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11.
公开(公告)号:US06277988B1
公开(公告)日:2001-08-21
申请号:US09515801
申请日:2000-02-29
申请人: John Robert Campbell , James Anthony Cella , Gregory Ronald Gillette , John Edward Kochanowski , Matthew Ladd Reitz
发明人: John Robert Campbell , James Anthony Cella , Gregory Ronald Gillette , John Edward Kochanowski , Matthew Ladd Reitz
IPC分类号: C07F96509
CPC分类号: C07F9/2458 , C07F9/650952 , C07F9/6521
摘要: Sterically hindered phosphoramidates such as N,N′-bis[di-(2,6-xylenoxy)phosphinyl]piperazine are prepared by the reaction of a sterically hindered diaryl chlorophosphate, such as di-(2,6-xylyl) chlorophosphate, with a basic nitrogen compound containing at least two basic N—H groups, preferably a heterocyclic compound such as piperazine, in a predominantly liquid, solvent-free reaction mixture. The reaction may be conducted in the melt or in the presence of a non-solvent carrier, typically an aliphatic hydrocarbon. An excess of the basic nitrogen compound is employed as an acid acceptor.
摘要翻译: 通过空间位阻的氯化磷酸二芳基酯如氯代磷酸二(2,6-二甲苯基)酯与二(2,6-二甲苯基)氧膦基]哌嗪的反应制备了N,N'-双[二 - (2,6-二甲苯氧基) 在主要是液体,无溶剂的反应混合物中含有至少两个碱性NH基团,优选杂环化合物如哌嗪的碱性氮化合物。 反应可以在熔体中或在非溶剂载体(通常为脂族烃)的存在下进行。 使用过量的碱性氮化合物作为酸受体。
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公开(公告)号:US08048956B2
公开(公告)日:2011-11-01
申请号:US12328797
申请日:2008-12-05
CPC分类号: C08F130/04
摘要: The present invention relates to process comprising reacting a polyfluorenes comprising at least one structural group of formula I with an iridium (III) compound of formula II The invention also relates to the polyfluorenes, which are products of the reaction, and the use of the polyfluorenes in optoelectronic devices.
摘要翻译: 本发明涉及使包含至少一种式I结构基团的聚芴与式II的铱(III)化合物反应的方法。本发明还涉及作为反应产物的聚芴和聚芴的用途 在光电器件中。
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公开(公告)号:US07968004B2
公开(公告)日:2011-06-28
申请号:US12250770
申请日:2008-10-14
CPC分类号: C08G61/12 , C08G2261/3142 , C08G2261/3162 , C08G2261/411 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1033 , H01L51/0039 , H01L51/5016 , H05B33/10 , H05B33/14 , Y10S428/917 , Y10T428/31504
摘要: Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
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公开(公告)号:US20100270537A1
公开(公告)日:2010-10-28
申请号:US12428055
申请日:2009-04-22
申请人: Qing Ye , James Anthony Cella , Jie Liu , Eisaku Katoh
发明人: Qing Ye , James Anthony Cella , Jie Liu , Eisaku Katoh
IPC分类号: H01L51/54 , C07D471/14
CPC分类号: H05B33/14 , C09K11/06 , C09K2211/1022 , C09K2211/1029 , C09K2211/1033
摘要: An optoelectronic device comprises a cathode; an electron-transporting layer comprising a compound of formula I; a light emitting-layer; and an anode; wherein R1 and R2 are independently at each occurrence, hydrogen, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R3 is H or alkyl; a and b are, independently at each occurrence 0, or an integer ranging from 1 to 3; n is 2 or 3; and Ar is an aryl.
摘要翻译: 光电器件包括阴极; 包含式I化合物的电子传输层; 发光层; 和阳极; 其中R 1和R 2在每次出现时独立地为氢,C 1 -C 20脂族基,C 3 -C 20芳族基或C 3 -C 20环脂族基; R3是H或烷基; a和b各自独立地为0或1至3的整数; n为2或3; 并且Ar是芳基。
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15.
