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    METHOD AND SYSTEM FOR CARRYING OUT AN EXOTHERMIC GAS PHASE REACTION ON A HETEROGENEOUS PARTICULATE CATALYST
    5.
    发明申请
    METHOD AND SYSTEM FOR CARRYING OUT AN EXOTHERMIC GAS PHASE REACTION ON A HETEROGENEOUS PARTICULATE CATALYST 审中-公开

    公开(公告)号：US20160367960A1

    公开(公告)日：2016-12-22

    申请号：US14898788

    申请日：2014-06-16

    Applicant: BASF SE

    Inventor： Gerhard OLBERT ,  Gauthier Luc Maurice AVERLANT

    IPC: B01J8/06 ,  B01J8/04 ,  C01B7/04 ,  C10G2/00 ,  C07C5/48

    CPC classification number: B01J8/067 ,  B01J8/0496 ,  B01J8/065 ,  B01J19/249 ,  B01J2208/00053 ,  B01J2208/00061 ,  B01J2208/00115 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00407 ,  B01J2208/0053 ,  B01J2208/065 ,  B01J2219/2462 ,  B01J2219/2467 ,  B01J2219/2481 ,  C01B7/04 ,  C07C5/48 ,  C10G2/341

    Abstract: The invention relates to a method for producing 1,3 butadien by means of the oxidative dehydration of n-butenes on a heterogenous particulate multimetal oxide catalyst which contains molybdenum as the active compound and at least one other metal and which is filled into the contact tubes (KR) of two or more tube bundle reactors (R-I, R-II), wherein a heat transfer medium flows around the intermediate space between the contact tubes (KR) of the two or more tube bundle reactors (R-I, R-II). The method includes a production mode and a regeneration mode which are carried out in an alternating manner. In the production mode, an n-butene-containing feed flow is mixed with an oxygen-containing gas flow and conducted as a supply flow (1) over the heterogenous particulate multimetal oxide catalyst filled into the contact tubes (KR) of the two or more tube bundle reactors (R-I, R-II), and the heat transfer medium absorbs the released reaction heat, minus the heat quantity used to heat the supply flow (1) to the reaction temperature in the production mode, by means of an indirect heat exchange and completely or partly dispenses the reaction heat onto a secondary heat transfer medium (H2Oliq) in an external cooler (SBK). In the regeneration mode, the heterogenous particulate multimetal oxide catalyst is regenerated by conducting an oxygen-containing gas mixture (3) over the catalyst and burning off the deposits accumulated on the heterogenous particulate multimetal oxide catalyst. The invention is characterized in that the two or more tube bundle reactors (R-I, R-II) have a single heat transfer medium circuit and as many of the two or more tube bundle reactors (R-I, R-II) as necessary are operated constantly in the production mode so that the released reaction heat, minus the heat quantity used to heat the supply flow (1) to the reaction temperature in the production mode, suffices to keep the temperature of the heat transfer medium in the intermediate spaces between the content tubes (KR) of all the tube bundle reactors (R-I, R-II) at a constant level with a variation range of maximally +/−10 DEG C.

    METHOD FOR PRODUCING A GASEOUS FUEL COMPRISING HYDROGEN FROM KINETIC AND/OR POTENTIAL ENERGY RECOVERED FROM A VEHICLE POWERED BY A FOUR STROKE DIESEL ENGINE FITTED WITH AN ENGINE BRAKING MECHANISM AND SYSTEM USEFUL TO IMPLEMENT SUCH METHOD
    8.
    发明申请
    METHOD FOR PRODUCING A GASEOUS FUEL COMPRISING HYDROGEN FROM KINETIC AND/OR POTENTIAL ENERGY RECOVERED FROM A VEHICLE POWERED BY A FOUR STROKE DIESEL ENGINE FITTED WITH AN ENGINE BRAKING MECHANISM AND SYSTEM USEFUL TO IMPLEMENT SUCH METHOD 有权
    生产包含氢的动力和/或潜在能量的气体燃料的方法，该动力学和/或潜在能量由配备发动机制动机构的四冲程柴油发动机所驱动的动力和用于实施该方法的系统

    公开(公告)号：US20150337722A1

    公开(公告)日：2015-11-26

    申请号：US14443521

    申请日：2013-11-15

    Applicant: WALDERSON MIAMI LLC

    Inventor： Carlos Manuel Bastos

    IPC: F02B43/00 ,  F02M21/02 ,  C01B3/30

    CPC classification number: F02B43/00 ,  B01J8/067 ,  B01J2208/00221 ,  B01J2219/00006 ,  C01B3/30 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0833 ,  F02M21/0227 ,  F02M25/12 ,  Y02T10/121 ,  Y02T10/16 ,  Y02T10/32

