公开(公告)号：US11801499B2

公开(公告)日：2023-10-31

申请号：US17359360

申请日：2021-06-25

Applicant: PTT Global Chemical Public Company Limited

Inventor： Chularat Wattanakit ,  Chadatip Rodaum ,  Anawat Thivasasith ,  Sitthiphong Pengpanich

IPC: C07C4/06 ,  B01J29/40 ,  B01J21/04 ,  B01J21/10 ,  B01J35/00 ,  B01J29/04 ,  B01J21/16 ,  C10G11/04 ,  B01J35/06 ,  C10G11/06 ,  C10G11/08

CPC classification number: B01J29/40 ,  B01J21/04 ,  B01J21/10 ,  B01J21/16 ,  B01J29/041 ,  B01J35/0006 ,  B01J35/0046 ,  B01J35/06 ,  C07C4/06 ,  C10G11/04 ,  C10G11/06 ,  C10G11/08 ,  B01J2229/186 ,  C07C2529/04 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70

Abstract: The present invention relates to a catalyst for producing light olefins from C4-C7 hydrocarbons from catalytic cracking reaction and the production process of light olefins from said catalyst, wherein said catalyst has core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and layered double hydroxide shell (LDH). The catalyst according to the invention provides high percent conversion of substrate to products and high selectivity to light olefins product.

公开(公告)号：US20190135722A1

公开(公告)日：2019-05-09

申请号：US16202914

申请日：2018-11-28

Applicant: Mitsubishi Chemical Corporation ,  TOKUSHIMA UNIVERSITY

Inventor： Yuki Kato ,  Wataru Ninomiya ,  Shigeru Sugiyama

IPC: C07C45/51 ,  B01J29/04

CPC classification number: C07C45/511 ,  B01J29/035 ,  B01J29/041 ,  B01J35/10 ,  C07C45/52 ,  C07C47/02

Abstract: To provide a method for producing propionaldehyde directly from glycerol with high yield, gasified glycerol is brought into contact with a silica-type regular mesoporous body. More specifically, gasified glycerol is supplied to a catalyst layer containing a regular mesoporous body while heating the catalyst layer at a temperature ranging from 200 to 800° C. in such a manner that a W/F value can fall within the range from 0.001 to 1000 g·min/ml inclusive wherein W represents an amount (g) of a catalyst and F represents a supply rate (ml/min) of supplied glycerol.

公开(公告)号：US20180334390A1

公开(公告)日：2018-11-22

申请号：US15821001

申请日：2017-11-22

Applicant: Saudi Arabian Oil Company

Inventor： Lianhui Ding ,  Essam Al-Sayed ,  Kareemuddin Shaik ,  Abdennour Bourane

IPC: C01B39/02 ,  B01J29/04 ,  B01J29/08 ,  B01J23/28 ,  B01J23/30 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08

CPC classification number: C01B39/026 ,  B01J23/28 ,  B01J23/30 ,  B01J23/75 ,  B01J23/755 ,  B01J29/041 ,  B01J29/042 ,  B01J29/044 ,  B01J29/045 ,  B01J29/084 ,  B01J29/166 ,  B01J35/0066 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/08 ,  B01J37/20 ,  B01J2029/081 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/38 ,  B01J2229/40 ,  B01J2229/42 ,  B01J2229/62 ,  C01B39/04 ,  C01B39/205 ,  C01B39/24 ,  C10G45/04 ,  C10G47/20

Abstract: According to one or more embodiments disclosed herein, a mesoporous zeolite may be made by a method comprising contacting an initial zeolite material with ammonium hexafluorosilicate to modify the framework of the initial zeolite material, and forming mesopores in the framework-modified zeolite material. The contacting may form a framework-modified zeolite material. The mesoporous zeolites may be incorporated into catalysts.

公开(公告)号：US20180304241A1

公开(公告)日：2018-10-25

申请号：US15867920

申请日：2018-01-11

Applicant: James J. Spivey ,  Kunlun Ding ,  Swarom Kanitkar

Inventor： James J. Spivey ,  Kunlun Ding ,  Swarom Kanitkar

IPC: B01J29/70 ,  B01J27/06 ,  B01J29/40 ,  B01J37/02 ,  C07C2/76

CPC classification number: B01J29/70 ,  B01J27/06 ,  B01J29/041 ,  B01J29/40 ,  B01J37/0209 ,  C07C2/76 ,  C07C5/2705 ,  C07C5/2708 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2527/08 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2529/70 ,  C07C9/12 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C9/10 ,  C07C11/10

Abstract: Catalysts are disclosed having metal oxide support structures and acidic reaction sites. The reaction sites may be according to the general formula MxOyAlBrzX]−H+ where x is one or two; y is one or two; z is one or two; X is selected from Br or Cl; M is Al or Si and one or more of M, O and Al has a molecular bond with the metal oxide support structure.

