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公开(公告)号：US09834506B2
公开(公告)日：2017-12-05
申请号：US15102792
申请日：2014-12-18
IPC分类号： C07C255/22 , C07C253/10 , B01J21/06 , B01J23/02 , B01J23/04 , B01J23/06 , B01J23/10 , B01J27/236 , B01J27/26 , B01J31/06
CPC分类号： C07C255/22 , B01J21/066 , B01J23/02 , B01J23/04 , B01J23/06 , B01J23/10 , B01J27/236 , B01J27/26 , B01J31/06 , C07C253/10 , C07C255/09
摘要： The present invention relates to an improved process for addition of hydrogen cyanide across olefins and, in particular, to the use of a specific aluminum oxide to catalyze the reaction. The aluminum oxide catalyst must have total alkali metal and/or alkaline earth metal content, measured in the form of alkali metal oxide and/or alkaline earth metal oxide, of less than 3,000 ppm by weight.
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公开(公告)号：US09637689B2
公开(公告)日：2017-05-02
申请号：US13560377
申请日：2012-07-27
IPC分类号： C10G29/02 , C10G29/16 , C10G19/02 , B01J37/06 , B01J23/00 , B01J23/06 , B01J27/236 , C10G25/00
CPC分类号： C10G29/16 , B01J21/04 , B01J21/10 , B01J23/007 , B01J23/06 , B01J27/236 , B01J37/06 , C10G19/02 , C10G25/003 , C10G2300/203 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/80
摘要： A process is described for reducing the total acid number of a refinery feedstock. In one embodiment, refinery feedstock containing naphthenic acids is contacted with an effective amount of solid catalyst in the presence of an aqueous caustic base, wherein the caustic base is sodium hydroxide or potassium hydroxide, for a period of time sufficient to neutralize at least a portion of the naphthenic acids in the feedstock. Thereafter, the aqueous phase is separated from the neutralized refinery feedstock. In another embodiment catalyst is pretreated with a caustic base solution and contacted with refinery feedstock to reducing the total acid number.
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公开(公告)号：US09636665B2
公开(公告)日：2017-05-02
申请号：US13883686
申请日：2011-12-01
IPC分类号： C07C27/06 , B01J27/236 , B01J23/00 , B01J23/28 , C07C29/153
CPC分类号： B01J27/236 , B01J23/007 , B01J23/28 , C07C27/06 , C07C29/153 , C07C31/08 , C07C31/10
摘要： Catalyst compositions for production of higher alcohols comprise a hydrotalcite or hydrotalcite-like support impregnated with molybdenum and an alkali metal. When the compositions are used to convert syngas, selectivity to higher (C2+) alcohols is increased in comparison to conversions accomplished over many other catalyst systems.
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公开(公告)号：US20170107116A1
公开(公告)日：2017-04-20
申请号：US15129137
申请日：2015-03-25
IPC分类号： C01F11/18 , B01J27/25 , B01J27/053 , B01J31/26 , B01J31/28 , B01J31/02 , B01J35/10 , B01J35/02 , B01J37/03 , B01J37/02 , B01J20/22 , B01J20/04 , B01J20/08 , B01J20/28 , B01J20/30 , C09D1/00 , C01F11/46 , C01F11/36 , C01G53/00 , C01G51/00 , C01G3/00 , B01J27/236
CPC分类号： C01F11/18 , B01J20/041 , B01J20/043 , B01J20/045 , B01J20/08 , B01J20/22 , B01J20/28016 , B01J20/28061 , B01J20/3085 , B01J27/053 , B01J27/236 , B01J27/25 , B01J31/0208 , B01J31/26 , B01J31/28 , B01J35/026 , B01J35/1019 , B01J37/0236 , B01J37/031 , C01F7/002 , C01F7/004 , C01F7/005 , C01F11/36 , C01F11/46 , C01G3/006 , C01G51/006 , C01G53/006 , C01P2002/22 , C01P2002/72 , C01P2004/03 , C01P2004/50 , C01P2004/60 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C09D1/00
摘要： Layered double hydroxides having a high surface area (at least 125 m2/g) and the formula (I) [Mz+1-xM′y+x(OH)2]a+(Xn-)a/n+bH2O.c(AMO-solvent) (I) wherein M and M′ are different and each is a charged metal cation (and must be present), z=1 or 2; y=3 or 4, 0
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公开(公告)号：US20170022175A1
公开(公告)日：2017-01-26
申请号：US15207312
申请日：2016-07-11
发明人： Bal Rajaram , Pendem Chandrashekar , Bordoloi Ankur , Konathala Laxmi Narayan Sivakumar , Manoj Kumar , Saran Sandeep
IPC分类号： C07D307/33 , B01J37/02 , B01J37/08 , B01J37/18 , B01J23/42 , B01J27/236
CPC分类号： C07D307/33 , B01J21/16 , B01J23/007 , B01J23/42 , B01J27/236 , B01J37/0201 , B01J37/0207 , B01J37/088 , B01J37/18
摘要： The present invention provides a process for the hydrogenation of the levulinic acid to γ-valerolactone in a single step with a single Pt supported on hydrotalcite catalyst. The process provides conversion of γ-valerolactone over Pt supported hydrotalcite catalyst at room temperature (25° C.). The process provides a levulinic acid conversion of 34-100% with 20-50 bar hydrogen pressure to give γ-valerolactone selectivity up to 99%.
