286 ,  B32B27/34 ,  B32B2270/00 ,  B32B2307/206 ,  B32B2307/518 ,  B32B2307/734 ,  C08J5/18 ,  C08J2381/04 ,  C08L81/02 ,  C08L2666/02

摘要： A biaxially oriented polyphenylene sulfide film contains polyphenylene sulfide and polyether imide, wherein the contents of the polyphenylene sulfide and the polyether imide are 70 to 99 parts by weight and 1 to 30 parts by weight respectively when the total amount of the polyphenylene sulfide and the polyether imide is taken as 100 parts by weight, and further contains a compound having one or more groups selected from an epoxy group, an amino group and an isocyanate group as a compatibilizing agent in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the polyphenylene sulfide and polyether imide in total, and the polyether imide forms a dispersed phase with an average particle diameter of 10 to 500 nm and the biaxially oriented polyphenylene sulfide film exhibits a tensile elongation at break of 110 to 250% in both the longitudinal direction and width direction.

摘要翻译： 双轴取向聚苯硫醚膜含有聚苯硫醚和聚醚酰亚胺，其中聚苯硫醚和聚醚酰亚胺的含量分别为70〜99重量份和1〜30重量份，当聚苯硫醚和聚醚 将酰亚胺作为100重量份，进一步含有相对于100重量份为0.1〜10重量份的具有一个以上选自环氧基，氨基和异氰酸酯基的基团的化合物 的聚苯硫醚和聚醚酰亚胺，聚醚酰亚胺形成平均粒径为10〜500nm的分散相，双轴取向聚苯硫醚膜在拉伸断裂伸长率为110〜250％ 纵向和宽度方向。

公开(公告)号：US20070299219A1

公开(公告)日：2007-12-27

申请号：US11667384

申请日：2005-10-04

申请人： Takuji Higashioji ,  Tetsuya Machida ,  Masatoshi Ohkura ,  Yasuyuki Imanishi ,  Atsushi Ishio ,  Megumi Yamada

发明人： Takuji Higashioji ,  Tetsuya Machida ,  Masatoshi Ohkura ,  Yasuyuki Imanishi ,  Atsushi Ishio ,  Megumi Yamada

IPC分类号： C08L81/02 ,  C08J5/18 ,  C08L101/00

CPC分类号： B32B27/28 ,  B32B27/08 ,  B32B27/281 ,  B32B27/285 ,  B32B27/286 ,  B32B27/34 ,  B32B2270/00 ,  B32B2307/206 ,  B32B2307/518 ,  B32B2307/734 ,  C08J5/18 ,  C08J2381/04 ,  C08L81/02 ,  C08L2666/02

摘要： A biaxially oriented polyarylene sulfide film and laminated polyarylene sulfide sheets of the film contain polyarylene sulfide and other thermoplastic resin A different from the polyarylene sulfide, wherein the contents of the polyarylene sulfide and the thermoplastic resin A are 70 to 99 parts by weight and 1 to 30 parts by weight respectively when the total amount of the polyarylene sulfide and the thermoplastic resin A is taken as 100 parts by weight and the resin thermoplastic A forms a dispersed phase with an average particle diameter of 10 to 500 nm and the biaxially oriented polyarylene sulfide film exhibits a tensile elongation at break of 110 to 250% in at least one of the longitudinal direction and width direction and a tensile fracture elongation of 80 to 250% in the other direction.

摘要翻译： 双轴取向聚芳硫醚膜和层压聚亚芳基硫醚片含有不同于聚芳硫醚的聚芳硫醚和其它热塑性树脂A，其中聚芳硫醚和热塑性树脂A的含量为70〜99重量份，1〜 当聚芳硫醚和热塑性树脂A的总量为100重量份时，分别为30重量份，树脂热塑性A形成平均粒径为10〜500nm的分散相，双轴取向聚亚芳基硫醚 在纵向方向和宽度方向中的至少一个方向上，断裂拉伸断裂伸长率为110〜250％，拉伸断裂伸长率在另一方向为80〜250％。

公开(公告)号：US07115704B2

公开(公告)日：2006-10-03

申请号：US10897028

申请日：2004-07-23

申请人： Shunsuke Horiuchi ,  Atsushi Ishio ,  Kei Saitoh

发明人： Shunsuke Horiuchi ,  Atsushi Ishio ,  Kei Saitoh

IPC分类号： C08G75/04

CPC分类号： C08G75/0204 ,  C08G75/0213 ,  C08G75/0254 ,  C08G75/0281

摘要： This invention provides a method for producing a polyarylene sulfide, comprising the step of bringing a low-hydrated alkali metal sulfide containing respectively 0.05 to less than 0.8 mole of water and an organic amide solvent per mole of the sulfur contained in the alkali metal sulfide, into contact with a dihalogenated aromatic compound in an organic polar solvent for polymerization. This invention also provides a polyarylene sulfide obtained by the method. The problem to be solved by this invention is to provide a method for efficiently producing a polyarylene sulfide in a short time using an alkali metal sulfide small in water content and organic amide solvent content.

摘要翻译： 本发明提供一种聚芳硫醚的制造方法，其特征在于，在碱金属硫化物中，相对于每摩尔硫含有低分子量的含有0.05〜0.8摩尔的水和有机酰胺溶剂的碱金属硫化物， 在有机极性溶剂中与二卤化芳族化合物接触进行聚合。 本发明还提供了通过该方法获得的聚芳硫醚。 本发明要解决的问题是提供一种使用小含水量的碱金属硫化物和有机酰胺溶剂含量在短时间内高效生产聚芳硫醚的方法。

公开(公告)号：US20050043505A1

公开(公告)日：2005-02-24

申请号：US10897028

申请日：2004-07-23

申请人： Shunsuke Horiuchi ,  Atsushi Ishio ,  Kei Saitoh

发明人： Shunsuke Horiuchi ,  Atsushi Ishio ,  Kei Saitoh

IPC分类号： C08G75/02 ,  C08G75/14

CPC分类号： C08G75/0204 ,  C08G75/0213 ,  C08G75/0254 ,  C08G75/0281

摘要： This invention provides a method for producing a polyarylene sulfide, comprising the step of bringing a low-hydrated alkali metal sulfide containing respectively 0.05 to less than 0.8 mole of water and an organic amide solvent per mole of the sulfur contained in the alkali metal sulfide, into contact with a dihalogenated aromatic compound in an organic polar solvent for polymerization. This invention also provides a polyarylene sulfide obtained by the method. The problem to be solved by this invention is to provide a method for efficiently producing a polyarylene sulfide in a short time using an alkali metal sulfide small in water content and organic amide solvent content.

摘要翻译： 本发明提供一种聚芳硫醚的制造方法，其特征在于，在碱金属硫化物中，每摩尔含有硫的含水量分别为0.05〜0.8摩尔的水和有机酰胺系溶剂的低水合碱金属硫化物的工序， 在有机极性溶剂中与二卤化芳族化合物接触进行聚合。 本发明还提供了通过该方法获得的聚芳硫醚。 本发明要解决的问题是提供一种使用小含水量的碱金属硫化物和有机酰胺溶剂含量在短时间内高效生产聚芳硫醚的方法。