公开(公告)号：US08057773B2

公开(公告)日：2011-11-15

申请号：US12655243

申请日：2009-12-28

Applicant: James B. MacArthur ,  James J. Colyar

Inventor： James B. MacArthur ,  James J. Colyar

IPC: C01B31/20 ,  C01B3/24 ,  C01B3/26

CPC classification number: C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/06 ,  C01B2203/0811 ,  C01B2203/0827 ,  C01B2203/1241 ,  C01B2203/145 ,  C01B2203/146 ,  C01B2203/148 ,  Y02P30/30

Abstract: The invention described herein relates to a novel process that eliminates the need for post combustion CO2 capture from fired heaters (at atmospheric pressure and in dilute phase) in a petroleum refinery to achieve environmental targets by capturing CO2 in a centralized facility and providing fuel gas low in carbon to the fired heaters. It combines the pre-combustion capture of carbon dioxide with production of a hydrogen fuel source within a refinery to drastically reduce the carbon dioxide emissions of the plant. The hydrogen fuel is utilized for the process fired heaters and the fuel quality (carbon content) can be set to meet the refinery's emissions objectives. Moreover, the carbon dioxide captured can be sequestered and/or utilized for enhanced oil recovery (EOR).

Abstract translation: 本文所述的发明涉及一种新的方法，其消除了在炼油厂中从燃烧的加热器（在大气压和在稀相中）捕集后燃烧的需要，以通过在集中式设备中捕获CO 2并提供低的燃料气体来实现环境目标 在燃烧的加热器的碳。 它将二氧化碳的燃烧前捕获与炼油厂内的氢燃料源的生产相结合，大大减少了工厂的二氧化碳排放。 氢燃料用于过程燃烧加热器，燃料质量（碳含量）可以设定为满足炼油厂的排放目标。 此外，捕获的二氧化碳可以隔离和/或用于增强采油（EOR）。

公开(公告)号：US20110198266A1

公开(公告)日：2011-08-18

申请号：US12658373

申请日：2010-02-12

Applicant: James J. Colyar

Inventor： James J. Colyar

IPC: C10C3/02

CPC classification number: C10G67/049

Abstract: The described invention discloses an innovative solvent deasphalter and hydroconversion-processing configuration for converting bitumen or heavy oils to produce a transportable synthetic crude oil (SCO). The innovative processing scheme disclosed herein maximizes the synthetic crude oil yield at a minimal investment compared to currently known methods.

Abstract translation: 所述发明公开了用于转化沥青或重油以产生可运输的合成原油（SCO）的创新的溶剂脱沥青和加氢转化处理构型。 与目前已知的方法相比，本文公开的创新处理方案以最小的投资最大化合成原油产量。

公开(公告)号：US20110155639A1

公开(公告)日：2011-06-30

申请号：US12655242

申请日：2009-12-28

Applicant: James J. Colyar

Inventor： James J. Colyar

IPC: C10G49/00

CPC classification number: C10G49/12 ,  C10G65/14 ,  C10G2300/107 ,  C10G2300/1077

Abstract: The described invention discloses an innovative hydroconversion-processing configuration for converting bitumen or heavy oils to produce a transportable synthetic crude oil (SCO). The innovative processing scheme disclosed herein maximizes the synthetic crude oil yield at a minimal investment compared to currently known methods.

Abstract translation: 所描述的发明公开了一种用于转化沥青或重油以生产可运输的合成原油（SCO）的创新的加氢转化处理配置。 与目前已知的方法相比，本文公开的创新处理方案以最小的投资最大化合成原油产量。

公开(公告)号：US5033413A

公开(公告)日：1991-07-23

申请号：US547561

申请日：1990-07-02

Applicant: Frederick A. Zenz ,  James J. Colyar ,  Allen S. Li

Inventor： Frederick A. Zenz ,  James J. Colyar ,  Allen S. Li

IPC: F22B31/00 ,  F23C10/02

CPC classification number: F22B31/0084 ,  F23C10/02

Abstract: A fluidized bed combustion system and method for combusting particulate fuel such as coal together with a sorbent material such as limestone to heat a pressurized liquid and generate saturated vapor, such as steam. The combustion system utilizes at least one concentric dual-sided riser-downcomer unit having a central riser passageway and a concentric outer downcomer passageway located above a dense phase fluidized bed in an enclosure module, the downcomer being configured for directing particulate solids back to the bed. The unit inner and outer passageway surfaces each include a heat exchange panel containing the pressurized liquid for absorbing heat from combustion of the fuel and generating the vapor such as pressurized steam. Primary air is provided below the fluidized bed, while secondary air is provided into the riser passageway. The coal feed particles are substantially completely combusted during their passage through the circulating loop passages, and flue gas is passed outwardly through a cyclone separator, from which any unburned solids are returned to the fluidized bed. The resulting ash and spent limestone are withdrawn from the lower portion of the fluidized bed. Pressurized saturated steam is withdrawn from the unit, while particulates are removed from the flue gas.

