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    Hydrocarbon Conversion Using An Improved Molecular Sieve
    1.
    发明申请
    Hydrocarbon Conversion Using An Improved Molecular Sieve 失效
    使用改进的分子筛的烃转化

    公开(公告)号：US20100152512A1

    公开(公告)日：2010-06-17

    申请号：US12365584

    申请日：2009-02-04

    申请人： Hayim Abrevaya ,  Julio C. Marte ,  John E. Bauer

    发明人： Hayim Abrevaya ,  Julio C. Marte ,  John E. Bauer

    IPC分类号： C07C5/22

    CPC分类号： C07C5/2737 ,  C07C5/2775 ,  C07C15/08

    摘要： The present invention comprises a hydrocarbon-conversion process using an improved MgMxAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.

    摘要翻译： 本发明包括使用改进的MgMxAPSO-31分子筛的烃转化方法，其表现出芳烃转化率的转化率和选择性的有利组合。 该筛包含至少两个具有限定晶体特征的骨架结构中具有窄比浓度极限的二价元素。 元素Mx可以包含锰，钴，镍，铁和锌中的一种或多种。

    Hydrocarbon conversion using an improved molecular sieve
    3.
    发明授权
    Hydrocarbon conversion using an improved molecular sieve 失效
    使用改进的分子筛进行烃转化

    公开(公告)号：US08431760B2

    公开(公告)日：2013-04-30

    申请号：US12365584

    申请日：2009-02-04

    申请人： Hayim Abrevaya ,  Julio C. Marte ,  John E. Bauer

    发明人： Hayim Abrevaya ,  Julio C. Marte ,  John E. Bauer

    IPC分类号： C07C5/22

    CPC分类号： C07C5/2737 ,  C07C5/2775 ,  C07C15/08

    摘要： The present invention comprises a hydrocarbon-conversion process using an improved MgMxAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.

    摘要翻译： 本发明包括使用改进的MgMxAPSO-31分子筛的烃转化方法，其表现出芳烃转化率的转化率和选择性的有利组合。 该筛包含至少两个具有限定晶体特征的骨架结构中具有窄比浓度极限的二价元素。 元素Mx可以包含锰，钴，镍，铁和锌中的一种或多种。

    Molecular Sieve
    5.
    发明申请
    Molecular Sieve 审中-公开
    分子筛

    公开(公告)号：US20100152025A1

    公开(公告)日：2010-06-17

    申请号：US12365545

    申请日：2009-02-04

    申请人： Hayim Abrevaya ,  Julio C. Marte

    发明人： Hayim Abrevaya ,  Julio C. Marte

    IPC分类号： B01J29/068 ,  C01B39/02 ,  B01J29/06

    CPC分类号： C01B39/54 ,  B01J23/42 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2708 ,  Y02P20/52 ,  C07C15/08

    摘要： The present invention comprises an improved MgMxAPSO-31 molecular sieve and a catalyst composite which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises a at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.

    摘要翻译： 本发明包括改进的MgMxAPSO-31分子筛和催化剂复合物，其表现出在芳烃转化中转化率和选择性的有利组合。 该筛包括具有限定的晶体特性的骨架结构中具有窄特定浓度限度的至少两个二价元素。 元素Mx可以包含锰，钴，镍，铁和锌中的一种或多种。

    Process for Preparing a Dielectric Interlayer Film Containing Silicon Beta Zeolite
    6.
    发明申请
    Process for Preparing a Dielectric Interlayer Film Containing Silicon Beta Zeolite 失效
    制备含硅β沸石的介电层间膜的方法

    公开(公告)号：US20090197426A1

    公开(公告)日：2009-08-06

    申请号：US12356201

    申请日：2009-01-20

    申请人： Hayim Abrevaya ,  Richard R. Willis ,  Stephen T. Wilson

    发明人： Hayim Abrevaya ,  Richard R. Willis ,  Stephen T. Wilson

    IPC分类号： H01L21/31 ,  B01J29/04

    CPC分类号： C01B39/026 ,  H01L21/31695

    摘要： A process for forming a zeolite beta dielectric layer onto a substrate such as a silicon wafer has been developed. The zeolite beta is characterized in that it has an aluminum concentration from about 0.1 to about 2.0 wt. %, and has crystallites from about 5 to about 40 nanometers. The process involves first dealuminating a starting zeolite beta, then preparing a slurry of the dealuminated zeolite beta followed by coating a substrate, e.g. silicon wafer with the slurry, heating to form a zeolite beta film and treating the zeolite beta with a silylating agent.

    摘要翻译： 已经开发了用于在诸如硅晶片的基底上形成沸石β电介质层的工艺。 沸石β的特征在于其铝浓度为约0.1至约2.0重量％。 并具有约5至约40纳米的微晶。 该方法首先对起始沸石β进行脱铝，然后制备脱铝沸石β的浆料，然后涂覆底物，例如。 硅晶片与浆料，加热形成沸石β膜并用甲硅烷基化剂处理沸石β。

    Process for removing polymeric by-products from acetylene hydrogenation product
    8.
    发明授权
    Process for removing polymeric by-products from acetylene hydrogenation product 失效
    从乙炔氢化产物中除去聚合物副产物的方法

