Hyperbranched polymer and process for production thereof
    12.
    发明授权
    Hyperbranched polymer and process for production thereof 有权
    超支化聚合物及其生产方法

    公开(公告)号:US08153744B2

    公开(公告)日:2012-04-10

    申请号:US12310804

    申请日:2007-09-04

    摘要: There is provided a novel hyperbranched polymer in which the refractive index is precisely controlled while retaining its hyperbranched structure, and a method for producing the hyperbranched polymer. Further, there is also provided an optically and thermally stable novel hyperbranched polymer in which the desired refractive index is precisely controlled, and a method for producing the hyperbranched polymer. The hyperbranched polymer has, as a branched structure, a repeating unit structure produced from two dithiocarbamate compounds each having a vinyl structure, at the polymerization initiation site having a vinyl structure. A specific example of the hyperbranched polymer can be produced by subjecting to a living radical polymerization N,N-diethyldithiocarbamylmethylstyrene in the presence of N,N-diethyldithiocarbamylethyl methacrylate.

    摘要翻译: 提供了一种新颖的超支化聚合物,其中折射率被精确地控制,同时保持其超支化结构,以及制备超支化聚合物的方法。 此外,还提供了光学和热稳定的新型超支化聚合物,其中精确控制所需的折射率,以及制备超支化聚合物的方法。 超支化聚合物作为支链结构具有由具有乙烯基结构的两个二硫代氨基甲酸酯化合物产生的重复单元结构,在聚合引发部位具有乙烯基结构。 超支化聚合物的具体实例可以通过在N,N-二乙基二硫代氨基甲酰基乙基甲基丙烯酸酯的存在下进行活性自由基聚合N,N-二乙基二硫代氨基甲酰基苯乙烯来制备。

    Hyperbranched Polymer and Method for Producing the Same
    13.
    发明申请
    Hyperbranched Polymer and Method for Producing the Same 审中-公开
    超支化聚合物及其制备方法

    公开(公告)号:US20100240792A1

    公开(公告)日:2010-09-23

    申请号:US12308567

    申请日:2007-06-13

    IPC分类号: C08F2/48 C08F228/02

    摘要: Disclosed is a novel hyperbranched polymer having a functional group in a molecular chain of a repeating unit. Also disclosed is a method for producing such a hyperbranched polymer. Specifically disclosed is a hyperbranched polymer having a repeating unit derived from a (meth)acrylate compound as a linear structure, while having a repeating unit derived from a dithiocarbamate compound having a vinyl group structure as a branched structure. This hyperbranched polymer can be obtained by holding a dithiocarbamate compound having a vinyl group structure and a (meth)acrylate compound together and subjecting them to a living radical polymerization.

    摘要翻译: 公开了一种在重复单元的分子链中具有官能团的新型超支化聚合物。 还公开了制备这种超支化聚合物的方法。 具体公开了具有衍生自(甲基)丙烯酸酯化合物的重复单元作为直链结构的超支化聚合物,同时具有衍生自具有乙烯基结构的二硫代氨基甲酸酯化合物作为支化结构的重复单元。 这种超支化聚合物可以通过将具有乙烯基结构的二硫代氨基甲酸酯化合物和(甲基)丙烯酸酯化合物一起保持并进行活性自由基聚合而获得。

    ELECTROCHROMIC MATERIAL
    14.
    发明申请
    ELECTROCHROMIC MATERIAL 失效
    电化学材料

    公开(公告)号:US20110149367A1

    公开(公告)日:2011-06-23

    申请号:US12991201

    申请日:2009-05-07

    IPC分类号: G02F1/15 C08F259/00 C09K3/00

    摘要: The present invention relates to an electrochromic polymer compound composed of a hyperbranched polymer having electrochromic characteristics derived from a quaternary pyridinium salt, a terephthalic acid diester or a biphenyl-4,4′-diester structure, and a varnish, a thin film structure and an electrochromic device that are obtained by the polymer compound. The electrochromic material has high response speed, high coloring efficiency, and excellent repetition stability and can be used for a long time, and has excellent solubility in various solvents.

