Water- and oil-repellent compositions
    13.
    发明授权
    Water- and oil-repellent compositions 有权
    防水和防油组合物

    公开(公告)号:US06960642B2

    公开(公告)日:2005-11-01

    申请号:US10339418

    申请日:2003-01-09

    摘要: Fiber, fabric, film, molded or blown article comprising a water- and oil-repellent composition comprising a melt blend of components (a) and (b) in which: (a) comprises a repellency-imparting, fluorochemical composition comprising at least one fluorine-containing aromatic ester oligomer comprising (1) at least two repeat units derived or derivable from the reaction of at least one dicarboxylic acid (or a derivative thereof) and at least one polyol, with the proviso that either the dicarboxylic acid (or derivative) or the polyol (or both) is aromatic or heteroaromatic, and (2) fluorochemical endgroups derived or derivable from the reaction of (i) the dicarboxylic acid (or derivative) and at least one fluorine-containing monoalcohol, or (ii) the polyol and at least one fluorine-containing monocarboxylic acid; and (b) comprises a treatable substrate material; with the proviso that, when the treatable substrate material comprises a mixture of at least two polymers, the mixture is non-stratifying.

    摘要翻译: 1.一种纤维,织物,薄膜,模制或吹塑制品,其包含防水和拒油组合物,其包含组分(a)和(b)的熔融共混物,其中:(a)包含驱斥剂的含氟化合物组合物,其包含至少一种 含氟芳族酯低聚物包含(1)至少两个衍生或衍生自至少一种二羧酸(或其衍生物)和至少一种多元醇的反应的重复单元,条件是二羧酸(或衍生物) )或多元醇(或两者)是芳香族或杂芳族的,和(2)由(i)二羧酸(或衍生物)和至少一种含氟一元醇的反应衍生或衍生的含氟端基,或(ii) 多元醇和至少一种含氟一元羧酸; 和(b)包括可处理的基材; 条件是当可处理基材材料包含至少两种聚合物的混合物时,该混合物是非分层的。

    Water- and oil-repellent composition
    15.
    发明授权
    Water- and oil-repellent composition 失效
    防水防油组合物

    公开(公告)号:US06586522B1

    公开(公告)日:2003-07-01

    申请号:US09592105

    申请日:2000-06-12

    IPC分类号: C08J300

    摘要: A water- and oil-repellent composition comprises (a) a repellency-imparting, fluorochemical composition comprising at least one fluorine-containing aromatic ester oligomer comprising (1) at least two repeat units derived or derivable from the reaction of at least one dicarboxylic acid (or a derivative thereof) and at least one polyol, with the proviso that either the dicarboxylic acid (or derivative) or the polyol (or both) is aromatic or heteroaromatic, and (2) fluorochemical endgroups derived or derivable from the reaction of (i) the dicarboxylic acid (or derivative) and at least one fluorine-containing monoalcohol, or (ii) the polyol and at least one fluorine-containing monocarboxylic acid; and (b) a treatable substrate; with the proviso that, when the treatable substrate comprises a mixture of at least two polymers, the mixture is non-stratifying.

    摘要翻译: 拒水拒油剂组合物包含(a)具有排斥性的氟化合物组合物,其包含至少一种含氟芳族酯低聚物,其包含(1)至少两个衍生或衍生自至少一种二羧酸 (或其衍生物)和至少一种多元醇,条件是二羧酸(或衍生物)或多元醇(或两者)都是芳族或杂芳族的,和(2)衍生或可衍生自( i)二羧酸(或衍生物)和至少一种含氟一元醇,或(ii)多元醇和至少一种含氟一元羧酸; 和(b)可处理基材; 条件是当可处理基材包含至少两种聚合物的混合物时,该混合物是非分层的。

    Water and oil repellent masonry treatments
    16.
    发明授权
    Water and oil repellent masonry treatments 失效
    防水和拒油砌石处理

    公开(公告)号:US06303190B1

    公开(公告)日:2001-10-16

    申请号:US09448629

    申请日:1999-11-24

    IPC分类号: B05D302

    摘要: The present invention provides a water-soluble and shelf-stable aqueous fluorochemical polymeric treatment useful to treat porous substrates to render them repellent to water- and oil-based stains. The treatment comprises a water-soluble fluorochemical polymer containing only carbon atoms in the backbone, with a plurality of each of the following groups pendent from the backbone: (a) fluoroaliphatic groups, (b) carboxyl-containing groups, (c) oxyalkylene or polyoxyalkylene groups, and, optionally, (d) silyl groups. Typically, the treatment polymers have interpolymerized units derived from one or more, and preferably a plurality, of each of the following monomers: (a) monomer selected from the group consisting of acrylate, methacrylate, acrylamide, methacrylamide, thioacrylate or meththioacrylate compounds containing a fluoroaliphatic moiety that is linked to the residue of the compound through a divalent, organic linking group; (b) monomer selected from the group consisting of acrylic acid, methacrylic acid, carboxyalkylacrylate and carboxyalkylmethacrylate compounds; and (c) monomer selected from the group consisting of acrylate, methacrylate, acrylamide, methacrylamide, thioacrylate or meththioacrylate compounds containing an oxyalkylene or polyoxyalkylene group linked to the residue of the compound through an oxygen, sulfur or nitrogen atom.

    摘要翻译: 本发明提供了一种水溶性和储存稳定的含氟含氟聚合物处理剂,其可用于处理多孔基材以使其驱除基于油和油的污渍。 该处理包括在骨架中仅含有碳原子的水溶性含氟化合物聚合物,其中多个以下各个基团从主链侧倾:(a)氟代脂族基团,(b)含羧基团,(c)氧化烯或 聚氧化烯基和任选的(d)甲硅烷基。 通常,处理聚合物具有衍生自以下单体中的一种或多种,​​优选多种的各自的共聚单元:(a)选自丙烯酸酯,甲基丙烯酸酯,丙烯酰胺,甲基丙烯酰胺,硫代丙烯酸酯或甲硫基丙烯酸酯化合物的单体,其包含 氟化脂族部分,其通过二价有机连接基团与化合物的残基连接;(b)选自丙烯酸,甲基丙烯酸,丙烯酸羧丙酯和甲基丙烯酸烷基酯化合物的单体; 和(c)选自丙烯酸酯,甲基丙烯酸酯,丙烯酰胺,甲基丙烯酰胺,硫代丙烯酸酯或含有通过氧,硫或氮原子与化合物的残基连接的氧化烯或聚氧化烯基的甲硫基丙烯酸酯化合物的单体。