公开(公告)号:US07718087B2
公开(公告)日:2010-05-18
申请号:US11504552
申请日:2006-08-14
CPC分类号: C09K11/06 , C08L65/00 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0039 , H01L51/0043 , H01L51/0085 , H01L51/5012 , H01L51/5016 , H01L51/5048 , H01L51/5088 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要: The present invention provides compositions comprising at least one novel polymeric organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions of the present invention are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要翻译: 本发明提供包含至少一种包含至少一种环金属配体和至少一种酮吡咯配体的新型聚合有机铱化合物的组合物。 本发明的聚合有机铱组合物称为(2)型有机铱组合物,其构成为使得新型有机铱化合物的至少一种配位体的数均分子量为2000克/摩尔或更高(如 通过凝胶渗透色谱法测定)。 类型(2)有机铱组合物在本文中被称为包含“聚合有机铱络合物”。 新型有机铱组合物可用于诸如OLED器件和光电器件的光电子器件。 一方面,本发明提供了用于制备具有增强的颜色特性和光输出效率的OLED器件的新型有机铱组合物。
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公开(公告)号:US20100093968A1
公开(公告)日:2010-04-15
申请号:US12250826
申请日:2008-10-14
CPC分类号: C08G61/02 , C08G61/12 , C08G2261/3142 , C08G2261/3162 , Y10S428/917
摘要: Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
摘要翻译: 在芴的2和5位上具有大量(10-100%)芴的聚芴聚合物和共聚物可用作需要三元组能量> 2.10eV的OLED器件中的有源层。
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公开(公告)号:US07635792B1
公开(公告)日:2009-12-22
申请号:US12250807
申请日:2008-10-14
IPC分类号: C07C22/00
CPC分类号: C07F5/025 , C07C39/42 , C07C43/225 , C07C2603/18 , C07D295/088 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , H05B33/14
摘要: Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
摘要翻译: 在芴的2和5位上具有大量(10-100%)芴的聚芴聚合物和共聚物可用作需要三元组能量> 2.10eV的OLED器件中的有源层。
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公开(公告)号:US20090156783A1
公开(公告)日:2009-06-18
申请号:US11957579
申请日:2007-12-17
申请人: Joseph John Shiang , Kelly Scott Chichak , James Anthony Cella , Larry Neil Lewis , Kevin Henry Janora
发明人: Joseph John Shiang , Kelly Scott Chichak , James Anthony Cella , Larry Neil Lewis , Kevin Henry Janora
IPC分类号: C08G73/00
CPC分类号: C08G61/12 , C08G2261/142 , C08G2261/1526 , C08G2261/3142 , C08G2261/3162 , H01L51/0039 , H01L51/5012 , Y10S428/917
摘要: Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R1, R3, R4 and R6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R1a is hydrogen or alkyl; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R2a is alkylene; R5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR1a)2, or located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
摘要翻译: 包括至少一种衍生自式I化合物或包含至少一个式II侧基的结构单元的聚合物可用于其中R 1,R 3,R 4和R 6独立地为氢,烷基,烷氧基,氧杂烷基,烷芳基, 芳基,芳基烷基,杂芳基,取代的烷基; 取代的烷氧基,取代的氧杂烷基,取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基,取代的亚烷基,氧杂亚烷基,CO或CO 2; R2a是亚烷基; R5各自独立地为氢,烷基,烷基芳基,芳基,芳基烷基,烷氧基,羧基,取代的烷基; 取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的烷氧基,X是卤素,三氟甲磺酸酯,-B(OR1a)2,或位于2,5-或2,7-位; 苯基吡啶,苯并噻吩并吡啶,二苯并喹嗪,芴基吡啶,酮吡咯,2-(1-萘基)苯并恶唑)),2-苯基苯并恶唑,2-苯基苯并噻唑,香豆素,噻吩基吡啶,苯基吡啶,苯并噻吩基吡啶,3-甲氧基 - 2-苯基吡啶,噻吩基吡啶,苯基亚胺,乙烯基吡啶,吡啶基萘,吡啶基吡咯,吡啶基咪唑,苯基吲哚,其衍生物或其组合。
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公开(公告)号:US07381985B1
公开(公告)日:2008-06-03
申请号:US11610032
申请日:2006-12-13
