公开(公告)号：US06376571B1

公开(公告)日：2002-04-23

申请号：US09035773

申请日：1998-03-06

申请人： Chander P. Chawla ,  Gerry K. Noren

发明人： Chander P. Chawla ,  Gerry K. Noren

IPC分类号： C08F250

CPC分类号： C08L51/08 ,  B33Y70/00 ,  C03C25/106 ,  C03C25/1065 ,  C08F290/061 ,  C08F290/062 ,  C08F290/067 ,  C08F290/147 ,  C09D151/08 ,  Y10T428/2938 ,  C08L2666/02

摘要： A fast curing radiation-curable composition useful as coating compositions for inner and outer primary coatings, inks, ribbons other matrix material coating layers for coating and surrounding optical fibers. The improved radiation-curable compositions, having a propoxylated monomer or oligomer component, demonstrate unexpectedly fast cure speeds while providing strong adhesion characteristics to a variety of substrates and can also be used as a general radiation-curable adhesive or can be adapted for use in the specialized process of digital versatile disk (DVD) production.

摘要翻译： 一种快速固化的可辐射固化组合物，可用作内部和外部初级涂料，油墨，带状涂料组合物，用于涂料和周围光纤的其他基质材料涂层。 具有丙氧基化单体或低聚物组分的改进的可辐射固化组合物表现出意想不到的快速固化速度，同时为各种基材提供强粘附性，并且还可以用作通常的可辐射固化粘合剂，或者可以适用于 数字通用盘（DVD）生产的专业化过程。

公开(公告)号：US4806574A

公开(公告)日：1989-02-21

申请号：US757249

申请日：1985-07-22

申请人： John J. Krajewski ,  Timothy E. Bishop ,  Clive J. Coady ,  John M. Zimmerman ,  Gerry K. Noren ,  Christopher E. Fisher

发明人： John J. Krajewski ,  Timothy E. Bishop ,  Clive J. Coady ,  John M. Zimmerman ,  Gerry K. Noren ,  Christopher E. Fisher

IPC分类号： C03C25/24 ,  C03C25/10 ,  C08F2/48 ,  C08F2/50 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C08G18/50 ,  C08G18/67 ,  C08G18/78 ,  C08G18/79 ,  C08G18/81 ,  C09D5/00 ,  C09D175/14 ,  G02B6/44 ,  C08F20/58 ,  C08F20/60 ,  G02B6/16

CPC分类号： C08G18/672 ,  C03C25/106 ,  C03C25/1065 ,  C08G18/5024 ,  C08G18/7831 ,  C08G18/792 ,  C08G18/8175

摘要： An ultraviolet curing liquid coating composition which, when cured with ultraviolet light in the presence of an appropriate photoinitiator, provides a coating adapted for the coating of optical glass fiber. This coating composition comprises as the essential component, an acrylate-terminated polyurethane oligomer based on a polyfunctional core which is at least trifunctional and which supports one branch for each functionality in the core. Each of the branches leads to an acrylate-functional terminal group, with there being from about 150 to about 2500 units of molecular weight in each branch between the trifunctional core and the acrylate-functional terminal group. Depending primarily upon the molecular weight of the branches, one can provide coating compositions for buffer coat, single coat or topcoat use.

摘要翻译： 一种紫外线固化液体涂料组合物，其在适当的光引发剂存在下用紫外线固化时，提供适于涂覆光学玻璃纤维的涂层。 该涂料组合物包含基于至少三官能的多官能核心的丙烯酸酯封端的聚氨酯低聚物，并且其对核心中的每个官能团支持一个分支。 每个支链通过丙烯酸酯官能的末端基团，在三官能核心和丙烯酸酯官能的末端基团之间的每个分支中分子量为约150至约2500单位。 主要取决于分支的分子量，可以提供缓冲涂层，单涂层或面漆使用的涂料组合物。

公开(公告)号：US5334456A

公开(公告)日：1994-08-02

申请号：US888919

申请日：1992-05-26

申请人： Gerry K. Noren ,  John J. Krajewski ,  Sami A. Shama ,  John M. Zimmerman ,  Danny C. Thompson ,  John T. Vandeberg