    摘要翻译: 本发明涉及由具有源自季吡啶盐,对苯二甲酸二酯或联苯-4,4'-二酯结构的电致变色特征的超支化聚合物和清漆,薄膜结构和 通过高分子化合物获得的电致变色装置。 电致变色材料具有高响应速度,高着色效率和优异的重复稳定性,并且可长时间使用,并且在各种溶剂中具有优异的溶解性。

    Electrochromic material
    15.
    发明授权
    Electrochromic material 失效
    电致变色材料

    公开(公告)号:US08773745B2

    公开(公告)日:2014-07-08

    申请号:US12991201

    申请日:2009-05-07

    IPC分类号: G02F1/15 C08F8/30 C09K9/02

    摘要: The present invention relates to an electrochromic polymer compound composed of a hyperbranched polymer having electrochromic characteristics derived from a quaternary pyridinium salt, a terephthalic acid diester or a biphenyl-4,4′-diester structure, and a varnish, a thin film structure and an electrochromic device that are obtained by the polymer compound. The electrochromic material has high response speed, high coloring efficiency, and excellent repetition stability and can be used for a long time, and has excellent solubility in various solvents.

    摘要翻译: 本发明涉及由具有源自季吡啶盐,对苯二甲酸二酯或联苯-4,4'-二酯结构的电致变色特征的超支化聚合物和清漆,薄膜结构和 通过高分子化合物获得的电致变色装置。 电致变色材料具有高响应速度,高着色效率和优异的重复稳定性,并且可长时间使用,并且在各种溶剂中具有优异的溶解性。

    Polymer Structure Whose Surface and/or Interface Is Modified, and Method for Producing the Same
    16.
    发明申请
    Polymer Structure Whose Surface and/or Interface Is Modified, and Method for Producing the Same 审中-公开
    其表面和/或界面被修饰的聚合物结构及其制备方法

    公开(公告)号:US20090163657A1

    公开(公告)日:2009-06-25

    申请号:US12083690

    申请日:2006-10-24

    IPC分类号: C08F28/00 C08F14/00

    摘要: There is provided a novel, simple, general-purpose technique capable of being applied to the modification of the polymer surface and/or interface.A polymer structure whose surface and/or interface is modified is obtained by mixing a branched polymer (preferably a dendritic polymer, a comb-like polymer or a hyperbranched polymer) into a linear polymer as a matrix polymer to concentrate the branched polymer on the surface and/or interface of the matrix polymer.

    摘要翻译: 提供了一种可应用于聚合物表面和/或界面的改性的新颖简单的通用技术。 其表面和/或界面被改性的聚合物结构是通过将支化聚合物(优选树枝状聚合物,梳状聚合物或超支化聚合物)混合为线性聚合物作为基质聚合物而获得的,以将支化聚合物浓缩在表面上 和/或基质聚合物的界面。

    FILM-FORMING COMPOSITION
    18.
    发明申请
    FILM-FORMING COMPOSITION 有权
    成膜组合物

    公开(公告)号:US20130154043A1

    公开(公告)日:2013-06-20

    申请号:US13818546

    申请日:2011-08-23

    IPC分类号: C09D179/02 H01L31/0232

    摘要: A film-forming composition including a triazine ring-containing hyperbranched polymer with a repeating unit structure indicated by formula (1), and inorganic micro particles is provided. This enables the provision of a film-forming composition capable of hybridizing without reducing dispersion of the inorganic micro particles in a dispersion fluid, capable of depositing a coating film with a high refractive index, and suitable for electronic device film formation. (In the formula, R and R′ are mutually independent and indicate a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, or an aralkyl group, and Ar indicates a divalent organic group including either an aromatic ring or a heterocyclic ring, or both.)