公开(公告)号：US20180111117A1

公开(公告)日：2018-04-26

申请号：US15839835

申请日：2017-12-12

Applicant: WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.

Inventor： Li XU ,  Wanwan WANG ,  Youliang SHI

IPC: B01J29/85 ,  B01J29/04 ,  B01J21/06 ,  B01J27/185 ,  B01J35/02 ,  C01B39/54 ,  C10G47/20

CPC classification number: B01J29/85 ,  B01J21/00 ,  B01J21/04 ,  B01J21/066 ,  B01J27/1853 ,  B01J29/041 ,  B01J32/00 ,  B01J35/026 ,  B01J35/10 ,  B01J2229/62 ,  C01B39/02 ,  C01B39/54 ,  C10G2/00 ,  C10G47/20 ,  C10G2400/04

Abstract: A carrier for selectively synthesizing kerosene fraction from syngas, the carrier including the following components in parts by weight: 5-50 parts of mesoporous zirconia (ZrO2), 10-55 parts of a silicoaluminophosphate (SAPO) molecular sieve, 5-50 parts of modified mesoporous molecular sieve Al-SBA-16, 1-3 parts of sesbania gum powder, and 10-70 parts of alumina A catalyst includes a soluble cobalt salt and the aforesaid carrier. The soluble cobalt salt is loaded on the surface of the carrier.

公开(公告)号：US09909072B2

公开(公告)日：2018-03-06

申请号：US14796335

申请日：2015-07-10

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chidambaram Mandan ,  Kshudiram Mantri ,  Supriya Apegaonkar ,  Ramesh Bhujade ,  Nagesh Sharma ,  Raksh Vir Jasra

IPC: B01J27/24 ,  C10G3/00 ,  C10G1/00 ,  B01J37/03 ,  B01J21/04 ,  B01J21/06 ,  B01J23/46 ,  B01J23/882 ,  B01J23/883 ,  B01J27/16 ,  B01J29/04 ,  B01J37/02 ,  C10L9/08 ,  C10L1/32

CPC classification number: C10G3/00 ,  B01J21/04 ,  B01J21/066 ,  B01J23/464 ,  B01J23/882 ,  B01J23/883 ,  B01J27/16 ,  B01J29/041 ,  B01J29/045 ,  B01J37/0203 ,  B01J37/036 ,  C10G1/00 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10L1/326 ,  C10L9/086 ,  Y02P30/20

Abstract: The present disclosure relates to a process for the production of bio-oil which involves heating a mixture of a biomass slurry and a first catalyst composition at a temperature ranging from 200 to 350° C. and at a pressure ranging from 70 to 250 bars to obtain a mass containing crude bio oil, a residue and the catalyst; separating the crude bio oil from said mass to obtain a separated crude bio oil; extracting said separated crude bio oil with at least one solvent and evaporating said solvent to obtain a solvent free crude bio oil; subjecting said solvent free crude bio oil to reduction in the presence of a second catalyst composition and hydrogen source at temperature and pressure conditions similar to those employed for the conversion of bio mass into crude bio oil to obtain bio-oil. The second catalyst composition is the same as that of the first catalyst composition. The process also comprises a method step of recovering the first catalyst and reusing it either for preparing crude bio oil or bio oil or both.

公开(公告)号：US09896628B2

公开(公告)日：2018-02-20

申请号：US14073505

申请日：2013-11-06

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Patricia Rayo Mayoral ,  Jorge Ancheyta Juarez ,  Gustavo Jesus Marroquin Sanchez ,  Guillermo Centeno Nolasco ,  Jorge Fernando Ramirez Solis

IPC: B01J29/06 ,  C10G47/20 ,  B01J29/80 ,  B01J29/14 ,  B01J29/16 ,  B01J29/03 ,  B01J29/035 ,  B01J29/04 ,  C10G45/08 ,  C10G45/12 ,  B01J37/08 ,  B01J21/12 ,  B01J23/883 ,  B01J29/08 ,  B01J29/10 ,  B01J35/02 ,  B01J37/02 ,  B01J35/10 ,  B01J37/00

CPC classification number: C10G47/20 ,  B01J21/12 ,  B01J23/883 ,  B01J29/0308 ,  B01J29/0356 ,  B01J29/0358 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/084 ,  B01J29/106 ,  B01J29/146 ,  B01J29/166 ,  B01J29/80 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/08 ,  B01J2229/186 ,  C10G45/08 ,  C10G45/10 ,  C10G45/12 ,  C10G47/14 ,  C10G47/16 ,  C10G47/18