发明人： Gerry K. Noren ,  John J. Krajewski ,  Sami A. Shama ,  John M. Zimmerman ,  Danny C. Thompson ,  John T. Vandeberg

IPC分类号： C08F2/50 ,  C08F265/04 ,  C08F299/04 ,  C08L67/06 ,  C09D167/06 ,  C09D167/07 ,  C14C11/00 ,  D21H19/16 ,  D21H19/48 ,  G03F7/027 ,  G03F7/029 ,  B32B27/06 ,  B32B27/36 ,  C08F16/32

CPC分类号： C08F265/04 ,  C08F299/0485 ,  C08L67/06 ,  C09D167/06 ,  C09D167/07 ,  C14C11/003 ,  D21H19/16 ,  D21H19/48 ,  G03F7/027 ,  G03F7/029 ,  Y10T428/3162 ,  Y10T428/31681 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/31794 ,  Y10T428/31826

摘要： A free-radical radiation curable composition comprising:a) at least one compound containing from one to about six vinyl ether groups; andb) at least one compound containing a saturated backbone and at least one maleate or fumarate end group per molecule,wherein the ratio of vinyl ether groups to maleate or fumarate groups in the composition is in the range of about 5:1 to about 1:5.

摘要翻译： 一种自由基可辐射固化组合物，其包含：a）至少一种含有1至约6个乙烯基醚基团的化合物; 和b）每分子含有饱和骨架和至少一种马来酸盐或富马酸酯端基的至少一种化合物，其中组合物中乙烯基醚基团与马来酸盐或富马酸盐基团的比例在约5:1至约1的范围内 ：5。

公开(公告)号：US4690501A

公开(公告)日：1987-09-01

申请号：US752582

申请日：1985-07-08

申请人： John M. Zimmerman ,  Gerry K. Noren ,  Timothy E. Bishop

发明人： John M. Zimmerman ,  Gerry K. Noren ,  Timothy E. Bishop

IPC分类号： C03C25/24 ,  C03C25/10 ,  C08F2/48 ,  C08F2/50 ,  C08F20/00 ,  C08F20/42 ,  C08F290/00 ,  C08F299/06 ,  C08G18/10 ,  C08G18/50 ,  C08G18/67 ,  C08G18/81 ,  C09D5/00 ,  C09D175/14 ,  G02B6/44 ,  C08F26/02 ,  C08F126/02 ,  G02B6/22

CPC分类号： C08G18/8175 ,  C03C25/106 ,  C03C25/1065 ,  C08F299/065 ,  C08G18/10 ,  C08G18/5024 ,  C08G18/672 ,  Y10T428/2938

摘要： Ultraviolet curing oligomers and liquid coating compositions based thereon are disclosed which cure with ultraviolet light in the presence of a photoinitiator. The coating compositions can provide either a single coating for optical glass fiber which resists microbending difficulties down to around -40.degree. C., or a topcoat for overcoating softer buffer coatings which resist microbending down to around -60.degree. C. The coating compositions consist essentially of the linear polyacrylate-terminated polyurethane polyurea oligomer in admixture with an ultraviolet curable liquid acrylate or polyacrylate to provide the liquidity needed for application and to adjust the hardness or softness of the cured coating for the selected single coat or topcoat utility. The oligomer contains a linear polyurethane core terminated by urea formation with a polyhydroxy-functional amine containing a single isocyanate-reactive amino hydrogen atom. The plurality of hydroxy-terminated branches provided by the amine are capped with an acrylate-functional compound, and the several acrylate-functional branches increase the toughness and the cure speed.

