公开(公告)号：US08968601B2

公开(公告)日：2015-03-03

申请号：US13971182

申请日：2013-08-20

Applicant: Korea Institute of Science and Technology

Inventor： Dong Ju Moon ,  Yun Ju Lee ,  Jae Sun Jung ,  Jin Hee Lee ,  Seung Hwan Lee ,  Bang Hee Kim ,  Hyun Jin Kim ,  Eun Hyeok Yang

IPC: C01B3/26 ,  C01B3/38 ,  C07C1/02 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J20/00 ,  B01J21/04 ,  B01J23/89 ,  B01J23/78 ,  C01B3/40

CPC classification number: B01J23/8946 ,  B01J23/007 ,  B01J23/78 ,  B01J27/236 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/082 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52 ,  Y10S502/524 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/847

Abstract: Disclosed is a catalyst used for steam carbon dioxide reforming of natural gas, wherein an alkaline earth metal alone or an alkaline earth metal and a group 8B metal are supported on a hydrotalcite-like catalyst containing nickel, magnesium and aluminum. The disclosed catalyst is useful as a steam carbon dioxide reforming (SCR) catalyst of natural gas at high temperature and high pressure, while minimizing deactivation of the catalyst due to sintering of the active component nickel and deactivation of the catalyst due to coke generation at the same time. A synthesis gas prepared using the catalyst has a H2/CO molar ratio maintained at 1-2.2. A synthesis gas having a H2/CO molar ratio of 1.8-2.2 may be used as a raw material for Fischer-Tropsch synthesis or methanol synthesis and a synthesis gas having a H2/CO molar ratio of may be used as a raw material for dimethyl ether synthesis.

Abstract translation: 公开了用于天然气蒸汽二氧化碳重整的催化剂，其中单独的碱土金属或碱土金属和第8B族金属负载在含有镍，镁和铝的类水滑石催化剂上。 所公开的催化剂可用作天然气在高温和高压下的蒸汽二氧化碳重整（SCR）催化剂，同时使由于活性组分镍的烧结导致的催化剂失活最小化以及催化剂由于在 同时。 使用该催化剂制备的合成气的H 2 / CO摩尔比保持在1-2.2。 可以使用H 2 / CO摩尔比为1.8-2.2的合成气作为费 - 托合成或甲醇合成的原料，并且可以使用具有H 2 / CO摩尔比的合成气作为二甲基原料 醚合成。