Abstract translation: 一种流化床燃烧系统和方法，用于将颗粒燃料如煤与吸附剂材料如石灰石一起燃烧，以加热加压液体并产生饱和蒸气，如蒸汽。 该燃烧系统利用至少一个同心的双面立管降液管单元，其具有位于外壳模块中的致密相流化床上方的中心立管通道和同心外部降液管通道，所述降液管构造成用于将颗粒状固体返回到床 。 单元内部和外部通道表面各自包括热交换面板，该热交换面板包含用于从燃料燃烧吸收热量并产生诸如加压蒸汽的蒸气的加压液体。 初级空气设置在流化床的下方，而二次空气被提供到提升管通道中。 煤进料颗粒在其通过循环回路通道期间基本上完全燃烧，并且烟道气通过旋风分离器向外通过，任何未燃烧的固体从该分离器返回到流化床。 所得到的灰分和废石灰石从流化床的下部排出。 加压的饱和蒸汽从单元中取出，而颗粒物从烟道气中除去。

公开(公告)号：US10351712B2

公开(公告)日：2019-07-16

申请号：US15142198

申请日：2016-04-29

Applicant: James J. Colyar ,  John Duddy

Inventor： James J. Colyar ,  John Duddy

IPC: C09C1/48

CPC classification number: C09C1/48

Abstract: The invention described herein relates to a novel process to create carbon black feed stocks derived from coal by utilizing direct coal liquefaction resulting in an economic process for producing carbon black feedstock. Moreover, relative to the current state of the art (use of FCC slurry oil), the invention process will be significantly more profitable when oil prices increase.

公开(公告)号：US20170313886A1

公开(公告)日：2017-11-02

申请号：US15142198

申请日：2016-04-29

Applicant: James J. Colyar ,  John Duddy

Inventor： James J. Colyar ,  John Duddy

IPC: C09C1/48

CPC classification number: C09C1/48

Abstract: The invention described herein relates to a novel process to create carbon black feed stocks derived from coal by utilizing direct coal liquefaction resulting in an economic process for producing carbon black feedstock. Moreover, relative to the current state of the art (use of FCC slurry oil), the invention process will be significantly more profitable when oil prices increase.

公开(公告)号：US09738839B1

公开(公告)日：2017-08-22

申请号：US15142159

申请日：2016-04-29

Applicant: James J. Colyar

Inventor： James J. Colyar

IPC: C10G47/00 ,  B01J16/00

CPC classification number: C10G47/00 ,  B01J16/005 ,  C10G2300/1077 ,  C10G2300/20

Abstract: This invention relates to the conversion or hydrotreatment of petroleum or coal derived liquids in a novel ebullated-bed reactor system. The novel processing scheme results in a much simpler and less costly (investment and annual operating) ebullated-bed reaction system through the elimination of the high pressure, high temperature separator, hydrogen purification plant, and recycle gas compressor as well as a smaller hydrogen make-up compressor all resulting in substantial operational and construction efficiency.

公开(公告)号：US08568583B2

公开(公告)日：2013-10-29

申请号：US12655242

申请日：2009-12-28

Applicant: James J. Colyar

Inventor： James J. Colyar

IPC: C10G47/00

CPC classification number: C10G49/12 ,  C10G65/14 ,  C10G2300/107 ,  C10G2300/1077

Abstract: The described invention discloses an innovative hydroconversion-processing configuration for converting bitumen or heavy oils to produce a transportable synthetic crude oil (SCO). The innovative processing scheme disclosed herein maximizes the synthetic crude oil yield at a minimal investment compared to currently known methods.