    Abstract: A method for producing a hydrogen gaseous fuel from kinetic and/or potential energy recovered from a vehicle powered by a four stroke Diesel engine fitted with a Jacobs engine brake during a deceleration stage. Such a method comprises the following steps: a) providing a preheated steam flow; b) providing a gas flow from at least one chemical species used as preheated carbon and hydrogen source; c) mixing the gas flow from at least one chemical species used as carbon and hydrogen source from step a) with the steam flow from step b); d) reacting the mixture from step c) in the catalytic bed of a reforming reactor, heated by high temperature air from the compression stage of the Diesel engine acting as engine brake upon deceleration, producing an outlet synthesis gas flow which contains hydrogen; e) causing water to condense in the outlet synthesis gas flow which contains hydrogen, producing a water-free synthesis gas flow, and f) storing the synthesis gas flow obtained at step e) in a reservoir for its subsequent use during an acceleration stage of the vehicle. A system useful to implement the method for recovering kinetic and/or potential energy from a vehicle powered by a four stroke Diesel engine fitted with a Jacobs engine brake during a deceleration stage.

    Abstract translation: 一种从在由减速阶段装配有雅可比发动机制动器的四冲程柴油发动机驱动的车辆中回收的动能和/或势能产生氢气体燃料的方法。 这种方法包括以下步骤：a）提供预热的蒸汽流; b）提供来自用作预热碳和氢源的至少一种化学物质的气流; c）将来自步骤a）的用作碳和氢源的至少一种化学物质的气流与来自步骤b）的蒸汽流混合; d）将来自步骤c）的混合物在重整反应器的催化床中反应，由减压时作为发动机制动的柴油发动机的压缩级的高温空气加热，产生含有氢气的出口合成气流; e）使水在包含氢气的出口合成气流中冷凝，产生无水合成气流，以及f）将步骤e）中获得的合成气流存储在储存器中，以便在加速阶段期间随后使用 机动车。 一种用于实现用于在由减速阶段装配有Jacobs发动机制动器的四冲程柴油发动机驱动的车辆中恢复动能和/或势能的方法的系统。

    Steam reformer furnace, and method for the same
    9.
    发明授权
    Steam reformer furnace, and method for the same 有权
    蒸汽重整炉，及其方法

    公开(公告)号：US09145298B2

    公开(公告)日：2015-09-29

    申请号：US14386327

    申请日：2013-03-26

    Applicant: Stamicarbon B.V.

    Inventor： Paola Volpi ,  Barbara Morico ,  Lorena Mosca ,  Cristina Guazzotti ,  Fabio Prosperi ,  Gaetano Iaquaniello

    IPC: B01J7/00 ,  C01B3/38 ,  B01J8/02

    CPC classification number: C01B3/38 ,  B01J7/00 ,  B01J8/0257 ,  B01J2208/00221 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2219/18 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1235

    Abstract: A reformer furnace (1), comprising: at least one triple conduit assembly (200), including a flue gas conduit (220) enclosing a reaction conduit (240) enclosing a product gas conduit (260), wherein: the reaction conduit (240) extends between a lower end (244) defining a reaction gas inlet (245), and a closed upper end (242); the product gas conduit (260) extends between an upper end (262) defining a product gas inlet (263), and a lower end (264) defining a product gas outlet (265); the flue gas conduit (220) extends between an upper end (222) defining a flue gas inlet (223), and a lower end (224) defining a flue gas outlet (225); and an annulus (250) between the reaction conduit (240) and the product gas conduit (260) comprises a catalyst (252); a combustion chamber (100) that encloses an approximate upper half (226, 246, 266) of the at least one triple conduit assembly (200) while an approximate lower half (228, 248, 268) thereof resides outside of and below the combustion chamber, and that includes at least one burner (110), disposed inside of the combustion chamber and outside of the flue gas conduit (220), such that the approximate upper half (226) of the flue gas conduit substantially shields the reaction conduit (240) from direct burner flame heat radiation and impingement.

    Abstract translation: 一种重整炉（1），包括：至少一个三重管道组件（200），包括封闭产品气体管道（260）的反应管道（240）的烟道气导管（220），其中：反应管道（240） ）在限定反应气体入口（245）的下端（244）和封闭的上端（242）之间延伸; 产品气体管道（260）在限定产品气体入口（263）的上端（262）和限定产品气体出口（265）的下端（264）之间延伸; 所述烟道气管道（220）在限定烟道气入口（223）的上端（222）和限定出烟气出口（225）的下端（224）之间延伸; 并且所述反应管道（240）和所述产物气体管道（260）之间的环（250）包括催化剂（252）; 燃烧室（100），其围绕所述至少一个三重管道组件（200）的大致上半部（226,246,266），同时其大致下半部（228,248,268）位于燃烧室外面和下方 并且其包括设置在燃烧室内部和烟道气导管（220）外部的至少一个燃烧器（110），使得烟道气管道的大致上半部（226）基本上屏蔽反应管道 240）从直接燃烧器火焰的热辐射和冲击。

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