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11.发明授权Hydrocarbon processes comprised of catalytic distillation using Lewis acid promoted inorganic oxide catalyst systems 失效使用路易斯酸催化蒸馏的烃工艺促进无机氧化物催化剂体系
公开(公告)号：US4935577A
公开(公告)日：1990-06-19
申请号：US297805
申请日：1989-01-17
IPC分类号： B01D3/00 , B01J20060101 , B01J27/08 , B01J27/12 , B60P1/00 , C07C2/60 , C07C9/14 , C07C9/22 , C10G20060101
CPC分类号： B01D3/009 , B01J27/08 , B01J27/12 , C07C2/60 , C07C2521/04 , C07C2521/08 , C07C2527/10 , C07C2527/1213 , C07C2527/126 , C07C2527/133 , Y02P20/127
摘要： This invention relates to catalytic distillation utilizing Lewis acid promoted non-zeolitic inorganic oxide, large pore crystalline molecular sieve and/or ion exchange resin systems. Alkylation and oligomerization processes are adapted to this catalytic distillation technique.
摘要翻译： 本发明涉及利用路易斯酸促进的非沸石无机氧化物，大孔结晶分子筛和/或离子交换树脂体系的催化蒸馏。 烷基化和低聚方法适用于该催化蒸馏技术。
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公开(公告)号：US5347064A
公开(公告)日：1994-09-13
申请号：US45435
申请日：1993-04-12
CPC分类号： C10G50/00 , C07C2/62 , C07C9/16 , C07C2527/1213 , C07C2527/173
摘要： An isoparaffin-olefin alkylation process is disclosed which improves alkylate quality by segregating the olefin feed into intermediate feedstreams which are enriched in propene, 1-butene, and/or 2-butenes with respect to the olefin feed, and alkylating these intermediate feedstreams in separate reaction zones at reaction temperatures specific to the olefin feed to increase the ratio of trimethylpentanes to dimethylhexanes in the resulting alkylate product.
摘要翻译： 公开了一种异链烷烃烯烃烷基化方法，其通过将烯烃进料分离成相对于烯烃进料富含丙烯，1-丁烯和/或2-丁烯的中间进料流，并将这些中间进料流分离 反应区域在烯烃进料特有的反应温度下，以增加所得烷基化产物中三甲基戊烷与二甲基己烷的比例。
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13.发明授权Alkylation process using co-current downflow reactor with a continuous hydrocarbon phase 失效使用具有连续烃相的并流下流反应器的烷基化方法
公开(公告)号：US5345027A
公开(公告)日：1994-09-06
申请号：US933163
申请日：1992-08-21
申请人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Frederick J. Krambeck , Thomas R. Melli , Sergei Yurchak
发明人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Frederick J. Krambeck , Thomas R. Melli , Sergei Yurchak
CPC分类号： C07C2/62 , B01J27/12 , B01J27/16 , C07C2527/1213 , C07C2527/173
摘要： A continuous alkylation process for the production of high octane gasoline comprising contacting a mixture of an isoparaffin and an olefin with a catalyst complex comprising BF3:H.sub.3 PO.sub.4 in a continuous hydrocarbon downflow reactor.
摘要翻译： 包括用于生产高辛烷值汽油的连续烷基化方法，包括使异链烷烃和烯烃的混合物与包含BF 3 :H 3 PO 4的催化剂络合物在连续的烃下流反应器中接触。
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公开(公告)号：US5449851A
公开(公告)日：1995-09-12
申请号：US49586
申请日：1993-04-19
CPC分类号： B01J29/65 , C07C5/2775 , B01J2229/26 , B01J2229/42 , B01J29/7042 , B01J29/7046
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High iso-olefin selectivities thus can be obtained, even at relatively low temperatures and high linear olefin partial pressures.
摘要翻译： 公开了一种用于线性烯烃的有机原料的高度选择性骨架异构化的方法，其中线性烯烃例如正丁烯在异构化条件下与包含ZSM-35的催化剂接触以产生相应碳数的异烯烃，例如， 异丁烯 因此，即使在较低的温度和高的线性烯烃分压下，也可以获得高的异烯烃选择性。
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公开(公告)号：US5334792A
公开(公告)日：1994-08-02
申请号：US958826
申请日：1992-10-09
申请人： Kenneth J. Del Rossi , David J. Dovedytis , David J. Esteves , Mohsen N. Harandi , Albin Huss, Jr.
发明人： Kenneth J. Del Rossi , David J. Dovedytis , David J. Esteves , Mohsen N. Harandi , Albin Huss, Jr.