摘要翻译： 公开了基于其的紫外线固化低聚物和液体涂料组合物，其在光引发剂存在下用紫外光固化。 涂料组合物可以提供单一的光学玻璃纤维涂层，其抗微弯曲难度低至约-40℃;或用于外涂柔软的缓冲涂层的顶涂层，其抗微弯曲至约-60℃。涂层组合物基本上 的线性聚丙烯酸酯封端的聚氨酯聚脲低聚物与紫外线可固化液体丙烯酸酯或聚丙烯酸酯混合以提供所需的流动性，并调节所选择的单一涂层或面漆实用程序的固化涂层的硬度或柔软度。 低聚物含有由含有单个异氰酸酯反应性氨基氢原子的多羟基官能胺形成脲形成的线性聚氨酯芯。 由胺提供的多个羟基封端的分支用丙烯酸酯官能化合物封端，并且几个丙烯酸酯官能的分支增加韧性和固化速度。

公开(公告)号：US4520144A

公开(公告)日：1985-05-28

申请号：US577553

申请日：1984-02-06

申请人： Gerry K. Noren ,  Mary F. Clifton

发明人： Gerry K. Noren ,  Mary F. Clifton

IPC分类号： C08G18/10 ,  C08G18/61 ,  C08G77/42 ,  C08L63/02 ,  C08L83/08

CPC分类号： C08G77/42 ,  C08G18/10 ,  C08G18/61 ,  Y10T428/31529

摘要： A modified polyepoxide is disclosed which cures with an amine-functional curing agent at room temperature to form coatings having better flexibility and resistance to Skydrol hydraulic fluid. This modified polyepoxide is the reaction product of a diurethane diisocyanate with a resinous polyepoxide having a molecular weight of from about 500 to about 1000 and a 1,2-epoxy equivalency of from about 1.5 to about 2.0. The diurethane diisocyanate is reacted with the resinous polyepoxide in an amount of from about 1.5 moles to about 16 moles per 100 moles of the polyepoxide. The diurethane diisocyanate is itself the reaction product of a dicarbinol-terminated polydimethyl polysiloxane having a molecular weight of from about 1000 to about 4000 with substantially a 2:1 stoichiometric excess of an organic diisocyanate.

摘要翻译： 公开了改进的聚环氧化物，其在室温下用胺官能固化剂固化以形成具有更好柔性和对Skydrol液压流体的耐受性的涂层。 该改性聚环氧化物是二氨基甲酸酯二异氰酸酯与分子量为约500至约1000的树脂聚环氧化物和约1,2-至约2.0的1,2-环氧当量的反应产物。 二氨基甲酸酯二异氰酸酯与树脂多环氧化物的反应量为每100摩尔聚环氧化物约1.5摩尔至约16摩尔。 二氨基甲酸酯二异氰酸酯本身是分子量为约1000至约4000的基于二元素化学计量过量的有机二异氰酸酯的二甲醇封端的聚二甲基聚硅氧烷的反应产物。

公开(公告)号：US5596669A

公开(公告)日：1997-01-21

申请号：US426601

申请日：1995-04-21

申请人： Edward J. Murphy ,  Stephen C. Lapin ,  Gerry K. Noren

发明人： Edward J. Murphy ,  Stephen C. Lapin ,  Gerry K. Noren

IPC分类号： C03C25/10 ,  G02B6/02 ,  G02B6/22

CPC分类号： C03C25/1065 ,  C03C25/106 ,  G02B6/02395

摘要： Provided is a radiation curable coating composition suitable for coating optical glass fiber, having a viscosity in the range of about 10 mPas to 10,000 mPas made of about 20 to about 99.9 weight % of at least one of a thermoplastic non-crosslinking polymer and an ethylenically-unsaturated oligomeric compound; optionally, from 0 to about 60 weight % of an ethylenically-unsaturated diluent, optionally, from 0 to about 60 weight % of a multifunctional ethylenically-unsaturated compound, and optionally, from 0 to about 10 weight % of a photoinitiator, provided that if the thermoplastic non-crosslinking polymer is present and no ethylenically-unsaturated oligomeric compound is present, then the ethylenically-unsaturated diluent is present in an amount up to about 60 weight % and the multifunctional ethylenically-unsaturated compound is present in an amount up to about 60 weight %. The composition provides a tack-free handeable fiber after radiation cure and is fugitive upon thermolysis. Also provided is an optical fiber coated with the coating composition.