申请人: Qing Ye , Jie Liu , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang
发明人: Qing Ye , Jie Liu , James Anthony Cella , Kyle Erik Litz , Joseph John Shiang
CPC分类号: C07D209/88 , C08G63/6854 , C08G64/12 , C08G73/1046 , C08G73/1085 , H01L51/0035 , H01L51/0037 , H01L51/0072 , H01L51/0085 , H01L51/5012 , Y10T428/31507 , Y10T428/31721 , Y10T428/31786
摘要: The invention relates to compounds of formula I wherein R1, R2, and R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R3 and R5 are independently at each occurrence hydrogen, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; and a, b and d are independently 0 or an integer ranging from 1 to 3. The invention further relates to polymers derived from compounds of formula I. The polymers may be polyesters, polyethers, polycarbonates, polyestercarbonates, polyetherketones, or polyethersulfones. Compounds and polymers of the invention find use in light emitting devices.
摘要翻译: 本发明涉及式I化合物,其中R 1,R 2,R 4和R 4各自独立地为C 1 C 20 -C 20脂肪族基团,C 3 -C 20芳族基团或C 3 H 3 -C 20脂环族基团; R 3和R 5在每次出现时独立地为氢,C 1 -C 20脂族基团, C 3 -C 20芳族基团或C 3 -C 20脂环族基团; C 3 -C 20芳族基团或C 3 -C 20 -C 20脂环族基团; 并且a,b和d独立地为0或1至3的整数。本发明还涉及衍生自式I化合物的聚合物。聚合物可以是聚酯,聚醚,聚碳酸酯,聚酯碳酸酯,聚醚酮或聚醚砜。 本发明的化合物和聚合物可用于发光器件。
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公开(公告)号:US20080026496A1
公开(公告)日:2008-01-31
申请号:US11637582
申请日:2006-12-12
申请人: Joseph John Shiang , Kevin Henry Janora , Gautam Parthasarathy , James Anthony Cella , Kelly Scott Chichak
发明人: Joseph John Shiang , Kevin Henry Janora , Gautam Parthasarathy , James Anthony Cella , Kelly Scott Chichak
CPC分类号: H01L51/0043 , H01L51/0003 , H01L51/0035 , H01L51/0039 , H01L51/005 , H01L51/0085 , H01L51/56 , Y10T428/31511
摘要: The present invention provides a method for the preparation of organic light-emitting devices comprising a bilayer structure made by forming a first film layer comprising an electroactive material and an INP precursor material, and exposing the first film layer to a radiation source under an inert atmosphere to generate an interpenetrating network polymer composition comprising the electroactive material. At least one additional layer is disposed on the reacted first film layer to complete the bilayer structure. The bilayer structure is comprised within an organic light-emitting device comprising standard features such as electrodes and optionally one or more additional layers serving as a bipolar emission layer, a hole injection layer, an electron injection layer, an electron transport layer, a hole transport layer, exciton-hole transporting layer, exciton-electron transporting layer, a hole transporting emission layer, or an electron transporting emission layer.
摘要翻译: 本发明提供一种制备有机发光器件的方法,其包括通过形成包含电活性材料和INP前体材料的第一膜层制备的双层结构,并在惰性气氛下将第一膜层暴露于辐射源 以产生包含电活性材料的互穿网络聚合物组合物。 在反应的第一膜层上设置至少一个附加层以完成双层结构。 双层结构包括在包括标准特征的有机发光器件中,例如电极和可选地用作双极型发射层的一个或多个附加层,空穴注入层,电子注入层,电子传输层,空穴传输 层,激子 - 空穴传输层,激子 - 电子传输层,空穴传输发射层或电子传输发射层。
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