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公开(公告)号：US20100187155A1
公开(公告)日：2010-07-29
申请号：US12655128
申请日：2009-12-23
申请人： Stephen J. McCarthy , Gary Paul Schleicher , Krista Marie Prentice , Michel Daage , Christopher Gordon Oliveri , Thomas Francis Degnan , Jose Guadalupe Santiesteban , Ajit Bhaskar Dandekar , William Joseph Novak , Wenyih F. Lai
发明人： Stephen J. McCarthy , Gary Paul Schleicher , Krista Marie Prentice , Michel Daage , Christopher Gordon Oliveri , Thomas Francis Degnan , Jose Guadalupe Santiesteban , Ajit Bhaskar Dandekar , William Joseph Novak , Wenyih F. Lai
IPC分类号： C10G65/02
CPC分类号： C10G65/12 , C10G45/12 , C10G65/043 , C10G67/04 , C10G2300/202 , C10G2300/207 , C10G2400/02 , C10G2400/04 , C10G2400/10
摘要： An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants. The integrated process includes an initial hydrotreatment, hydrocracking, catalytic dewaxing of the hydrocracking effluent, and an option final hydrotreatment.
摘要翻译： 提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。 在更高硫和/或氮条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。 整合过程包括初步的加氢处理，加氢裂化，加氢裂化流出物的催化脱蜡以及最终的加氢处理。
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12.发明授权Partially decomposed catalyst and hydrocarbon oxidation processes using the same 有权部分分解的催化剂和烃氧化方法使用它们公开(公告)号：US07718564B2
公开(公告)日：2010-05-18
申请号：US11434717
申请日：2006-05-16
申请人： Jihad Mohammed Dakka , Sabato Miseo , Stuart Leon Soled , Jose Guadalupe Santiesteban , Joseph Ernest Baumgartner , Michiel Christian Alexander Van Vliet , Roger Arthur Sheldon
发明人： Jihad Mohammed Dakka , Sabato Miseo , Stuart Leon Soled , Jose Guadalupe Santiesteban , Joseph Ernest Baumgartner , Michiel Christian Alexander Van Vliet , Roger Arthur Sheldon
IPC分类号： B01J23/72 , B01J23/755 , B01J31/00 , B01J27/24
CPC分类号： B01J31/2243 , B01J23/76 , B01J2231/70 , B01J2531/16 , B01J2531/847 , C07C68/00 , C07C69/96
摘要： The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex located on a catalyst support, and is obtained by partial decomposition of the organic metal complex. For example, the process can be used to produce dimethyl carbonate from dimethoxy methane. The invention is also related to a partially decomposed catalyst that comprises a silica support and an organic metal complex, wherein at least 5% of the organic compound remains in the catalyst. The organic metal complex comprises an organic compound and a metal-based compound wherein the metal is selected from copper, nickel, and combinations thereof. The invention is also related to a process for manufacturing of a catalyst comprising mixing L-arginine, a Cu-based compound, water, and optionally another metal-based compound to form a solution; impregnating the solution onto a silica support to form a catalyst precursor; and partially decomposing the L-arginine to form the catalyst so that at least 5% of L-arginine remains in the catalyst.
摘要翻译： 本发明涉及烃氧化方法。 该方法包括在自由基引发剂和催化剂的存在下使一种或多种烃与氧源接触。 催化剂包含位于催化剂载体上的有机金属络合物，并通过有机金属络合物的部分分解获得。 例如，该方法可用于从二甲氧基甲烷生产碳酸二甲酯。 本发明还涉及包含二氧化硅载体和有机金属络合物的部分分解的催化剂，其中至少5％的有机化合物保留在催化剂中。 有机金属络合物包括有机化合物和金属基化合物，其中金属选自铜，镍及其组合。 本发明还涉及制造催化剂的方法，其包括将L-精氨酸，Cu基化合物，水和任选的其它金属类化合物混合以形成溶液; 将溶液浸渍到二氧化硅载体上以形成催化剂前体; 并部分分解L-精氨酸以形成催化剂，使得至少5％的L-精氨酸保留在催化剂中。
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公开(公告)号：US07595420B2
公开(公告)日：2009-09-29
申请号：US10535531
申请日：2003-11-18
申请人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Luo Shifang , Sabato Miseo , James Clarke Vartuli
发明人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Luo Shifang , Sabato Miseo , James Clarke Vartuli
CPC分类号： B01J29/0325 , B01J23/462 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0203 , B01J2229/186 , C07C51/36 , C07C67/303 , C07C2601/14 , C07C61/22 , C07C61/24 , C07C61/08 , C07C61/09 , C07C69/75
摘要： A process for hydrogenating benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, by bringing one or more benzenepolycarboxylic acids or one or more derivatives thereof into contact with a hydrogen-containing gas in the presence of one or more catalytically active metal, such as platinum, palladium, ruthenium or mixtures thereof, deposited on a catalyst support comprising one or more ordered mesoporous materials.