摘要翻译： 本发明提供了在单一步骤中将乙酰丙酸氢化为γ-戊内酯的方法，其中单一Pt负载在水滑石催化剂上。 该方法在室温（25℃）下提供γ-戊内酯与Pt负载的水滑石催化剂的转化。 该方法在20-50巴氢压下提供34-100％的乙酰丙酸转化率，得到高达99％的γ-戊内酯选择性。
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公开(公告)号：US20160214859A1
公开(公告)日：2016-07-28
申请号：US15089085
申请日：2016-04-01
发明人： Jorge N. Beltramini , Moses O. Adebajo , Joao Carlos Diniz Da Costa , Gao Qing Lu , Thang V. Pham , Sai P. Katikaneni
IPC分类号： C01B3/48
CPC分类号： C01B3/48 , B01J8/0411 , B01J23/007 , B01J23/464 , B01J23/75 , B01J23/755 , B01J23/78 , B01J23/8913 , B01J27/236 , B01J35/0006 , B01J35/002 , B01J35/0053 , B01J35/006 , B01J35/04 , B01J35/065 , B01J37/009 , B01J37/0201 , B01J37/0215 , B01J37/0236 , B01J37/0244 , B01J37/031 , B01J37/036 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/082 , B01J37/18 , B01J2523/00 , C01B3/40 , C01B3/503 , C01B2203/0244 , C01B2203/0283 , C01B2203/041 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1235 , C01B2203/142 , Y02P20/52 , B01J2523/22 , B01J2523/31 , B01J2523/847
摘要： An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide particles dispersed homogenously throughout the support structure.
摘要翻译： 一种用于从液态烃，蒸汽和氧气源产生氢气的自热重整催化结构。 自热重整催化结构包括均匀分散在整个载体结构中的载体结构和纳米级混合金属氧化物颗粒。
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公开(公告)号：US20160052949A1
公开(公告)日：2016-02-25
申请号：US14817920
申请日：2015-08-04
IPC分类号： C07G1/00 , C07C45/51 , B01J27/236
CPC分类号： C07G1/00 , B01J23/007 , B01J23/755 , B01J27/236 , B01J35/002 , B01J37/0201 , B01J37/031 , C07C45/513 , C10G1/086 , C10G2300/1014 , Y02P30/20
摘要： Solid base catalysts and their use for the base-catalyzed depolymerization (BCD) of lignin to compounds such as aromatics are presented herein. Exemplary catalysts include layered double hydroxides (LDHs) as recyclable, heterogeneous catalysts for BCD of lignin.
摘要翻译： 固体碱催化剂及其用于木质素对芳族化合物的碱催化解聚（BCD）的用途。 示例性催化剂包括作为可回收的木质素BCD的多相催化剂的层状双氢氧化物（LDH）。
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公开(公告)号：US20130224095A1
公开(公告)日：2013-08-29
申请号：US13773975
申请日：2013-02-22
申请人： INTERCAT, INC.
