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11.发明授权公开(公告)号：US07211692B2
公开(公告)日：2007-05-01
申请号：US10961110
申请日：2004-10-12
IPC分类号： C07C51/16
CPC分类号： C07C51/252 , C07C57/04
摘要： A process for the long-term operation of a two-stage heterogeneously catalyzed gas phase partial oxidation of propene to acrylic acid, in which the temperature of the fixed catalyst beds is increased over the time and the gas phase partial oxidation is interrupted from time to time and an oxygen-containing gas mixture is conducted through the fixed catalyst beds at elevated temperature of the fixed catalyst beds.
摘要翻译： 长期运行丙烯到丙烯酸的两阶段非均相催化气相部分氧化丙烯酸的方法，其中固定催化剂床的温度随时间增加，气相部分氧化从时间到 时间和含氧气体混合物通过固定催化剂床在固定催化剂床的升高温度下进行。
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12.发明授权Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid 有权丙烯醛的异相催化部分气相氧化成丙烯酸公开(公告)号：US06982347B2
公开(公告)日：2006-01-03
申请号：US10806460
申请日：2004-03-23
IPC分类号： C07C51/235
CPC分类号： C07C51/252 , C07C57/04
摘要： In a process for partially oxidizing acrolein to acrylic acid in the gas phase under heterogeneous catalysis, the starting reaction gas mixture is oxidized at an acrolein loading of ≦145 and ≧70 l (STP) of acrolein/l of fixed catalyst bed·h over a fixed catalyst bed which is accommodated in two successive reaction zones A, B, the highest temperature of the reaction gas mixture within reaction zone A being above the highest temperature of the reaction gas mixture within reaction zone B.
摘要翻译： 在非均相催化下在气相中将丙烯醛部分氧化为丙烯酸的方法中，起始反应气体混合物以丙烯醛负载<= 145和> = 70l（STP）的丙烯醛/ l固定催化剂床进行氧化。 h在固定的催化剂床上，其被容纳在两个连续的反应区A，B中，反应区A内的反应气体混合物的最高温度高于反应区B内的反应气体混合物的最高温度。
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公开(公告)号：US20050038291A1
公开(公告)日：2005-02-17
申请号：US10917414
申请日：2004-08-13
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound over a fresh fixed catalyst bed, in which the process is started up at a reduced hourly space velocity of charging gas mixture on the fixed catalyst bed.
摘要翻译： 通过在新鲜的固定催化剂床上的有机前体化合物的非均相催化气相部分氧化制备（甲基）丙烯醛和/或（甲基）丙烯酸的方法，其中该方法以减小的小时空速充电开始 固定催化剂床上的气体混合物。
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公开(公告)号：US07015354B2
公开(公告)日：2006-03-21
申请号：US10917414
申请日：2004-08-13
申请人： Jochen Petzoldt , Signe Unverricht , Heiko Arnold , Klaus Joachim Müller-Engel , Martin Dieterle
发明人： Jochen Petzoldt , Signe Unverricht , Heiko Arnold , Klaus Joachim Müller-Engel , Martin Dieterle
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound over a fresh fixed catalyst bed, in which the process is started up at a reduced hourly space velocity of charging gas mixture on the fixed catalyst bed.
摘要翻译： 通过在新鲜的固定催化剂床上的有机前体化合物的非均相催化气相部分氧化制备（甲基）丙烯醛和/或（甲基）丙烯酸的方法，其中该方法以减小的小时空速充电开始 固定催化剂床上的气体混合物。
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15.发明授权Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid 有权将丙烯非均相催化部分气相氧化成丙烯酸公开(公告)号：US06888024B2
公开(公告)日：2005-05-03
申请号：US10799754
申请日：2004-03-15
CPC分类号： B01J23/002 , B01J23/8876 , B01J23/8877 , B01J35/0006 , B01J37/0221 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/842 , B01J2523/845
摘要： In a process for heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, the starting reaction gas mixture is oxidized at a propene loading of
摘要翻译： 在将丙烯非均相催化的部分气相氧化成丙烯酸的过程中，起始反应气体混合物在第一反应阶段中以<160l（STP）/ 1h的丙烯负载量在被容纳的固定催化剂床1上被氧化 在两个连续的反应区A，B和第一反应阶段的含丙烯醛的产物气体混合物随后在第二反应阶段中在固定的催化剂床2上氧化，固定的催化剂床2容纳在两个连续的反应区C，D中， 反应区A内的反应气体混合物的最高温度高于反应区B内反应气体混合物的最高温度，反应区C内的反应气体混合物的最高温度高于反应气体混合物的最高温度 区D.