摘要翻译： 通过使一种或多种苯多羧酸或其一种或多种衍生物在含有一种或多种催化活性金属的存在下与含氢气体接触来使苯多元羧酸或其衍生物如酯和/或酸酐氢化的方法， 例如铂，钯，钌或其混合物，沉积在包含一种或多种有序介孔材料的催化剂载体上。
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公开(公告)号：US06733572B2
公开(公告)日：2004-05-11
申请号：US10210566
申请日：2002-07-30
申请人： Sebastian C. Reyes , Krishnan V. Venkatesan , Gregory J. DeMartin , John H. Sinfelt , Karl G. Strohmaier , Jose Guadalupe Santiesteban
发明人： Sebastian C. Reyes , Krishnan V. Venkatesan , Gregory J. DeMartin , John H. Sinfelt , Karl G. Strohmaier , Jose Guadalupe Santiesteban
IPC分类号： B01D5302
CPC分类号： C07C7/13 , Y10S95/902 , C07C11/06
摘要： The present invention is a process for separating propylene and dimethylether from a mixture comprising propylene, dimethylether, and propane. The mixture is passed through a bed of an adsorbent comprising a porous crystalline material having (i) diffusion time constants for dimethylether and propylene of at least 0.1 sec−1, and (ii) a diffusion time constant for propane of than 0.02 of the diffusion time constants for dimethylether and propylene. The bed preferentially adsorbs propylene and dimethylether from the mixture. The adsorbed propylene and dimethylether are then desorbed from the bed.
摘要翻译： 本发明是从丙烯，二甲醚和丙烷的混合物中分离丙烯和二甲醚的方法。 将混合物通过包含多孔结晶材料的吸附剂床，其具有（i）二甲醚和丙烯的扩散时间常数为至少0.1秒-1，和（ii）丙烷的扩散时间常数为0.02以上 二甲醚和丙烯的扩散时间常数。 床优先从混合物中吸附丙烯和二甲醚。 吸附的丙烯和二甲醚然后从床上解吸。
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15.发明授权Process for the production of unsymmetric and/or symmetric dialkyl carbonates and diols 失效用于生产不对称和/或对称的碳酸二烷基酯和二醇的方法公开(公告)号：US06620959B1
公开(公告)日：2003-09-16
申请号：US10123717
申请日：2002-04-16
IPC分类号： C07C6996
CPC分类号： C07C68/065 , C07C69/96
摘要： A process for the production of a dialkyl carbonate and a diol, such as dimethyl carbonate and ethylene glycol, by reacting a feed containing a cyclic carbonate, a hydroxy alkyl carbonate and an aliphatic monohydric alcohol in the presence of a transesterification catalyst is described. In another aspect, a process is described which is particularly useful for producing unsymmetric dialkyl carbonates, such as ethyl methyl carbonate.
摘要翻译： 描述了在酯交换催化剂存在下，通过使含有环状碳酸酯，羟基烷基碳酸酯和脂肪族一元醇的进料反应来制造碳酸二烷基酯和二醇的方法，例如碳酸二甲酯和乙二醇。 在另一方面，描述了一种方法，其特别可用于生产不对称的碳酸二烷基酯，例如碳酸甲乙酯。
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公开(公告)号：US20090234152A1
公开(公告)日：2009-09-17
申请号：US12426704
申请日：2009-04-20
申请人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Luo Shifang , Sabato Miseo , James Clarke Vartuli
发明人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Luo Shifang , Sabato Miseo , James Clarke Vartuli
IPC分类号： C07C67/08
CPC分类号： B01J29/0325 , B01J23/462 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0203 , B01J2229/186 , C07C51/36 , C07C67/303 , C07C2601/14 , C07C61/22 , C07C61/24 , C07C61/08 , C07C61/09 , C07C69/75
摘要： A process for hydrogenating benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, by bringing one or more benzenepolycarboxylic acids or one or more derivatives thereof into contact with a hydrogen-containing gas in the presence of one or more catalytically active metal, such as platinum, palladium ruthenium or mixtures thereof, deposited on a catalyst support comprising one or more ordered mesoporous materials.
摘要翻译： 通过使一种或多种苯多羧酸或其一种或多种衍生物在含有一种或多种催化活性金属的存在下与含氢气体接触来使苯多元羧酸或其衍生物如酯和/或酸酐氢化的方法， 例如沉积在包含一种或多种有序介孔材料的催化剂载体上的铂，钯钌或其混合物。
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公开(公告)号：US07491837B2
公开(公告)日：2009-02-17
申请号：US10642367
申请日：2003-08-15
申请人： Richard H. Schlosberg , J. Scott Buchanan , Jose Guadalupe Santiesteban , Zhaozhong Jiang , William A. Weber
发明人： Richard H. Schlosberg , J. Scott Buchanan , Jose Guadalupe Santiesteban , Zhaozhong Jiang , William A. Weber
IPC分类号： C07C69/96
CPC分类号： C07D317/38 , B01J2219/00006 , C07C29/128 , C07C29/1285 , C07C68/065 , C07D317/36 , C08G64/307 , C08G64/34 , Y02P20/125 , Y02P20/127 , Y02P20/584 , C07C69/96 , C07C31/202
摘要： An integrated process for the production of a dialkyl carbonate and a diol from an alkylene oxide, carbon dioxide and an aliphatic monohydric alcohol is described in which an alkylene oxide is first reacted with carbon dioxide in the presence of a halogen-free carbonation catalyst to provide a corresponding cyclic carbonate and the cyclic carbonate is then reacted with an aliphatic monohydric alcohol in the presence of the carbonation catalyst and/or a transesterification catalyst and recycling the carbonation catalyst to provide a corresponding dialkyl carbonate and diol, wherein the dialkyl carbonate product exhibits a halogen concentration of about 5 ppm or less.
