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    Polyamines and a process for their production from polyisocyanates
    11.
    发明授权
    Polyamines and a process for their production from polyisocyanates 失效
    多胺及其由多异氰酸酯制备的方法

    公开(公告)号：US4724252A

    公开(公告)日：1988-02-09

    申请号：US895629

    申请日：1986-08-11

    申请人： Werner Rasshofer

    发明人： Werner Rasshofer

    IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/18 ,  C08G18/20 ,  C08G18/50 ,  C08G18/83

    CPC分类号： C08G18/5021 ,  C08G18/10 ,  C08G18/1858 ,  C08G18/2027 ,  C08G18/2063

    摘要： Polyamines containing aromatically bound primary amino groups are prepared in a single stage process by hydrolyzing an isocyanate in the presence of a compound containing an amidine and/or guanidine group and a water-miscible, aprotic-dipolar solvent. This hydrolysis is carried out at from 20.degree. to 210.degree. C. with the reactants being in substantially homogeneous phase. The isocyanate starting material contains aromatically bound NCO groups and has NCO content of from 0.5 to 40 wt. %. The compound containing amidine and/or guanidine groups functions as a catalyst and is used in a quantity of at least 0.001 parts by weight for every 100 parts by weight of isocyanate. The water-miscible solvent is used in a quantity of at least 10 parts by weight for every 100 parts by weight of polyisocyanate. The polyamines thus-produced are particularly useful in the production of polyurethanes.

    摘要翻译： 通过在含有脒和/或胍基和水混溶性非质子偶极溶剂的化合物的存在下水解异氰酸酯，在单阶段方法中制备含芳香结合的伯氨基的多胺。 该水解在20至210℃下进行，反应物基本上是均匀的相。 异氰酸酯原料含有芳香结合的NCO基团，并且NCO含量为0.5〜40wt。 ％。 含有脒和/或胍基的化合物用作催化剂，并且对于每100重量份的异氰酸酯，其用量至少为0.001重量份。 该水混溶性溶剂的使用量相对于每100重量份多异氰酸酯至少为10重量份。 如此生产的聚胺在聚氨酯的生产中特别有用。

    Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes
    13.
    发明授权
    Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes 失效
    具有高乙二醇含量的均相，储存稳定的多元醇组合物及其用于生产聚氨酯的用途

    公开(公告)号：US4554340A

    公开(公告)日：1985-11-19

    申请号：US703059

    申请日：1985-02-19

    申请人： Rudolf Heusch ,  Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz

    发明人： Rudolf Heusch ,  Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz

    IPC分类号： C08G18/32 ,  C08G18/66

    CPC分类号： C08G18/667 ,  C08G18/3206 ,  C08G18/6674 ,  C08G2120/00 ,  C08G2130/00

    摘要： A homogeneous, storage-stable, emulsifier-free polyol mixture having a high mixed OH-number and a high ethylene glycol content comprising 100 parts of a relatively high molecular weight polyalkylene oxide polyol having an OH-number of from 20 to 210, which contains at least 5%, and less than 80%, by weight, of terminal ethylene oxide blocks, from 0.1 to 30 parts of a low molecular weight diol mixture having an OH-- number of 1200 to 1650 in the form of a reaction product of 1 mole of ethylene glycol with 0.1 to 0.5 moles of propylene oxide, optionally, up to 5 parts of di- and/or tri-functional compounds containing reactive hydrogen atoms and having a molecular weight of from 32 to 399, and optionally, other auxiliaries and additives known in the production of polyurethanes. Also, polyurethanes produced using these polyol mixtures.

    摘要翻译： 具有高混合OH-数和高乙二醇含量的均匀，储存稳定，无乳化剂的多元醇混合物，其包含100份具有20至210的OH-数的相对高分子量的聚环氧烷多元醇，其含有 至少5重量％和小于80重量％的末端环氧乙烷嵌段，0.1至30重量份的羟基数为1200至1650的低分子量二醇混合物，其反应产物为1 摩尔的乙二醇与0.1至0.5摩尔的环氧丙烷，任选的至多5份含有反应性氢原子且分子量为32至399的二官能和/或三官能化合物，以及任选的其它助剂和 在聚氨酯生产中已知的添加剂。 此外，使用这些多元醇混合物制备的聚氨酯。