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16.发明授权公开(公告)号：US08076510B2
公开(公告)日：2011-12-13
申请号：US12107420
申请日：2008-04-22
申请人： Ulrich Hammon , Thorsten Friese , Jochen Petzoldt , Klaus Joachim Mueller-Engel , Ulrich Cremer , Andreas Raichle
发明人： Ulrich Hammon , Thorsten Friese , Jochen Petzoldt , Klaus Joachim Mueller-Engel , Ulrich Cremer , Andreas Raichle
IPC分类号： C07C51/16
CPC分类号： B01J8/067 , B01J23/002 , B01J23/8885 , B01J27/199 , B01J35/0006 , B01J2208/00212 , B01J2208/00221 , B01J2208/00513 , B01J2208/025 , B01J2219/30207 , B01J2219/30215 , B01J2523/00 , C07C51/235 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/17 , B01J2523/55 , B01J2523/15 , B01J2523/51 , B01J2523/53 , B01J2523/62
摘要： A process for starting-up a heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid or of methacrolein to methacrylic acid over a fixed catalyst bed disposed in a tube bundle reactor cooled by a heat exchange medium, wherein the temperature of the heat exchange medium is ≧290° C. and the temperature of that reactor plate surface which faces the reaction gas entry mixture and the temperature of the reaction gas entry mixture itself are ≦285° C.
摘要翻译： 一种在由热交换介质冷却的管束反应器中的固定催化剂床上启动丙烯醛异丙烯醛至丙烯醛或甲基丙烯醛至甲基丙烯酸的非均相催化部分气相氧化方法，其中热交换介质的温度 ≧290℃，反应气体入口混合物的反应器板表面的温度和反应气体入口混合物本身的温度为285℃
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公开(公告)号：US07777082B2
公开(公告)日：2010-08-17
申请号：US10934525
申请日：2004-09-07
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/108 , B01J37/0018 , B01J37/0063 , B01J37/08 , B01J2523/00 , C07C45/35 , C07C45/37 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845
摘要： A process for preparing annular unsupported catalysts by thermally treating annular shaped unsupported catalyst precursor bodies, wherein the side crushing strength of the annular shaped unsupported catalyst precursor bodies is ≧12 N and ≦23 N; such precursor bodies per se; annular unsupported catalysts having a specific pore structure; and a method of using such annular unsupported catalysts for the catalytic partial oxidative preparation in the gas phase of (meth)acrolein.
摘要翻译： 一种通过热处理环形的未负载的催化剂前体体来制备环形的未负载的催化剂的方法，其中环形的未负载的催化剂前体体的侧面破碎强度为≥12N和＆lt; NlE; 23N; 这样的前体体本身; 具有特定孔结构的环状无载体催化剂; 以及在（甲基）丙烯醛气相中使用这种环状无载体催化剂用于催化部分氧化制备的方法。
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18.发明授权Process for recharging the reaction tubes of a tube bundle reactor with a new fixed catalyst bed 有权用新的固定催化剂床对管束反应器的反应管再充电的方法公开(公告)号：US09126171B2
公开(公告)日：2015-09-08
申请号：US12130116
申请日：2008-05-30
申请人： Volker Schliephake , Klaus Bott , Rolf-Dieter Becher , Klaus Joachim Mueller-Engel , Jochen Petzoldt , Ulrich Cremer , Andreas Raichle
发明人： Volker Schliephake , Klaus Bott , Rolf-Dieter Becher , Klaus Joachim Mueller-Engel , Jochen Petzoldt , Ulrich Cremer , Andreas Raichle
CPC分类号： C07C51/252 , B01J8/0045 , B01J8/06 , B01J2208/00761 , B08B9/0436 , C07C45/35
摘要： A process for recharging the reaction tubes of a tube bundle reactor with a new fixed catalyst bed, in which a heterogeneously catalyzed partial gas phase oxidation of an organic compound had been performed beforehand in a preceding fixed catalyst bed comprising Mo-comprising multielement oxide active compositions to form a steam-comprising product gas mixture, in which, before the recharge, solid deposit which had been deposited on the tube inner walls and comprises molybdenum oxide and/or molybdenum oxide hydrate is brushed away with the aid of a brush.