摘要翻译： 本发明提供一种适用于涂覆光学玻璃纤维的可辐射固化涂料组合物，其粘度范围为约20〜99.9重量％的热塑性非交联聚合物和烯属化合物中的至少一种的约10mPas至10,000mPas 不饱和低聚化合物; 任选地，0至约60重量％的烯键式不饱和稀释剂，任选地0至约60重量％的多官能烯属不饱和化合物和任选的0至约10重量％的光引发剂，条件是如果 存在热塑性非交联聚合物并且不存在烯键式不饱和低聚化合物，则烯键式不饱和稀释剂以高达约60重量％的量存在，并且多官能烯属不饱和化合物以高达约 60重量％。 组合物在辐射固化后提供无粘性的可再生纤维，并且在热分解时是挥发性的。 还提供涂覆有涂料组合物的光纤。

公开(公告)号：US4999216A

公开(公告)日：1991-03-12

申请号：US396853

申请日：1989-08-21

申请人： Joseph Gaske ,  John J. Krajewski ,  Gerry K. Noren

发明人： Joseph Gaske ,  John J. Krajewski ,  Gerry K. Noren

IPC分类号： B05D3/06 ,  C04B41/48 ,  C04B41/63 ,  E04F21/24

CPC分类号： B05D3/06 ,  C04B41/4826 ,  C04B41/4857 ,  C04B41/63 ,  E04F21/24 ,  Y10T428/31935 ,  Y10T428/4935

摘要： A method of coating a concrete floor is disclosed in which the concrete surface is coated with a homogeneous liquid coating composition containing maleate or fumarate unsaturation in combination with vinyl ether unsaturation and a ketonic photoinitiator, the wet coating is allowed to seep into the concrete surface and to flow out on the concrete surface to form a smooth coating, and this coating is cured by exposing it at light having a wavelength in the range of from about 200 to about 600 nanometers.

摘要翻译： 公开了一种涂覆混凝土地板的方法，其中混凝土表面涂覆有含有马来酸盐或富马酸盐不饱和度与乙烯基醚不饱和度和酮型光引发剂组合的均匀液体涂料组合物，允许湿涂层渗入混凝土表面， 在混凝土表面上流出以形成光滑的涂层，并且该涂层通过在波长为约200至约600纳米的光下曝光而固化。

公开(公告)号：US4943600A

公开(公告)日：1990-07-24

申请号：US321148

申请日：1989-03-10

申请人： Gerry K. Noren ,  Edward J. Murphy

发明人： Gerry K. Noren ,  Edward J. Murphy

IPC分类号： C08F2/50 ,  C08F290/00 ,  C08F299/02 ,  C08F299/04 ,  C08L67/06 ,  C09D5/00 ,  C09D133/04 ,  C09D133/06 ,  C09D167/06 ,  C09D179/02

CPC分类号： C08F299/0485 ,  C08F299/0478 ,  C09D167/06

摘要： A photocurable ethylenically unsaturated liquid coating composition consisting essentially of: 1- polyethylenically unsaturated material in which the ethylenically unsaturated groups are polymerizable groups which are not (meth)acrylate groups; 2- a polyamine resin; and 3- an hydroxyalkyl phenone photoinitiator to speed the cure. The photocure rate is also speeded by combining a tertiary amine-functional acrylic copolymer, an allyl-functional resin, and a maleate-functional resin in a weight ratio of about 15-65/5-45/30-70. In preferred practice both expedients are used to maximize the cure speed.

摘要翻译： 一种可光固化的烯键式不饱和液体涂料组合物，主要由以下组成：1-烯键式不饱和基团，其中烯属不饱和基团是不是（甲基）丙烯酸酯基团的可聚合基团; 2-聚胺树脂; 和3-羟基烷基苯酮光引发剂以加速固化。 通过将叔胺官能丙烯酸共聚物，烯丙基官能树脂和马来酸酯官能树脂以约15-65 / 5-45 / 30-70的重量比组合，光固化速度也加速。 在优选的实践中，使用两种方法来最大化固化速度。