    摘要翻译: 提供了包含具有式(1)所示重复单元结构的含三嗪环的超支化聚合物和无机微粒的成膜组合物。 这使得能够提供能够在不降低无机微粒在分散液中的分散性的成膜组合物,能够沉积高折射率的涂膜,并适用于电子器件成膜​​。 (式中,R和R'相互独立,表示氢原子,烷基,烷氧基,芳基或芳烷基,Ar表示包括芳香环或杂环的二价有机基团 环或两者)

    PRODUCTION PROCESS OF PHOSPHONIC ACID METAL SALT AND THERMOPLASTIC RESIN COMPOSITION CONTAINING PHOSPHONIC ACID METAL SALT
    19.
    发明申请
    PRODUCTION PROCESS OF PHOSPHONIC ACID METAL SALT AND THERMOPLASTIC RESIN COMPOSITION CONTAINING PHOSPHONIC ACID METAL SALT 审中-公开
    磷酸金属盐的生产工艺和含有磷酸金属盐的热塑性树脂组合物

    公开(公告)号:US20110196077A1

    公开(公告)日:2011-08-11

    申请号:US12878242

    申请日:2010-09-09

    CPC分类号: C08K5/5317 C07F9/3834

    摘要: A method for producing a phenylphosphonic acid metal salt, including reacting a phenylphosphonic acid compound (a) with a metal salt, metal oxide or metal hydroxide (b) that is present in an amount beyond the equivalent; a phenylphosphonic acid metal salt composition comprising a phenylphosphonic acid metal salt and surplus metal salt, surplus metal oxide or surplus metal hydroxide produced by the method; and a thermoplastic resin composition comprising the phenylphosphonic acid metal salt composition.

    摘要翻译: 苯基膦酸金属盐的制备方法,包括使苯基膦酸化合物(a)与金属盐,金属氧化物或金属氢氧化物(b)反应,其量超过当量; 包含苯基膦酸金属盐和多余金属盐的苯基膦酸金属盐组合物,通过该方法生产的剩余金属氧化物或剩余金属氢氧化物; 和包含苯基膦酸金属盐组合物的热塑性树脂组合物。

    PROCESS FOR PRODUCTION OF SURFACE-MODIFIED POLYMER STRUCTURES
    20.
    发明申请
    PROCESS FOR PRODUCTION OF SURFACE-MODIFIED POLYMER STRUCTURES 有权
    生产表面改性聚合物结构的方法

    公开(公告)号:US20100120984A1

    公开(公告)日:2010-05-13

    申请号:US12450778

    申请日:2008-04-23

    IPC分类号: C08L51/00 C08L41/00

    CPC分类号: C08J7/12 C08L101/005

    摘要: The present invention relates to a process for producing a polymer structure comprising: mixing and unifying a matrix polymer made of a linear polymer and a highly-branched polymer having hydrophilic functional groups at molecular ends and to form a structure containing the matrix polymer and the highly-branched polymer; and subjecting the obtained structure to either immersion in water and/or a hydrophilic solvent or exposure to an atmosphere of vapor of water and/or a hydrophilic solvent at a temperature ranging from a temperature lower than Tg of the matrix polymer by 30° C. to decomposition temperature of the matrix polymer; wherein the hydrophilic functional groups at the molecular ends of the highly-branched polymer are distributed in outermost surface of the polymer structure at an enhanced density. The present invention also relates to a process for producing a polymer structure in which vinyl polymer chains are grafted to at least a part of the hydrophilic functional groups.

    摘要翻译: 本发明涉及一种聚合物结构体的制造方法,其特征在于,在分子末端将由线性聚合物构成的基质聚合物和具有亲水性官能团的高支化聚合物混合均匀并形成含有基体聚合物的结构, 支链聚合物 并将得到的结构物浸入水和/或亲水性溶剂中或在低于基体聚合物的Tg的温度范围内暴露于水和/或亲水性溶剂的气体的气氛中30℃。 到基体聚合物的分解温度; 其中高度支化聚合物的分子末端的亲水官能团以增强的密度分布在聚合物结构的最外表面。 本发明还涉及其中乙烯基聚合物链接枝至至少一部分亲水官能团的聚合物结构的方法。