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公开(公告)号：US06951910B2
公开(公告)日：2005-10-04
申请号：US09951777
申请日：2001-09-14
IPC分类号： C08J7/04 , C08J7/18 , C09D4/06 , C09D5/00 , C09D133/06 , C09D183/04 , C08F130/04
CPC分类号： C08J7/047 , C08J7/18 , C08J2433/00
摘要： The present invention provides radiation-curable compositions for coating plastic substrates, wherein the compositions, after cure, have a combination of sufficient adhesion, flexibility, and hardness. The compositions include: (a) at least one component comprised of a metal oxide bonded to an organic compound, said organic compound having (i) a radiation curable group; and (ii) a group represented by the following formula (1): wherein X represents an amine (NH), oxygen (O), or sulfur (S) radical; and Y represents an oxygen (O), or sulfur (S) radical; (b) a poly(meth)acrylate compound; and (c) an adhesion promoter.
摘要翻译： 本发明提供了用于涂覆塑料基材的可辐射固化组合物，其中组合物在固化之后具有足够的粘合性，柔韧性和硬度的组合。 组合物包括：（a）至少一种由与有机化合物结合的金属氧化物组成的组分，所述有机化合物具有（i）可辐射固化基团; 和（ii）由下式（1）表示的基团：其中X表示胺（NH），氧（O）或硫（S）基; Y表示氧（O）或硫（S）基; （b）聚（甲基）丙烯酸酯化合物; 和（c）粘合促进剂。
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12.发明授权Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies 失效可辐射固化光学玻璃纤维涂料组合物，涂覆光学玻璃纤维和光学玻璃纤维组件公开(公告)号：US06298189B1
公开(公告)日：2001-10-02
申请号：US09035771
申请日：1998-03-06
申请人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
发明人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
IPC分类号： G02B622
CPC分类号： C03C25/1065
摘要： Optical fiber coatings are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be achieved by several means which include by use of additives, by use of radiation-curable oligomers having higher molecular weight, or by use of coatings having certain thermal properties. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
摘要翻译： 公开了具有优异的带剥离和粘合行为的光纤涂层。 涂层是可辐射固化的。 通过使用添加剂，通过使用具有较高分子量的可辐射固化的低聚物，或通过使用具有某些热性质的涂层，可以通过几种方式实现优异的剥离和粘合行为。 可以组合手段。 剥离行为可以通过裂纹扩展和纤维摩擦测量来测量。
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13.发明授权Radiation-curable optical fiber coatings having reduced yellowing and fast cure speed 失效可辐射固化的光纤涂层具有减少黄变和快速固化速度公开(公告)号：US06187835B1
公开(公告)日：2001-02-13
申请号：US09099198
申请日：1998-06-18
IPC分类号： C08F248
CPC分类号： C03C25/1065 , C03C25/106 , C09D4/06 , Y10T428/2933 , Y10T428/2938 , Y10T428/31645 , C08F290/06
摘要： Radiation-curable inner and outer primary optical fiber coatings are disclosed having both fast cure speed and reduced rates of yellowing. The compositions comprise particular photoinitiators and UV absorbers which are used in amounts to provide the combination of properties. The UV absorber can have ethylenic unsaturation. Outer primary coatings can be formulated to screen inner primary coatings and have fast cure speed.
摘要翻译： 公开了可辐射固化的内部和外部初级光纤涂层，其具有快速固化速度和降低的黄化速率。 组合物包含特定的光引发剂和UV吸收剂，其量用于提供性质的组合。 紫外线吸收剂可具有烯属不饱和键。 外部初级涂层可以配制成筛分内部初级涂层并具有快速固化速度。
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公开(公告)号：US5496870A
公开(公告)日：1996-03-05
申请号：US361449
申请日：1994-12-21
申请人： Chander P. Chawla , Tohru Ohtaka , Shinichirou Iwanaga , Tsuyoshi Watanabe , Katsutoshi Igarashi
发明人： Chander P. Chawla , Tohru Ohtaka , Shinichirou Iwanaga , Tsuyoshi Watanabe , Katsutoshi Igarashi
IPC分类号： C08F299/06 , B32B17/10 , C03C25/10 , C08F290/00 , C08G18/48 , C08G18/67 , C08G18/81 , C09D175/08 , C09D175/14 , G02B6/02
CPC分类号： C08G18/672 , B32B17/1077 , C03C25/106 , C08G18/4854 , C08G18/8175
摘要： A curable liquid resin composition comprising a urethane (meth)acrylate polymer obtained by reacting:(A) a polyol compound containing as structural units groups which are represented by formulae--CH.sub.2 CH.sub.2 O-- or--CH.sub.2 CH(CH.sub.2 CH.sub.3)O--;(B) a polyisocyanate compound; and(C) at least one (meth)acrylate compound containing a hydroxyl group and coated articles produced therefrom.
