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公开(公告)号：US07268268B2
公开(公告)日：2007-09-11
申请号：US10312704
申请日：2001-04-19
CPC分类号： C07C2/12 , C07C2529/70 , C07C2529/85
摘要： A process for the dimerization of at least one olefin with a carbon number between 2 and 10 by contacting the feed with a catalyst system comprising at least: (a) tectometallosilicate zeolite with having TON-type structure, (b) tectometallosilicate zeolite with having MTT-type structure, (c) tectometallosilicate zeolite with the same structure as that of the ZSM-48 zeolite, or (d) silicoaluminophosphate (SAPO) zeo-type with AEL-type structure; under dimerization condition to produce highly branched olefins.
摘要翻译： 通过使进料与至少包含以下的催化剂体系（a）具有TON型结构的组成层硅酸盐沸石，（b）具有MTT的组成层硅酸盐沸石，将碳原子数为2至10的至少一种烯烃二聚化的方法 （c）具有与ZSM-48沸石相同结构的结构硅酸盐硅酸盐沸石，或（d）具有AEL型结构的硅铝磷酸盐（SAPO）zeo型; 在二聚条件下产生高度支化的烯烃。
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公开(公告)号：US5625113A
公开(公告)日：1997-04-29
申请号：US365334
申请日：1994-12-28
CPC分类号： C07C2/58 , C07C2/62 , C07C9/16 , C07C2527/054 , C07C2529/70
摘要： A process is disclosed for alkylating an isoparaffin with an olefin comprising the steps of:(a) reacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in a first alkylation reaction stage at temperature from about -40.degree. C. to about 500.degree. C. and overall isoparaffin:olefin feed weight ratio of from about 1:1 to about 250:1 with a solid alkylation catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 35, X is a trivalent element and Y is a tetravalent element;(b) mixing the effluent from said first alkylation stage with additional olefin to evolve an intermediate stream having an isoparaffin:olefin weight ratio of from about 2:1 to about 100:1; and(c) reacting said intermediate stream in a second alkylation stage in the absence of intermediate fractionation with a liquid acid catalyst comprising H.sub.2 SO.sub.4 to produce C.sub.5 + alkylate.
摘要翻译： 公开了一种用烯烃烷基化异链烷烃的方法，该方法包括以下步骤：（a）使第一烷基化反应阶段中具有4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃反应， 40℃至约500℃，总异构链烷烃：烯烃进料重量比为约1:1至约250:1，其中固体烷基化催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括值 基本上如说明书的表I所述，并且具有包含摩尔关系X 2 O 3：（n）YO 2的组成，其中n小于约35，X是三价元素，Y是四价元素; （b）将来自所述第一烷基化阶段的流出物与另外的烯烃混合以产生具有约2:1至约100:1的异链烷烃：烯烃重量比的中间料流; 和（c）在不与中间分级分离的第二烷基化阶段中使所述中间物流与包含H 2 SO 4的液体酸催化剂反应，以产生C5 +烷基化物。
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公开(公告)号：US5191147A
公开(公告)日：1993-03-02
申请号：US785398
申请日：1991-10-30
CPC分类号： C07C2/58 , B01J29/041 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/16
摘要： The present invention provides a process for alkylating an isoparaffin with an olefin comprising contacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in an alkylation reaction zone at temperature from about -20.degree. C. to about 200.degree. C. in the presence of a Bronsted acid and an inorganic, porous crystalline phase material having, after calcination, a d-spacing greater than about 18 Angstrom Units and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 50 torr and 25.degree. C., wherein the molar ratio of said isoparaffin to said olefin is from about 1:1 to about 250:1 to evolve a product stream containing C.sub.5 + alkylate. In a preferred embodiment, the alkylation catalyst complex comprises a Bronsted acid and an inorganic, porous crystalline phase material having, after calcination, a hexagonal arrangement of uniformly-sized pores having diameters of at least about 13 Angstrom Units and exhibiting a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units.