Abstract translation: 所描述的发明公开了一种用于转化沥青或重油以生产可运输的合成原油（SCO）的创新的加氢转化处理配置。 与目前已知的方法相比，本文公开的创新处理方案以最小的投资最大化合成原油产量。

公开(公告)号：US20110290703A1

公开(公告)日：2011-12-01

申请号：US12800988

申请日：2010-05-28

Applicant: James J. Colyar ,  James B. MacArthur ,  Michael Peluso

Inventor： James J. Colyar ,  James B. MacArthur ,  Michael Peluso

IPC: C10G1/06 ,  C01B31/20 ,  B01D53/62

CPC classification number: B01D53/62 ,  B01D53/047 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2257/102 ,  B01D2257/504 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/062 ,  C01B2203/0827 ,  C01B2203/1235 ,  C01B2203/86 ,  C10G1/06 ,  C10G2300/4043 ,  C10J3/00 ,  C10J2300/093 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10J2300/16 ,  C10J2300/1612 ,  C10J2300/1678 ,  C10K1/004 ,  C10K1/005 ,  C10K1/024 ,  C10K1/08 ,  C10K1/143 ,  C10K1/32 ,  C10K3/04 ,  Y02C10/04 ,  Y02C20/20 ,  Y02P20/132 ,  Y02P20/152 ,  Y02P30/30 ,  Y02P30/446

Abstract: The invention described herein relates to a novel process for reducing the carbon dioxide emissions from a coal and/or biomass liquefaction facility by utilizing a steam methane reformer unit in the complex designed to produce additional hydrogen which can be thereafter utilized in the process, as required for the plant fired heaters (including the SMR furnace), and for the production of plant steam. The plant light ends (C1, C2, etc.), which are normally utilized as fuel gas streams are the primary feeds to the SMR Unit along with the tail gas purge from a gasification complex within the facility.

Abstract translation: 本文描述的本发明涉及一种用于通过利用设计成产生额外氢气的复合物中的蒸汽甲烷重整单元来减少来自煤和/或生物质液化设备的二氧化碳排放的新方法，其可以根据需要随后在该方法中使用 用于工厂燃烧的加热器（包括SMR炉），以及用于生产蒸汽。 通常用作燃料气体流的植物光束（C1，C2等）是来自SMR装置的主要进料以及来自设备内的气化复合物的尾气吹扫。

公开(公告)号：US20100147743A1

公开(公告)日：2010-06-17

申请号：US12316611

申请日：2008-12-16

Applicant: James B. MacArthur ,  James J. Colyar ,  John E. Duddy

Inventor： James B. MacArthur ,  James J. Colyar ,  John E. Duddy

IPC: C10G45/20

CPC classification number: C10G1/002 ,  C10G65/04 ,  C10G65/06 ,  C10G65/12 ,  C10G2300/1022 ,  C10G2300/1044 ,  C10G2300/107 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4081

Abstract: This invention utilizes a novel method and set of operating conditions to efficiently and economically process a potentially very fouling hydrocarbon feedstock. A multi-stage catalytic process for the upgrading of coal pyrolysis oils is developed. Coal Pyrolysis Oils are highly aromatic, olefinic, unstable, contain objectionable sulfur, nitrogen, and oxygen contaminants, and,may contain coal solids which will plug fixed-bed reactors. The pyrolysis oil is fed with hydrogen to a multi-stage ebullated-bed hydrotreater and hydrocracker containing a hydrogenation or hydrocracking catalyst to first stabilize the feed at low temperature and is then fed to downstream reactor(s) at higher temperatures to further treat and hydrocrack the pyrolysis oils to a more valuable syncrude or to finished distillate products. The relatively high heat of reaction is used to provide the energy necessary to increase the temperature of the subsequent stage thus eliminating the need for additional external heat input. A refined heavy oil product stream is recycled to the fresh feed to minimize feedstock fouling of heat exchangers and feed heaters.

Abstract translation: 本发明利用新颖的方法和一组操作条件来有效和经济地处理可能非常结垢的烃原料。 开发了用于改进煤热解油的多阶段催化方法。 煤热解油是高度芳香的，烯烃的，不稳定的，含有令人反感的硫，氮和氧污染物，并且可能含有将固定床反应器的煤固体。 将热解油用氢气加入到含有氢化或加氢裂化催化剂的多级沸腾床加氢处理器和加氢裂化器中，以在低温下首先稳定进料，然后在较高温度下进料至下游反应器以进一步处理和加氢裂化 热解油更有价值的syncrude或成品馏出物。 相对较高的反应热用于提供增加后续阶段的温度所需的能量，从而消除了额外的外部热量输入的需要。 精炼的重油产品流被再循环到新鲜饲料中以最小化热交换器和饲料加热器的原料污染。