摘要翻译： 一种可固化液体树脂组合物，其包含通过使（A）含有由式-CH 2 CH 2 O-或-CH 2 CH（CH 2 CH 3）O-表示的结构单元基团的多元醇化合物而得到的聚氨酯（甲基）丙烯酸酯聚合物; （B）多异氰酸酯化合物; 和（C）含有羟基的至少一种（甲基）丙烯酸酯化合物和由其制备的涂布制品。
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15.发明申请Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fibers, and optical glass fiber assemblies 审中-公开可辐射固化的光学玻璃纤维涂层组合物，涂覆的光学玻璃纤维和光学玻璃纤维，以及光学玻璃纤维组件公开(公告)号：US20090171011A1
公开(公告)日：2009-07-02
申请号：US12292286
申请日：2008-11-14
申请人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
发明人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
IPC分类号： C08L83/04
CPC分类号： C03C25/1065
摘要： Optical fiber coatings are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be achieved by several means which include by use of additives, by use of radiation-curable oligomers having higher molecular weight, or by use of coatings having certain thermal properties. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
摘要翻译： 公开了具有优异的带剥离和粘合行为的光纤涂层。 涂层是可辐射固化的。 通过使用添加剂，通过使用具有较高分子量的可辐射固化的低聚物，或通过使用具有某些热性质的涂层，可以通过几种方式实现优异的剥离和粘合行为。 可以组合手段。 剥离行为可以通过裂纹扩展和纤维摩擦测量来测量。
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公开(公告)号：US06661959B2
公开(公告)日：2003-12-09
申请号：US10004410
申请日：2001-12-06
申请人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
发明人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
IPC分类号： G02B622
CPC分类号： C03C25/1065
摘要： Optical fiber coatings are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be achieved by several means which include by use of additives, by use of radiation-curable oligomers having higher molecular weight, or by use of coatings having certain thermal properties. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
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17.发明授权Radiation-curable compositions comprising oligomers having an alkyd backbone 失效包含具有醇酸树脂主链的低聚物的可辐射固化组合物公开(公告)号：US06638616B2
公开(公告)日：2003-10-28
申请号：US09419113
申请日：1999-10-15
IPC分类号： C08G1842
CPC分类号： C03C25/1065 , C08G18/4288 , C08G18/8175 , C09D4/00 , C09D4/06 , C09D11/101 , Y10T428/2938 , C08F222/20 , C08F290/147
摘要： The present invention relates to a radiation-curable solvent-free coating composition for optical fiber having a radiation-curable urethane (meth)acrylate oligomer comprising an alkyd backbone, a reactive diluent, a photoinitiator and, optionally, an additive.
摘要翻译： 本发明涉及一种具有辐射固化型聚氨酯（甲基）丙烯酸酯低聚物的光纤的可辐射固化的无溶剂涂料组合物，其包含醇酸树脂主链，反应性稀释剂，光引发剂和任选的添加剂。
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公开(公告)号：US06534557B2
公开(公告)日：2003-03-18
申请号：US09353658
申请日：1999-07-15
申请人： David M. Szum , Chander P. Chawla , James R. Petisce , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora
发明人： David M. Szum , Chander P. Chawla , James R. Petisce , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora
IPC分类号： C08F246
CPC分类号： C03C25/1065 , Y10T428/2938 , Y10T428/2942 , Y10T428/2947 , Y10T428/2962 , Y10T428/2967
摘要： Optical fiber primary coating systems are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be inner piramry coating composition having a slip enhancing component and a high modulus outer primary coating composition. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
摘要翻译： 公开了具有优异的带剥离和粘合行为的光纤一次涂覆系统。 涂层是可辐射固化的。 良好的剥离和粘合行为可以是具有滑爽增强组分和高模量外部初级涂料组合物的内部薄膜涂料组合物。 可以组合手段。 剥离行为可以通过裂纹扩展和纤维摩擦测量来测量。
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公开(公告)号：US06376571B1
公开(公告)日：2002-04-23
申请号：US09035773
申请日：1998-03-06
申请人： Chander P. Chawla , Gerry K. Noren
发明人： Chander P. Chawla , Gerry K. Noren
IPC分类号： C08F250
CPC分类号： C08L51/08 , B33Y70/00 , C03C25/106 , C03C25/1065 , C08F290/061 , C08F290/062 , C08F290/067 , C08F290/147 , C09D151/08 , Y10T428/2938 , C08L2666/02
摘要： A fast curing radiation-curable composition useful as coating compositions for inner and outer primary coatings, inks, ribbons other matrix material coating layers for coating and surrounding optical fibers. The improved radiation-curable compositions, having a propoxylated monomer or oligomer component, demonstrate unexpectedly fast cure speeds while providing strong adhesion characteristics to a variety of substrates and can also be used as a general radiation-curable adhesive or can be adapted for use in the specialized process of digital versatile disk (DVD) production.
摘要翻译： 一种快速固化的可辐射固化组合物，可用作内部和外部初级涂料，油墨，带状涂料组合物，用于涂料和周围光纤的其他基质材料涂层。 具有丙氧基化单体或低聚物组分的改进的可辐射固化组合物表现出意想不到的快速固化速度，同时为各种基材提供强粘附性，并且还可以用作通常的可辐射固化粘合剂，或者可以适用于 数字通用盘（DVD）生产的专业化过程。
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20.发明授权Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies 有权可辐射固化光学玻璃纤维涂料组合物，涂覆光学玻璃纤维和光学玻璃纤维组件公开(公告)号：US06339666B2
公开(公告)日：2002-01-15
申请号：US09838140
申请日：2001-04-20
申请人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
发明人： David M. Szum , Chander P. Chawla , James R. Petisce , John T. Vandeberg , George Pasternack , Timothy E. Bishop , Paul E. Snowwhite , Edward P. Zahora , Stephen C. Lapin
IPC分类号： G02B622
CPC分类号： C03C25/1065
摘要： Optical fiber coatings are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be achieved by several means which include by use of additives, by use of radiation-curable oligomers having higher molecular weight, or by use of coatings having certain thermal properties. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
摘要翻译： 公开了具有优异的带剥离和粘合行为的光纤涂层。 涂层是可辐射固化的。 通过使用添加剂，通过使用具有较高分子量的可辐射固化的低聚物，或通过使用具有某些热性质的涂层，可以通过几种方式实现优异的剥离和粘合行为。 可以组合手段。 剥离行为可以通过裂纹扩展和纤维摩擦测量来测量。
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