Abstract: A hydrocracking catalyst having a support of a composite of mesoporous materials, molecular sieves and alumina, is used in the last bed of a multi-bed system for treating heavy crude oils and residues and is designed to increase the production of intermediate distillates having boiling points in a temperature range of 204° C. to 538° C., decrease the production of the heavy fraction (>538° C.), and increase the production of gasoline fraction (

公开(公告)号：US09895686B2

公开(公告)日：2018-02-20

申请号：US13505219

申请日：2009-12-01

Applicant: Xionghou Gao ,  Dong Ji ,  Haitao Zhang ,  Hongchang Duan ,  Di Li ,  ZhengGuo Tan ,  Yi Su ,  Zhicheng Tang ,  Yi Wang ,  Yanqing Ma ,  Yanbo Sun

Inventor： Xionghou Gao ,  Dong Ji ,  Haitao Zhang ,  Hongchang Duan ,  Di Li ,  ZhengGuo Tan ,  Yi Su ,  Zhicheng Tang ,  Yi Wang ,  Yanqing Ma ,  Yanbo Sun

IPC: B01J29/06 ,  B01J37/28 ,  B01J29/04 ,  B01J29/12 ,  B01J29/068 ,  B01J29/44 ,  B01J29/74 ,  C01B39/02 ,  C07C4/06 ,  C10G11/18 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J37/28 ,  B01J29/041 ,  B01J29/061 ,  B01J29/068 ,  B01J29/126 ,  B01J29/44 ,  B01J29/7415 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/08 ,  B01J2229/186 ,  B01J2229/24 ,  B01J2229/37 ,  B01J2229/40 ,  C01B39/026 ,  C07C4/06 ,  C07C2529/12 ,  C07C2529/22 ,  C07C2529/44 ,  C07C2529/74 ,  C10G11/18 ,  C10G2300/1044 ,  C10G2400/20 ,  C07C11/02

Abstract: A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.

公开(公告)号：US09789476B2

公开(公告)日：2017-10-17

申请号：US14380795

申请日：2013-03-25

Applicant: TOSOH CORPORATION

Inventor： Yasuyuki Takamitsu ,  Satoshi Yoshida

IPC: B01J29/06 ,  B01J29/70 ,  C01B39/40 ,  B01J29/40 ,  B01J35/00 ,  B82Y30/00 ,  B01J35/02 ,  B01J29/04 ,  C10G50/00 ,  B01J35/10

CPC classification number: B01J29/70 ,  B01J29/041 ,  B01J29/40 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B82Y30/00 ,  C01B39/40 ,  C01P2004/60 ,  C01P2004/64 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C10G50/00

Abstract: A novel MFI zeolite that when used as a catalyst, can be used for a selective catalytic reaction for larger molecules and provides a method for producing the MFI zeolite. The MFI zeolite includes uniform mesopores having a pore distribution curve which a peak-width thereof at half height (hw) is at most 20 nm (hw≦20 nm) and a center value (μ) of a maximum peak is 10 nm or more and 20 nm or less (10 nm≦μ≦20 nm), and having a pore volume (pv) of the uniform mesopores of at least 0.05 mL/g (0.05 mL/g≦pv); the MFI zeolite has no peak in a range of 0.1° to 3° in powder X-ray diffraction measurement with a diffraction angle represented by 2θ; and the MFI zeolite has an average particle diameter (PD) of at most 100 nm (PD≦100 nm).

公开(公告)号：US09782760B2

公开(公告)日：2017-10-10

申请号：US15605156

申请日：2017-05-25

Applicant: SK INNOVATION CO., LTD. ,  SK LUBRICANTS CO., LTD.

Inventor： Yoon Kyung Lee ,  Seung Woo Lee ,  Jae Suk Choi ,  Tae Jin Kim ,  Do Woan Kim ,  Seon Ju Lim

IPC: B01J29/06 ,  B01J29/70 ,  B01J29/78 ,  C07C5/27 ,  B01J29/74 ,  B01J35/10 ,  C10G45/64 ,  B01J29/76 ,  B01J29/04

CPC classification number: B01J29/7023 ,  B01J29/041 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/703 ,  B01J29/74 ,  B01J29/7461 ,  B01J29/76 ,  B01J29/7661 ,  B01J29/78 ,  B01J29/7846 ,  B01J29/7861 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J35/1095 ,  B01J2229/10 ,  B01J2229/14 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/38 ,  B01J2229/42 ,  C07C5/2775 ,  C07C2529/06 ,  C07C2529/068 ,  C07C2529/072 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/76 ,  C10G45/64

Abstract: Disclosed herein is a method of making activated EU-2 zeolite, including: pores having a diameter of 30 to 40 Å while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 Å, wherein the volume of the pores having a diameter of 30 to 40 Å is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 Å is 0.07 to 0.4 cc/g.