发明人： MARTIN EVANS , XUNHUA MO , RAYMOND PAUL FLETCHER
IPC分类号： B01D53/56
CPC分类号： B01D53/56 , B01D53/8628 , B01D53/8631 , B01D2255/2065 , B01J23/22 , B01J23/42 , B01J23/44 , B01J23/78 , B01J23/83 , B01J23/94 , B01J23/96 , B01J27/236 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/0045 , B01J37/031 , C10G11/182 , C10G2300/405
摘要： The invention includes a process for reducing the amount of NOx discharged to atmosphere from a FCC unit, having a regenerator and a means for collecting and supporting catalyst particles. The process comprises adding a catalyst to the regenerator flue gas prior to entering the collecting means and precipitating the catalyst in the collecting means to form a catalyst bed. Ammonia or ammonia precursor is added to the flue gas prior to and/or within the collecting means. The flue gas NOx is reacted with the ammonia or ammonia precursor at 200° C. to 800° C. in the presence of the catalyst bed to reduce the NOx amount, and the flue gas containing a reduced amount of NOx is discharged to atmosphere. The catalyst is one or more supported transition or lanthanide metal catalysts. The process can also be utilized in any combustion process.
摘要翻译： 本发明包括一种减少从具有再生器的FCC装置排放到大气中的NOx的量和用于收集和支撑催化剂颗粒的装置的方法。 该方法包括在进入收集装置之前向再生器烟气中加入催化剂，并将催化剂沉淀在收集装置中以形成催化剂床。 在收集装置之前和/或内部，将氨或氨前体加入烟道气中。 在催化剂床的存在下，烟道气NO x与氨或氨前体在200〜800℃下反应，以减少NOx量，并且将含有减少量的NOx的废气排放到大气中。 催化剂是一种或多种负载型过渡金属或镧系金属催化剂。 该方法也可用于任何燃烧过程。
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公开(公告)号：US20130037448A1
公开(公告)日：2013-02-14
申请号：US13560377
申请日：2012-07-27
CPC分类号： C10G29/16 , B01J21/04 , B01J21/10 , B01J23/007 , B01J23/06 , B01J27/236 , B01J37/06 , C10G19/02 , C10G25/003 , C10G2300/203 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/80
摘要： A process is described for reducing the total acid number of a refinery feedstock. In one embodiment, refinery feedstock containing naphthenic acids is contacted with an effective amount of solid catalyst in the presence of an aqueous caustic base, wherein the caustic base is sodium hydroxide or potassium hydroxide, for a period of time sufficient to neutralize at least a portion of the naphthenic acids in the feedstock. Thereafter, the aqueous phase is separated from the neutralized refinery feedstock. In another embodiment catalyst is pretreated with a caustic base solution and contacted with refinery feedstock to reducing the total acid number.
摘要翻译： 描述了一种降低炼油原料总酸值的方法。 在一个实施方案中，含有环烷酸的炼油原料在苛性碱水溶液存在下与有效量的固体催化剂接触，其中苛性碱为氢氧化钠或氢氧化钾，时间足以中和至少一部分 的原料中的环烷酸。 此后，将水相与中和的炼油原料分离。 在另一个实施方案中，催化剂用苛性碱溶液预处理并与炼油原料接触以降低总酸值。
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公开(公告)号：US20120258857A1
公开(公告)日：2012-10-11
申请号：US13083899
申请日：2011-04-11
申请人： Thang V. Pham , Sai P. Katikaneni , Jorge N. Beltramini , Moses O. Adebajo , Joao Carlos Diniz Da Costa , G.Q. Lu
发明人： Thang V. Pham , Sai P. Katikaneni , Jorge N. Beltramini , Moses O. Adebajo , Joao Carlos Diniz Da Costa , G.Q. Lu
IPC分类号： B01J37/03 , B01J37/08 , B01J37/18 , B01J37/06 , B01J35/10 , B01J37/04 , B01J21/02 , B82Y30/00 , B82Y40/00
CPC分类号： C01B3/48 , B01J8/0411 , B01J23/007 , B01J23/464 , B01J23/75 , B01J23/755 , B01J23/78 , B01J23/8913 , B01J27/236 , B01J35/0006 , B01J35/002 , B01J35/0053 , B01J35/006 , B01J35/04 , B01J35/065 , B01J37/009 , B01J37/0201 , B01J37/0215 , B01J37/0236 , B01J37/0244 , B01J37/031 , B01J37/036 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/082 , B01J37/18 , B01J2523/00 , C01B3/40 , C01B3/503 , C01B2203/0244 , C01B2203/0283 , C01B2203/041 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1235 , C01B2203/142 , Y02P20/52 , B01J2523/22 , B01J2523/31 , B01J2523/847
摘要： An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide, particles dispersed homogenously throughout the support structure.
摘要翻译： 一种用于从液态烃，蒸汽和氧气源产生氢气的自热重整催化结构。 自热重整催化结构包括支撑结构和纳米级混合金属氧化物，颗粒均匀分散在整个支撑结构中。
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