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18.发明授权Process for the production of unsymmetric and/or symmetric dialkyl carbonates and diols 失效用于生产不对称和/或对称的碳酸二烷基酯和二醇的方法公开(公告)号：US07453007B2
公开(公告)日：2008-11-18
申请号：US11148820
申请日：2005-06-09
IPC分类号： C07C69/96
CPC分类号： C07C68/065 , C07C69/96
摘要： A process for the production of a dialkyl carbonate and a diol, such as dimethyl carbonate and ethylene glycol, by reacting a feed containing a cyclic carbonate, a hydroxy alkyl carbonate and an aliphatic monohydric alcohol in the presence of a transesterification catalyst is described. In another aspect, a process is described which is particularly useful for producing unsymmetric dialkyl carbonates, such as ethyl methyl carbonate.
摘要翻译： 描述了在酯交换催化剂存在下，通过使含有环状碳酸酯，羟基烷基碳酸酯和脂肪族一元醇的进料反应来制造碳酸二烷基酯和二醇的方法，例如碳酸二甲酯和乙二醇。 在另一方面，描述了一种方法，其特别可用于生产不对称的碳酸二烷基酯，例如碳酸甲乙酯。
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19.发明授权Production of diisopropylbenzene by disproportion of cumene in the presence of a TEA-mordenite catalyst 有权在TEA丝光沸石催化剂存在下，通过异丙苯的不成比例生产二异丙基苯公开(公告)号：US07432405B2
公开(公告)日：2008-10-07
申请号：US11179320
申请日：2005-07-12
IPC分类号： C07C12/15
CPC分类号： C07C6/123 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C15/02
摘要： A process for the disproportionation of cumene is disclosed which comprises the step of contacting a feed containing cumene, under disproportionation conditions, with a catalyst comprising a molecular sieve, preferably TEA-mordenite. The contacting step disproportionates at least part of the cumene in the feed to provide a disproportionation effluent containing benzene and a mixture of diisopropylbenzene isomers. The effluent is then recovered and contains, prior to any separation step, less 1% of ortho-diisopropylbenzene by weight of the total diisopropylbenzene content of said effluent, less than 1 wt % of n-propylbenzene, less than 5 wt % of triisopropylbenzenes and less than 5 wt % of disproportionation products other than benzene and diisopropylbenzenes.
摘要翻译： 公开了异丙苯歧化的方法，其包括在歧化条件下使含有枯烯的进料与包含分子筛，优选TEA丝光沸石的催化剂接触的步骤。 接触步骤歧化进料中的异丙基苯的至少一部分，以提供含有苯和二异丙基苯异构体的混合物的歧化流出物。 然后回收流出物，并且在任何分离步骤之前，包含按所述流出物的总二异丙苯含量的重量计小于1重量％的邻二异丙基苯，小于1重量％的正丙基苯，小于5重量％的三异丙基苯和 除苯和二异丙基苯以外的歧化产物少于5重量％。
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公开(公告)号：US07081556B2
公开(公告)日：2006-07-25
申请号：US10285917
申请日：2002-11-01
CPC分类号： C07C5/2737 , C07C2/864 , C07C5/2775 , C07C2529/70 , Y02P20/52 , C07C15/08
摘要： There is provided a process for aromatics conversion by contacting a feed suitable for aromatics conversion under conversion condition and in the presence of a catalyst comprising ITQ-13. Examples of such conversion processes include isomerization of aromatic (xylenes) feedstock, disproportionation of toluene to benzene and xylenes, alkylation and transalkylation of aromatics, conversion of light paraffins and light olefins to aromatics, conversion of naphtha to aromatics, and conversion of alcohol to aromatics.
摘要翻译： 通过在转化条件下和在包含ITQ-13的催化剂的存在下接触适于芳族化合物转化的进料来提供芳族化合物转化的方法。 这种转化方法的实例包括芳族（二甲苯）原料的异构化，甲苯向苯和二甲苯的歧化，芳族化合物的烷基化和烷基转移，轻链烷烃和轻质烯烃转化为芳族化合物，将石脑油转化为芳族化合物，以及将醇转化成芳族化合物 。
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