Polymerization methods using the catalysts
    11.
    发明授权
    Polymerization methods using the catalysts 有权
    使用催化剂的聚合方法

    公开(公告)号:US07868105B2

    公开(公告)日:2011-01-11

    申请号:US11581470

    申请日:2006-10-17

    IPC分类号: C08F4/06 C08F4/12 C08F4/16

    CPC分类号: C08F4/70 C08F32/08

    摘要: Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group.According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

    摘要翻译: 提供一种通过环状烯烃单体的加成聚合制备环状烯烃聚合物的方法,该方法包括使由下述通式1表示的金属催化剂配合物与由下式2表示的环状烯烃单体接触:[M(L1)x( L'2)y(L3)z] a [Ani] b式1其中M是X族金属; [M(L1)x(L'2)y(L3)z]是阳离子络合物; L1是含阴离子烃基的配体; L'2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2≦̸ x + y + z≦̸ 6; a和b分别是能够与金属M弱配位的阳离子数和阴离子数,并且各自为1-10,其用于满足金属催化剂络合物的净电荷平衡,并且其中对于每个 的L 1,L 2和L 3,当多个配体存在于金属催化剂配合物的分子中时,配体可以相同或不同,并且其中m为0-4的整数; 并且R 7,R'7,R“7和R”'7各自独立地为极性官能团或非极性官能团。 根据本发明的方法,即使使用含极性官能团的环状烯烃单体,也可以高产率地制造高分子量环状烯烃加成聚合物。 使用该方法制备的聚合物显示出良好的热稳定性。

    System and method for providing social network service and for setting relationship between users
    13.
    发明授权
    System and method for providing social network service and for setting relationship between users 有权
    用于提供社交网络服务和设置用户关系的系统和方法

    公开(公告)号:US09560618B2

    公开(公告)日:2017-01-31

    申请号:US13599386

    申请日:2012-08-30

    摘要: Provided is a system for providing social network service (SNS) and a method for setting relationship between users of mobile terminals. The system may include a reception unit to receive location information on a user terminal allowing the location information to be shared in response to a friend request from the user terminal, a user terminal identification unit to identify at least one other user terminal present within a preset distance based on the location information on the user terminal and allows location information to be shared, a user information transmission unit to identify and send user information on the other user terminal to the user terminal, and a relationship setting unit to set a relationship between users of the user terminal and the other user terminal when the user information on the other user terminal is selected in the user terminal.

    摘要翻译: 提供了一种用于提供社交网络服务(SNS)的系统和用于设置移动终端的用户之间的关系的方法。 系统可以包括接收单元,用于接收用户终端上的位置信息,允许响应于来自用户终端的朋友请求共享位置信息;用户终端识别单元,用于识别存在于预设中的至少一个其他用户终端 基于用户终端上的位置信息的距离,并且允许共享位置信息;用户信息发送单元,用于向用户终端识别并发送另一用户终端上的用户信息;以及关系设置单元,用于设置用户之间的关系 当在用户终端中选择了另一用户终端上的用户信息时,用户终端和另一用户终端。

    Catalysts for polymerizing cyclic olefin
    15.
    发明授权
    Catalysts for polymerizing cyclic olefin 有权
    用于聚合环烯烃的催化剂

    公开(公告)号:US07863214B2

    公开(公告)日:2011-01-04

    申请号:US11542166

    申请日:2006-10-04

    IPC分类号: B01J27/24

    摘要: Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b   wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

    摘要翻译: 本发明提供一种金属催化剂配合物,其通过以下式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物:[M(L1)x(L'2)y(L3)z] a [Ani] b式1其中M是X族金属; [M(L1)x(L'2)y(L3)z]是阳离子预催化剂; L1是含阴离子烃基的配体; L'2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2≦̸ x + y + z≦̸ 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体,因此具有优异的热稳定性和反应性。