摘要:
A method for preparing a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula Mmn+Cgh+Rrp+Al(1-x)ExSiyOz The method includes forming a Charge Density Mismatch (CDM) reaction mixture comprising reactive sources of Al, Si, optionally a framework element, E, and at least one organic nitrogen containing cation template, C, in the hydroxide form. After the CDM mixture is mixed while aging, an organic cation crystallization template, R, and at least one alkali metal or alkaline earth metal, M, is added. The combined final reaction mixture is reacted with mixing to produce the zeolite, which may be used in various hydrocarbon conversion processes.
摘要:
A process for alkylating aromatic compounds using a family of zeolites, examples of which have been designated UZM-5, UZM-5P and UZM-6, and are represented by the empirical formula: Mmn+Cgh+Rrp+Al(1-x)ExSiyOz where M is an alkali or alkaline earth metal, E is an optional framework element, C organic nitrogen containing cation template, and R is an organic cation crystallization template. The zeolites have at least two x-ray diffraction peaks, one at a d-spacing of 3.9±0.12 Å and one at a d-spacing 8.6±0.20 Å; a tetragonal unit cell; and a micropore volume ranging from about 0.10 cc/g to about 0.18 cc/g.
摘要:
The present invention comprises a hydrocarbon-conversion process using an improved MgMxAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.
摘要:
The present invention comprises an improved MgMxAPSO-31 molecular sieve and a catalyst composite which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises a at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.