公开(公告)号：US08946113B2

公开(公告)日：2015-02-03

申请号：US13909412

申请日：2013-06-04

Applicant: Korea Institute of Science and Technology

Inventor： Dong Ju Moon ,  Eun Hyeok Yang ,  Jin Hee Lee ,  Hyun Jin Kim ,  Byoung Sung Ahn ,  Sang Woo Kim ,  Jae Sun Jung

IPC: B01J21/02 ,  B01J23/83 ,  B01J23/78 ,  B01J23/755 ,  B01J23/745 ,  C01B3/38 ,  C01B3/40 ,  B01J37/03 ,  B01J35/10 ,  B01J37/00 ,  C01B3/00

CPC classification number: B01J23/83 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/031 ,  B01J2523/00 ,  C01B3/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1241 ,  Y02P20/142 ,  Y02P20/52 ,  Y10S502/525 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/847 ,  B01J2523/842

Abstract: The present invention relates to an Fe-modified perovskite-type catalyst, a method for preparing same and a method for preparing a synthesis gas by a combined reforming reaction using same. More particularly, it relates to a catalyst for a combined natural gas/steam/carbon dioxide reforming reaction having a perovskite structure with La and Sr introduced at the A site and Ni and Fe introduced at the B site with specific molar ratios and a method for producing a synthesis gas for Fischer-Tropsch synthesis or methanol synthesis using the catalyst by the combined reforming reaction. The catalyst of the present invention exhibits higher carbon dioxide conversion rate, significantly reduced catalyst deactivation caused by carbon deposition and improved long-term catalyst stability and activity, as compared to the existing catalyst for reforming reaction prepared by the impregnation method.

Abstract translation: 本发明涉及Fe改性的钙钛矿型催化剂及其制备方法以及通过使用它们的组合重整反应制备合成气的方法。 更具体地说，本发明涉及一种具有钙钛矿结构的合成天然气/蒸汽/二氧化碳重整反应的催化剂，其中在A位置引入La和Sr，并在B位上引入具有特定摩尔比的Ni和Fe， 使用催化剂通过组合的重整反应生产费 - 托合成或甲醇合成的合成气。 与通过浸渍法制备的用于重整反应的现有催化剂相比，本发明的催化剂显示较高的二氧化碳转化率，显着降低了由碳沉积引起的催化剂失活和改善的长期催化剂稳定性和活性。

公开(公告)号：US08968601B2

公开(公告)日：2015-03-03

申请号：US13971182

申请日：2013-08-20

Applicant: Korea Institute of Science and Technology

Inventor： Dong Ju Moon ,  Yun Ju Lee ,  Jae Sun Jung ,  Jin Hee Lee ,  Seung Hwan Lee ,  Bang Hee Kim ,  Hyun Jin Kim ,  Eun Hyeok Yang

IPC: C01B3/26 ,  C01B3/38 ,  C07C1/02 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J20/00 ,  B01J21/04 ,  B01J23/89 ,  B01J23/78 ,  C01B3/40

CPC classification number: B01J23/8946 ,  B01J23/007 ,  B01J23/78 ,  B01J27/236 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/082 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52 ,  Y10S502/524 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/847

Abstract: Disclosed is a catalyst used for steam carbon dioxide reforming of natural gas, wherein an alkaline earth metal alone or an alkaline earth metal and a group 8B metal are supported on a hydrotalcite-like catalyst containing nickel, magnesium and aluminum. The disclosed catalyst is useful as a steam carbon dioxide reforming (SCR) catalyst of natural gas at high temperature and high pressure, while minimizing deactivation of the catalyst due to sintering of the active component nickel and deactivation of the catalyst due to coke generation at the same time. A synthesis gas prepared using the catalyst has a H2/CO molar ratio maintained at 1-2.2. A synthesis gas having a H2/CO molar ratio of 1.8-2.2 may be used as a raw material for Fischer-Tropsch synthesis or methanol synthesis and a synthesis gas having a H2/CO molar ratio of may be used as a raw material for dimethyl ether synthesis.

Abstract translation: 公开了用于天然气蒸汽二氧化碳重整的催化剂，其中单独的碱土金属或碱土金属和第8B族金属负载在含有镍，镁和铝的类水滑石催化剂上。 所公开的催化剂可用作天然气在高温和高压下的蒸汽二氧化碳重整（SCR）催化剂，同时使由于活性组分镍的烧结导致的催化剂失活最小化以及催化剂由于在 同时。 使用该催化剂制备的合成气的H 2 / CO摩尔比保持在1-2.2。 可以使用H 2 / CO摩尔比为1.8-2.2的合成气作为费 - 托合成或甲醇合成的原料，并且可以使用具有H 2 / CO摩尔比的合成气作为二甲基原料 醚合成。