Abstract:
An oligomer, composition, and composite material employing the same are provided. The oligomer has a structure represented by Formula (I) wherein R1 and R2 are independently hydrogen, C1-20 alkyl group, C2-20 alkenyl group, C6-12 aryl group, C6-12 alkylaryl group, C5-12 cycloalkyl group, C6-20 cycloalkylalkyl group, alkoxycarbonyl group, or alkylcarbonyloxy group; R1 is not hydrogen when R2 is hydrogen; a is 0 or 1; n≥0; m≥1; n:m is from 0:100 to 99:1; the oligomer has a number average molecular weight of less than or equal to 12,000; and the repeat unit and the repeat unit are arranged in a random or block fashion.
Abstract:
Disclosed is a method of fabricating a graphite sheet, including: polymerizing diamines and a dianhydride to form a polyamic acid. The polyamic acid is solvent casted on a substrate and hot baked to form a polyamic acid film or gel film. The polyamic acid film or gel film is biaxially stretched at a high temperature imidization or chemical imidization to form the polyimide film. The polyimide film is then carbonized and graphitized to form a graphite sheet. The diamines include a diamine of Formula 1 and a diamine of Formula 2, and the dianhydride includes a dianhydride of Formulae 3, Formula 4, Formula 5, Formula 6, Formula 7, Formula 8, Formula 9, or combinations thereof.
Abstract:
A polymer, a method for preparing the same, and a photosensitive resin composition thereof are provided. The polymer has a structure represented by Formula (I): wherein R1 is —OH, or —COOH; A1 is each A2 is independently each A3 is independently Z is —O—, —S—, —C(CH3)2-, —C(CF3)2-, m is a positive integer that is greater than 1; n is a positive integer that is greater than 1; i is a positive integer between 1 and 3; and, j is a positive integer between 1 and 20; and, the repeat units are arranged in a random fashion.
Abstract:
An aqueous-phase catalyst composition including a metal ion including copper, nickel, manganese or iron and a water-soluble linear polymer having a molecular weight ranging from 1,000 to 20,000 is provided. The metal ion and the water-soluble linear polymer have a weight ratio of 1:1 to 1:5. A method for preparing polyphenylene ether including providing the disclosed aqueous-phase catalyst composition and adding phenolic monomers to the aqueous-phase catalyst composition to proceed to a polymerization reaction to prepare polyphenylene ether is also provided.