    公开(公告)号：US6015933A

    公开(公告)日：2000-01-18

    申请号：US115481

    申请日：1998-07-15

    申请人： Hayim Abrevaya ,  Bipin V. Vora

    发明人： Hayim Abrevaya ,  Bipin V. Vora

    IPC分类号： C07C7/00 ,  C07C7/10

    CPC分类号： C07C7/005 ,  C07C7/10

    摘要： A process to remove polymeric by-products from the product of an acetylene selective hydrogenation reactor has been developed. The product is generated by introducing hydrogen and a liquid hydrocarbon stream containing largely butadiene and some acetylenes to a reactor containing a catalyst effective for the selective hydrogenation of acetylenes. The product contains at least hydrogen, butadiene, and polymeric by-products. The pressure of the product is reduced and the product cooled. The cooled product is conducted to a low pressure flash drum to produce a hydrogen enriched stream and a butadiene and polymeric by-product-enriched stream. The hydrogen-enriched stream is removed. The butadiene and polymeric by-product is passed to a knockout drum to produce a stream enriched in butadiene and polymeric by-products having less than about 12 carbon atoms and a stream enriched in polymeric by-products having about 12 or more carbon atoms. The stream enriched in polymeric by-products having about 12 or more carbon atoms is removed from the process. Polymeric by-products containing less than about 12 carbon atoms may be removed from the remaining stream by conducting a solvent and the stream enriched in butadiene and polymeric by-products containing less than about 12 carbon atoms to an extractive distillation column. In the extractive distillation column, the butadiene and polymeric by-products containing less than about 12 carbon atoms are carried with the solvent and removed in a bottoms stream as an extract mixture while the butanes and butenes are removed in an extractive distillation overhead stream. The bottoms extract stream is conducted to a stripper column where the solvent and the polymeric by-products are separated from the butadiene.

    摘要翻译： 已经开发了从乙炔选择性氢化反应器的产物中除去聚合物副产物的方法。 该产物通过将含有大量丁二烯和一些乙炔的氢气和液体烃流引入含有对乙炔的选择性氢化有效的催化剂的反应器而产生。 该产品至少含有氢，丁二烯和聚合副产物。 产品的压力降低，产品冷却。 冷却的产物被传导到低压闪蒸鼓以产生富氢流和丁二烯和聚合副产物富集流。 除去富氢流。 丁二烯和聚合副产物被传送到分离鼓中以产生富含丁二烯的流和具有小于约12个碳原子的聚合副产物和富含约12个或更多个碳原子的聚合副产物的物流。 从该方法中除去富含约12个或更多个碳原子的聚合副产物的物流。 含有少于约12个碳原子的聚合副产物可以通过将富含丁二烯的溶剂和含有少于约12个碳原子的聚合副产物的物流引入萃取蒸馏塔从剩余物流中除去。 在萃取蒸馏塔中，含有少于约12个碳原子的丁二烯和聚合副产物与溶剂一起携带并在塔底物流中作为提取物混合物除去，同时在萃取蒸馏塔顶馏出物中除去丁烷和丁烯。 将塔底提取物流引入汽提塔，其中溶剂和聚合副产物与丁二烯分离。

    Hydrocarbon conversion process utilizing surface impregnated catalyst
    9.
    发明授权
    Hydrocarbon conversion process utilizing surface impregnated catalyst 失效
    使用表面浸渍催化剂的烃转化方法

    公开(公告)号：US4973779A

    公开(公告)日：1990-11-27

    申请号：US434964

    申请日：1989-11-09

    申请人： Tamotsu Imai ,  Hayim Abrevaya

    发明人： Tamotsu Imai ,  Hayim Abrevaya

    IPC分类号： B01J23/62 ,  B01J23/656 ,  B01J35/00 ,  C10G45/00

    CPC分类号： B01J23/622 ,  B01J23/6567 ,  B01J35/0006 ,  C10G45/00

    摘要： A hydrocarbon conversion process which utilizes a novel catalytic composite is disclosed. The catalyst composite comprises a platinum group metal component, a first modifier selected from Group IA and IIA elements of the Periodic Table, a second modifier component selected from the group of elements consisting of palladium, iridium, and osmium, and a third modifier component selected from the elements of Group IVA of the Periodic Table of the Elements. All of the catalytic components are located on a refractory oxide support having a nominal diameter (d) of from 50 to 10,000 microns. The catalytic composite is characterized in that the second modifier components is surface-impregnated upon the support in such a manner that the average concentration of the surface-impregnated second modifier component on the outside 0.2d micron catalyst layer is at least 2 times the average concentration of the second modifier component in 0.4d micron diameter center core of the catalyst where d is the nominal diameter, and wherein the first modifier metal component is uniformly impregnated. The process has been found to be most useful in the dehydrogenation of dehydrogenatable hydrocarbons.

    摘要翻译： 公开了一种利用新型催化复合材料的烃转化方法。 催化剂复合材料包括铂族金属组分，选自元素周期表IA和IIA族元素的第一改性剂，选自钯，铱和锇的元素组的第二改性剂组分和选自第三种改性剂组分 从元素周期表第IVA部分的要素。 所有催化组分位于公称直径（d）为50至10,000微米的难熔氧化物载体上。 催化复合材料的特征在于，第二改性剂组分以这样的方式表面浸渍在载体上，使得外部0.2d微米催化剂层上的表面浸渍的第二改性剂组分的平均浓度为平均浓度的至少2倍 的第二改性剂组分在催化剂的0.4d微米直径中心核心中，其中d是公称直径，并且其中第一改性剂金属组分被均匀地浸渍。 已经发现该方法在可脱氢烃的脱氢中最有用。