摘要翻译： 本发明提供了一种用烯烃烷基化异链烷烃的方法，包括在烷基化反应区中将约4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃在约-20℃至约 在布朗斯台德酸和无机多孔结晶相材料存在下，在煅烧后，d-间距大于约18埃单位，苯吸附量大于15克苯/ 100克 所述材料在50托和25℃下，其中所述异链烷烃与所述烯烃的摩尔比为约1:1至约250:1，以放出含有C5 +烷基化物的产物流。 在优选的实施方案中，烷基化催化剂络合物包括布朗斯台德酸和无机多孔结晶相材料，其在煅烧之后具有直径为至少约13埃单位的均匀尺寸的孔的六边形排列并且显示出六边形电子衍射图 可以用大于约18埃单位的d100值进行索引。
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公开(公告)号：US5146029A
公开(公告)日：1992-09-08
申请号：US579766
申请日：1990-09-10
CPC分类号： B01J29/04 , C07C2/12 , C07C2529/70
摘要： Light olefins are converted to isoalkene-rich hydrocarbon products, e.g., isobutene and isoamylenes with zeolite MCM-22 catalyst.
摘要翻译： 使用沸石MCM-22催化剂将轻质烯烃转化为富含异烯烃的烃产物，例如异丁烯和异戊烯。
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公开(公告)号：US5516962A
公开(公告)日：1996-05-14
申请号：US283928
申请日：1994-08-01
CPC分类号： B01J29/04
摘要： There are provided a catalyst, a method for making this catalyst, and a process for using this catalyst in the alkylation of an isoparaffin with an olefin to provide an alkylate. The catalyst may be made from an as-synthesized material which, upon calcination, is capable of generating zeolites designated MCM-22. The as-synthesized material is then combined with a binder material, such as alumina, by an extrusion process. The uncalcined bound material may then be ammonium exchanged, followed by a calcination treatment. The as-synthesized material may also be swollen with a suitable swelling agent, such as a cetyltrimethylammonium compound, prior to the binding process.
摘要翻译： 提供催化剂，制备该催化剂的方法，以及使用该催化剂将异链烷烃与烯烃烷基化以提供烷基化物的方法。 催化剂可以由合成原料制成，其在煅烧时能够产生称为MCM-22的沸石。 然后通过挤出方法将合成后的材料与粘合剂材料如氧化铝组合。 然后将未煅烧的结合材料进行铵交换，随后进行煅烧处理。 在结合过程之前，合成的材料也可以用合适的溶胀剂如十六烷基三甲基铵化合物溶胀。
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6.发明授权
公开(公告)号：US5475175A
公开(公告)日：1995-12-12
申请号：US228780
申请日：1994-04-18
申请人： Altaf Husain , Albin Huss, Jr. , Iraj I. Rahmim
发明人： Altaf Husain , Albin Huss, Jr. , Iraj I. Rahmim
CPC分类号： B01J29/65 , B01J37/0009 , C07C2/58 , B01J2229/42 , B01J29/70 , C07C2521/04 , C07C2529/70
摘要： This invention provides a process for upgrading hydrocarbon feedstock comprising the steps of:(i) recovering a C.sub.4 -rich aliphatic stream from a catalytic cracking process;(ii contacting said C.sub.4 -rich aliphatic stream with an isomerization catalyst comprising a zeolite sorbing 30 to 55 mg n-hexane at 90.degree. C., 83 torr, and 15 to 40 mg 3-methylpentane at 90.degree. C., 90 torr, per g dry zeolite in the hydrogen form in a first reaction stage to selectively isomerize C.sub.4 n-olefins to C.sub.4 isoolefins; and(iii) contacting the product stream from said first reaction stage with a solid acid alkylation catalyst selected from the group consisting of MCM-36 and MCM-49, as described herein and zeolites having a Constraint Index of less than or equal to about 2, to produce isoparaffinic alkylate gasoline.