    Process for the preparation of a cellular polyurethane
    14.
    发明授权
    Process for the preparation of a cellular polyurethane 失效
    制备细胞聚氨酯的方法

    公开(公告)号：US4500656A

    公开(公告)日：1985-02-19

    申请号：US594054

    申请日：1984-03-28

    申请人： Werner Rasshofer ,  Ernst-Christoph Prolingheuer

    发明人： Werner Rasshofer ,  Ernst-Christoph Prolingheuer

    IPC分类号： C08G18/32 ,  C08G18/65 ,  C08G18/14

    CPC分类号： C08G18/3296 ,  C08G18/6535 ,  Y10S521/904

    摘要： The present invention relates to a process for the preparation of a cellular polyurethane by the reaction of(A) a polyisocyanate with(B) an isocyanate reactive component containing(1) at least one component having a molecular weight of about 60-2000 and a functionality of 2 to 8, containing isocyanate reactive groups,(2) optionally at least one component having a molecular weight of about 2000 to 12,000 and a functionality of 2 to 8 containing isocyanate reactive groups.(3) about 0.1 to 30 parts, based on 100 parts of (B1)+(B2), of a liquid adduct of an amine and carbon dioxide, and(4) optionally water, blowing agents, foam stabilizers, catalysts and other auxiliary agents and additives,characterized in that the liquid adduct of amine and carbon dioxide is liquid at 20.degree. C., optionally contains water, and is an adduct of carbon dioxide and an amine having at least one amino group and containing at least one primary, secondary or tertiary hydroxyl group, which amine may be solid or liquid at 20.degree. C.

    摘要翻译： 本发明涉及通过（A）多异氰酸酯与（B）异氰酸酯反应性成分的反应制备细胞聚氨酯的方法，所述异氰酸酯反应性成分含有（1）至少一种分子量为约60-2000的成分和 含有异氰酸酯反应性基团的官能度为2至8，（2）任选地至少一种分子量为约2000至12,000且官能度为2至8的含异氰酸酯反应性基团的组分。 （3）约0.1至30份，基于100份（B1）+（B2）的胺和二氧化碳的液体加合物，和（4）任选的水，发泡剂，泡沫稳定剂，催化剂和其它助剂 试剂和添加剂，其特征在于胺和二氧化碳的液体加合物在20℃下为液体，任选地含有水，并且是二氧化碳和具有至少一个氨基并且含有至少一个伯， 二羟基或叔羟基，该胺在20℃下可以是固体或液体。

    Catalytic hydrolysis process for polyamines
    17.
    发明授权
    Catalytic hydrolysis process for polyamines 失效
    多胺催化水解过程

    公开(公告)号：US4931595A

    公开(公告)日：1990-06-05

    申请号：US389384

    申请日：1989-08-02

    申请人： Werner Rasshofer

    发明人： Werner Rasshofer

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/62 ,  C07C211/14 ,  C08G18/08 ,  C08G18/10 ,  C08G18/18 ,  C08G18/22 ,  C08G18/50 ,  C08G18/65 ,  C08G18/83

    CPC分类号： C08G18/5048 ,  C08G18/0804 ,  C08G18/10 ,  C08G18/1825 ,  C08G18/225

    摘要： Polyamines containing primary amino groups are prepared in a single stage process by hydrolyzing an isocyanate in the presence of a catalyst incorporable through an NCO reactive group and a water-miscible aprotic-dipolar solvent. This hydrolysis is carried out at from 20.degree. to 210.degree. C. with the reactants being in substantially homogeneous phase. The isocyanate starting material has an NCO content of from 0.5 to 40% by weight. The catalyst is used in a quantity of at least 0.0001% by weight, based on 100% by weight of isocyanate compound. The water-miscible solvent is used in a quantity of at least 10% by weight, based on 100% by weight of isocyanate compound. The polyamines thus produced are particularly useful in the production of polyurethanes.