CPC分类号： C10G59/02 , Y10S585/94
摘要： There is provided a process for ring opening of aromatics and cycloaliphatics, as well as isomerization of aliphatics. The feedstream to this process comprises hydrocarbons having 6 carbon atoms. The process involves the use of at least two reactors connected in series. The first reactor contains a zeolite catalyst and is operated under conditions which particularly promote ring opening. The catalyst in this first reactor may comprise zeolite Beta and platinum. A downstream reactor is operated under conditions to promote isomerization of aliphatics. The catalyst in the second reactor may comprise alumina, platinum and a chloride component.
摘要翻译： 提供了芳烃和环烯烃开环方法以及脂肪族异构化方法。 该方法的进料流包含具有6个碳原子的烃。 该方法涉及使用串联连接的至少两个反应器。 第一反应器含有沸石催化剂，并在特别促进开环的条件下操作。 该第一反应器中的催化剂可以包括沸石β和铂。 下游反应器在促进脂肪族异构化的条件下运行。 第二反应器中的催化剂可以包括氧化铝，铂和氯化物组分。
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公开(公告)号：US5326922A
公开(公告)日：1994-07-05
申请号：US929547
申请日：1992-08-13
申请人： Albin Huss, Jr. , Quang N. Le , Robert T. Thomson
发明人： Albin Huss, Jr. , Quang N. Le , Robert T. Thomson
CPC分类号： C07C5/52 , C07C2/58 , C07C2529/70
摘要： The transfer of hydrogen from a paraffin to an olefin is carried out in the presence of, as catalyst, MCM-36. Especially when the paraffin reactant is an isoparaffin, the olefin produced from the reacted isoparaffin may react with unreacted isoparaffin to also produce an alkylate product.
摘要翻译： 氢气从烷烃转化为烯烃在作为催化剂的MCM-36存在下进行。 特别是当链烷烃反应物是异链烷烃时，由反应的异链烷烃产生的烯烃可与未反应的异链烷烃反应，产生烷基化产物。
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17.发明授权Highly selective n-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性n-烯烃异构化方法
公开(公告)号：US5157194A
公开(公告)日：1992-10-20
申请号：US811355
申请日：1991-12-20
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
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公开(公告)号：US5461182A
公开(公告)日：1995-10-24
申请号：US228769
申请日：1994-04-18
CPC分类号： C07C2/58 , C07C5/52 , C07C2529/70
摘要： The transfer of hydrogen from a paraffin to an olefin is provided. This reaction may be carried out in the presence of a catalyst, such as MCM-36. Especially when the paraffin reactant is an isoparaffin, the olefin produced from the reacted isoparaffin may react with unreacted isoparaffin to also produce an alkylate product.
摘要翻译： 提供氢从石蜡向烯烃的转移。 该反应可以在催化剂如MCM-36存在下进行。 特别是当链烷烃反应物是异链烷烃时，由反应的异链烷烃产生的烯烃可与未反应的异链烷烃反应，产生烷基化产物。
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19.发明授权
公开(公告)号：US5371314A
公开(公告)日：1994-12-06
申请号：US6905
申请日：1993-01-21
CPC分类号： B01J31/0237 , B01D5/00 , B01J31/0222 , B01J31/0225 , B01J31/0231 , C07C2/62 , B01J2231/323 , C07C2527/03 , C07C2527/1206 , C07C2531/025
摘要： The invention provides an isoparaffin-olefin alkylation catalyst composition comprising from about 5 to about 95 weight percent hydrofluoric acid, from about 5 to about 95 weight percent of a solvent having a Donor Number of less than about 40 and from about 0.05 to about 10 weight percent water.An isoparaffin-olefin alkylation process employing the catalyst composition of the invention is also disclosed.
摘要翻译： 本发明提供了一种异链烷烃烯烃烷基化催化剂组合物，其包含约5至约95重量％的氢氟酸，约5至约95重量％的供体数小于约40和约0.05至约10重量％的溶剂 百分之水。 还公开了使用本发明的催化剂组合物的异链烷烃烯烃烷基化方法。
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公开(公告)号：US5258569A
公开(公告)日：1993-11-02
申请号：US929550
申请日：1992-08-13
IPC分类号： C07C2/58
CPC分类号： B01J29/049 , C07C2/58 , C07C2521/04 , C07C2529/70
摘要： The alkylation of isoparaffin with olefin to provide alkylate is carried out in the presence of, as catalyst, MCM-36.
摘要翻译： 异烯烃与烯烃的烷基化以提供烷基化物在作为催化剂MCM-36的存在下进行。
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