摘要翻译： 本发明提供了一种用于升级烃原料的方法，包括以下步骤：（i）从催化裂化过程中回收富含C4的脂族物流; （ii）使所述富C4脂族物流与异构化催化剂接触，所述异构化催化剂包括在90℃下吸附30至55mg正己烷的沸石，83托和15至40mg 3-甲基戊烷，90℃，90托， 在氢气形式的每g干沸石中，在第一反应阶段中选择性地将C 4正构烯烃异构化为C 4异烯烃;和（iii）使来自所述第一反应阶段的产物流与固体酸烷基化催化剂接触，所述固体酸烷基化催化剂选自MCM -36和MCM-49，以及具有小于或等于约2的约束指数的沸石以产生异链烷烃烷基化汽油。
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公开(公告)号：US5354718A
公开(公告)日：1994-10-11
申请号：US42907
申请日：1993-04-05
CPC分类号： B01J29/04
摘要： There are provided a catalyst, a method for making this catalyst, and a process for using this catalyst in the alkylation of an isoparaffin with an olefin to provide an alkylate. The catalyst may be made from an as-synthesized material which, upon calcination, is capable of generating zeolites designated MCM-22. The as-synthesized material is then combined with a binder material, such as alumina, by an extrusion process. The uncalcined bound material may then be ammonium exchanged, followed by a calcination treatment. The as-synthesized material may also be swollen with a suitable swelling agent, such as a cetyltrimethylammonium compound, prior to the binding process.
摘要翻译： 提供催化剂，制备该催化剂的方法，以及使用该催化剂将异链烷烃与烯烃烷基化以提供烷基化物的方法。 催化剂可以由合成原料制成，其在煅烧时能够产生称为MCM-22的沸石。 然后通过挤出方法将合成后的材料与粘合剂材料如氧化铝组合。 然后将未煅烧的结合材料进行铵交换，随后进行煅烧处理。 在结合过程之前，合成的材料也可以用合适的溶胀剂如十六烷基三甲基铵化合物溶胀。
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8.发明授权Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49 失效异构烷烃：在合成多孔MCM-49存在下进行烯烃烷基化
公开(公告)号：US5254792A
公开(公告)日：1993-10-19
申请号：US774482
申请日：1991-10-10
CPC分类号： C07C2/58 , C07C2529/70
摘要： The invention provides an isoparaffin: olefin alkylation process comprising contacting isoparaffin and olefin with a synthetic porous crystalline material which is characterized, in its uncalcined form, by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 20, X is a trivalent element and Y is a tetravalent element.
摘要翻译： 本发明提供了异链烷烃：烯烃烷基化方法，其包括使异链烷烃和烯烃与合成的多孔结晶材料接触，所述合成多孔结晶材料的特征在于其未煅烧形式，其X射线衍射图包括基本上如本说明书的表I所述的值，并且具有 包含摩尔关系X 2 O 3：（n）YO 2的组合物，其中n小于约20，X是三价元素，Y是四价元素。
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公开(公告)号：US4992578A
公开(公告)日：1991-02-12
申请号：US491407
申请日：1990-03-09
申请人： Altaf Husain
发明人： Altaf Husain
IPC分类号： B01J23/40 , C07B61/00 , C07C381/04
CPC分类号： C07C381/04
摘要： Alkyl alkanethiolsulfonates are prepared by oxidation of the corresponding alkanethiol, dialkyl disulfide, or mixture thereof by aqueous hydrogen peroxide in the presence of a Group VIII transition metal catalyst.
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公开(公告)号：US5258569A
公开(公告)日：1993-11-02
申请号：US929550
申请日：1992-08-13
IPC分类号： C07C2/58
CPC分类号： B01J29/049 , C07C2/58 , C07C2521/04 , C07C2529/70
摘要： The alkylation of isoparaffin with olefin to provide alkylate is carried out in the presence of, as catalyst, MCM-36.
摘要翻译： 异烯烃与烯烃的烷基化以提供烷基化物在作为催化剂MCM-36的存在下进行。
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