    摘要翻译： 通过在可通过NCO反应性基团和水混溶性非质子 - 偶极溶剂掺入的催化剂存在下水解异氰酸酯，在单阶段方法中制备含有伯氨基的多胺。 该水解在20至210℃下进行，反应物基本上是均匀的相。 异氰酸酯原料的NCO含量为0.5〜40重量％。 基于100重量％的异氰酸酯化合物，催化剂的用量为至少0.0001重量％。 基于100重量％的异氰酸酯化合物，水混溶性溶剂的用量至少为10重量％。 如此生产的聚胺在聚氨酯的生产中特别有用。

    Process for the production of a cellular polyurethane
    18.
    发明授权
    Process for the production of a cellular polyurethane 失效
    生产细胞聚氨酯的方法

    公开(公告)号：US4735970A

    公开(公告)日：1988-04-05

    申请号：US20622

    申请日：1987-03-02

    申请人： Claus-Dieter Sommerfeld ,  Werner Rasshofer

    发明人： Claus-Dieter Sommerfeld ,  Werner Rasshofer

    IPC分类号： C08G18/32 ,  C08G18/65 ,  C08G18/14

    CPC分类号： C08G18/6535 ,  C08G18/3296

    摘要： The present invention is directed to a process for preparing a cellular polyurethane by reacting with an NCO-reactive component in the presence of a homogeneous mixture of an optionally water-containing adduct of carbon dioxide an amine containing at least one secondary amino group, low primary amino groups and at least one primary or secondary hydroxyl group (provided there are not more primary hydroxyl groups than amino groups), an amine catalyst and optionally monofluorotrichlormethane. The present invention is directed to the homogeneous mixture these three components.

    摘要翻译： 本发明涉及一种制备细胞聚氨酯的方法，该方法通过与二氧化碳的任选含水加合物的均匀混合物和含有至少一个仲氨基的胺，低级原料 氨基和至少一个伯或仲羟基（提供不比氨基更多的伯羟基），胺催化剂和任选的一氟三氟甲烷。 本发明涉及这三种组分的均相混合物。

    Modified polyamines and a process for their production
    19.
    发明授权
    Modified polyamines and a process for their production 失效
    改性多胺及其制备方法

    公开(公告)号：US4723032A

    公开(公告)日：1988-02-02

    申请号：US437641

    申请日：1982-10-29

    申请人： Werner Rasshofer ,  Dieter Dieterich

    发明人： Werner Rasshofer ,  Dieter Dieterich

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C275/14 ,  C07C325/00 ,  C07C333/00 ,  C08G18/10 ,  C08G18/50 ,  C08G18/82 ,  C08G18/83 ,  C08G73/00 ,  C08G73/02 ,  C07C125/06

    CPC分类号： C08G18/83 ,  C08G18/10 ,  C08G18/5048

    摘要： Modified polyamines containing carbamates, urethane and/or urea and/or thiourethane groups and having a primary amine content of from 0.1 to 20.2 wt % are produced by (a) mixing an organic isocyanate with a base in the presence of at least one hydrogen-active compound and water and (b) converting the carbamate, urethane and/or urea and/or thiourethane groups to amino groups. The isocyanate starting material has an isocyanate content of from 0.5 to 40 wt. %. The hydrogen-active compound contains a hydroxy and/or amino and/or thiol group. Water is used in a quantity such that one mol of water is present for each isocyanate equivalent. Conversion to form the amino groups is accomplished by treatment with a proton donor and/or thermal decomposition and/or solvent extraction. The polyamines thus-produced are particularly useful in the production of polyurethanes.

    摘要翻译： 含有氨基甲酸酯，氨基甲酸酯和/或脲和/或硫代氨基甲酸酯基团并且伯胺含量为0.1至20.2重量％的改性多胺通过以下步骤来制备：（a）在至少一种氢气存在下，将有机异氰酸酯与碱混合， 活性化合物和水，和（b）将氨基甲酸酯，氨基甲酸酯和/或脲和/或硫代氨基甲酸酯基团转化为氨基。 异氰酸酯原料的异氰酸酯含量为0.5〜40重量％。 ％。 氢活性化合物含有羟基和/或氨基和/或硫醇基团。 水的使用量使得每个异氰酸酯当量存在一摩尔的水。 通过用质子供体和/或热分解和/或溶剂萃取处理来实现形成氨基的转化。 如此生产的聚胺在聚氨酯的生产中特别有用。