摘要翻译： 一种用新的固定催化剂床对管束反应器的反应管进行再充电的方法，其中在先前的包含含钼的多元素氧化物活性组合物的固定催化剂床中预先进行了有机化合物的非均相催化的部分气相氧化 以形成含蒸汽的产物气体混合物，其中在再充电之前，已经沉积在管内壁上并且包含氧化钼和/或氧化钼水合物的固体沉积物借助于刷子被刷洗掉。
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19.发明授权Heterogeneous catalyst for the preparation of acrolein by partial gas phase oxidation of propene 有权通过丙烯的部分气相氧化制备丙烯醛的非均相催化剂公开(公告)号：US07772148B2
公开(公告)日：2010-08-10
申请号：US11627573
申请日：2007-01-26
IPC分类号： B01J27/192 , B01J21/00 , B01J23/00
CPC分类号： B01J35/026 , B01J23/8885 , B01J35/0006 , C07C45/35 , C07C47/22
摘要： An annular unsupported catalyst for the heterogeneously catalyzed partial gas phase oxidation of propene to acrolein at a propene hourly space velocity on the fixed catalyst bed of ≧120 1 (STP)/1·h and a total CO2 and saturated hydrocarbon content of the starting reaction gas mixture of below 15 mol %, the catalysts of the fixed catalyst bed are the annular unsupported catalysts whose active composition is a multimetal oxide in which the molar Co/Fe ratio=from 2 to 4 and the molar Co/Mo ratio=from 0.3 to 0.7.
摘要翻译： 一种环状无载体催化剂，用于丙烯到丙烯醛的非均相催化部分气相氧化，丙烯醛在固定催化剂床上的丙烯小时空速为≥1201（STP）/ 1·h，起始反应的总CO 2和饱和烃含量为 低于15mol％的气体混合物，固定催化剂床的催化剂是环状无载体催化剂，其活性组成是多金属氧化物，其中Co / Fe比为2-4，Co / Mo摩尔比为0.3 至0.7。
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公开(公告)号：US20120296108A1
公开(公告)日：2012-11-22
申请号：US13562552
申请日：2012-07-31
申请人： Andreas Raichle , Catharina Horstmann , Frank Rosowski , Klaus Joachim Mueller-Engel , Jochen Petzoldt , Ulrich Cremer
发明人： Andreas Raichle , Catharina Horstmann , Frank Rosowski , Klaus Joachim Mueller-Engel , Jochen Petzoldt , Ulrich Cremer
IPC分类号： B01J23/888 , C07C253/26 , C07C45/35
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8885 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/0221 , B01J37/34 , B01J2523/00 , C07C45/35 , C07C45/37 , C07C253/26 , Y02P20/52 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , C07C255/08
摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [BiaZ1bOx]p[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy]1, in which a finely divided oxide BiaZ1bOx and, formed from element sources, a finely divided mixture of stoichiometry BicMo12FedZ2eZ3fZ4gZ5hZ6i are mixed in a ratio of p:1, this mixture is used to form shaped bodies and these are treated thermally, where 0
摘要翻译： 用于生产几何形状的催化剂体K的方法，其活性材料是化学计量的多元素氧化物[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy] 1，其中细分的氧化物BiaZ1bOx和由元素源形成的细分的化学计量比BicMo 12 FedZ 2eZ 3 fZ 4 gZ 5hZ 6i的混合物混合 以p：1的比例，将该混合物用于形成成形体，并将它们热处理，其中0
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