公开(公告)号：US4562235A

公开(公告)日：1985-12-31

申请号：US601439

申请日：1984-04-18

申请人： John M. Zimmerman ,  John J. Krajewski ,  Gerry K. Noren

发明人： John M. Zimmerman ,  John J. Krajewski ,  Gerry K. Noren

IPC分类号： C08F2/00 ,  C08F2/38 ,  C08F20/00 ,  C08F20/10 ,  C08F20/12 ,  C09D133/04 ,  C09D175/00 ,  C09D201/02 ,  C08F20/18

CPC分类号： C08F2/38 ,  Y10T428/31699

摘要： There is disclosed linear polymers and copolymers of polymerized monoethylenically unsaturated monomers having a weight average molecular weight from about 1,500 to about 15,000, with most of the polymer ends being terminated with hydroxyl groups, one at each end of the polymer molecule. These polymers have an average of from about 1.6 to 5 hydroxyl groups per polymer molecule. Thermosetting coating compositions containing these polymers are also disclosed. The monomers which are polymerized may include a small proportion of hydroxy-functional monomers, but desirably consist of monoethylenically unsaturated monomers lacking hydroxyl functionality. The polymers are produced by polymerizing the monoethylenically unsaturated monomers in organic solvent solution medium containing a free radical initiator and a proportion of a chain-terminating agent which is a bis hydroxyorganic xanthogen disulfide in which the organic group is preferably an alkylene group contains from 2-18 carbon atoms to provide the desired molecular weight. The polymers are preferably liquid to slowly flowable at room temperature in the absence of organic solvent.

摘要翻译： 公开了具有约1,500至约15,000的重均分子量的聚合的单烯属不饱和单体的线性聚合物和共聚物，其中大多数聚合物末端以羟基封端，在聚合物分子的每个末端一个。 这些聚合物每个聚合物分子平均具有约1.6至5个羟基。 还公开了含有这些聚合物的热固性涂料组合物。 聚合的单体可以包括少量的羟基官能单体，但是理想地由缺乏羟基官能团的单烯属不饱和单体组成。 聚合物是通过将单烯属不饱和单体聚合在含有自由基引发剂的有机溶剂溶液介质中，以及作为双羟基有机黄原二硫化物的链终止剂的比例，其中有机基团优选为亚烷基， 18个碳原子以提供所需的分子量。 在不存在有机溶剂的情况下，聚合物优选液体以在室温下缓慢流动。

公开(公告)号：US4508889A

公开(公告)日：1985-04-02

申请号：US632613

申请日：1984-07-19

申请人： Gerry K. Noren ,  Erwin S. Poklacki ,  Fred D. Hawker ,  Janice M. Sich

发明人： Gerry K. Noren ,  Erwin S. Poklacki ,  Fred D. Hawker ,  Janice M. Sich

IPC分类号： C08G18/00 ,  C08G18/46 ,  C08G18/50 ,  C08G18/64 ,  C08G18/65 ,  C09D175/04 ,  C09J175/00 ,  C08G18/38

CPC分类号： C08G18/4692 ,  C08G18/5096 ,  C08G18/6469 ,  Y10S528/905

摘要： A process is disclosed in which polyalkoxy amino silane adhesion promoters are incorporated into isocyanate-functional polyurethane resins formed by the reaction of a stoichiometric excess of organic polyisocyanate with an hydroxy-functional resin without producing cloudy and/or unstable resin solutions. In this process, the hydroxy-functional resin is prereacted with the alkoxy functionality of the amino silane in a reaction which liberates alcohol, and then a stoichiometric excess of the organic polyisocyanate is added to cause the isocyanate groups of the polyisocyanate to react with both the hydroxy groups and the amino hydrogen atoms present.

摘要翻译： 公开了一种方法，其中将聚烷氧基氨基硅烷粘合促进剂引入通过化学计量过量的有机多异氰酸酯与羟基官能树脂的反应形成的异氰酸酯官能的聚氨酯树脂中，而不产生混浊和/或不稳定的树脂溶液。 在该方法中，在释放醇的反应中，羟基官能树脂与氨基硅烷的烷氧基官能团预反应，然后加入化学计量过量的有机多异氰酸酯使多异氰酸酯的异氰酸酯基团与 羟基和存在的氨基氢原子。