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公开(公告)号：US20110287678A1
公开(公告)日：2011-11-24
申请号：US13063809
申请日：2009-09-11
申请人： Shinichi Minami , Takashi Enomoto , Tetsuya Masutani , Masahiro Miyahara , Mitsuhiro Usugaya , Rumi Takeuchi , Ikuo Yamamoto , Peter Cheshire Hupfield
发明人： Shinichi Minami , Takashi Enomoto , Tetsuya Masutani , Masahiro Miyahara , Mitsuhiro Usugaya , Rumi Takeuchi , Ikuo Yamamoto , Peter Cheshire Hupfield
CPC分类号： D06M15/6436 , C08F283/122 , C08F290/068 , D06M15/277 , D06M15/3568 , Y10T442/2172 , C08F220/24 , C08F220/68
摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.
摘要翻译： 可以从含有以下的含氟聚合物获得能够赋予基材优异的防水拒油性，耐污性和感觉的表面处理剂：（A）包含以下物质的单体： （A1）下式的含氟单体：CH2 = C（-X）-C（= O）-Y-Z-Rf其中X为氢原子，一价有机基团或卤素原子，Y为 -O-或-NH-，Z为直接键或二价有机基团，Rf为碳原子数1〜20的氟烷基，（A2）具有环状烃基的（甲基）丙烯酸酯单体，（ B）至少一种选自巯基官能的有机聚硅氧烷，乙烯基官能的有机聚硅氧烷，（甲基）丙烯酰胺官能的有机聚硅氧烷和（甲基）丙烯酸酯官能团的官能的有机聚硅氧烷。
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公开(公告)号：US20100018659A1
公开(公告)日：2010-01-28
申请号：US12375086
申请日：2007-07-24
CPC分类号： C09D133/16 , C08F283/122 , D21H17/59 , D21H21/16 , Y10T428/31663 , C08F220/24
摘要： A greaseproof paper is provided for use in food processing and/or packaging of foods in which paper has been rendered oleophobic by treatment with a fluorine-containing polymer. The fluorine-containing polymer may be prepared by polymerizing a fluorine-containing monomer in the presence of a mercapto group-containing organopolysiloxane. The fluorine-containing polymer may be applied to paper by coating onto pre-formed paper, or by applying the polymer as a size during a papermaking process.
摘要翻译： 提供防油纸用于食品加工和/或包装通过用含氟聚合物处理已经产生疏油性的食品。 含氟聚合物可以通过在含巯基的有机聚硅氧烷的存在下聚合含氟单体来制备。 含氟聚合物可以通过涂布在预成型纸上或通过在造纸过程中以聚合物的尺寸施加到纸上。
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13.发明授权公开(公告)号：US08552106B2
公开(公告)日：2013-10-08
申请号：US12935344
申请日：2009-03-12
申请人： Ikuo Yamamoto , Tetsuya Masutani , Masahiro Miyahara , Takashi Enomoto , Shinichi Minami , Peter Cheshire Hupfield , Samantha Reed , Avril E. Surgenor
发明人： Ikuo Yamamoto , Tetsuya Masutani , Masahiro Miyahara , Takashi Enomoto , Shinichi Minami , Peter Cheshire Hupfield , Samantha Reed , Avril E. Surgenor
IPC分类号： C08L83/00
CPC分类号： C08F283/122 , C08F14/18 , C08F14/22 , C08F214/186 , C08F283/124 , C08J3/03 , C08J2383/10 , D06M15/277 , D06M15/3568 , D06M15/643 , D06M15/6436 , D06M15/657 , D06M2200/11 , D06M2200/12 , D06M2200/50 , C08F2/30
摘要： A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.
摘要翻译： 公开了巯基或乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟化硅反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）巯基或乙烯基官能的有机聚硅氧烷制备。
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公开(公告)号：US08022156B2
公开(公告)日：2011-09-20
申请号：US12375086
申请日：2007-07-24
IPC分类号： C08F30/08
CPC分类号： C09D133/16 , C08F283/122 , D21H17/59 , D21H21/16 , Y10T428/31663 , C08F220/24
摘要： A greaseproof paper is provided for use in food processing and/or packaging of foods in which paper has been rendered oleophobic by treatment with a fluorine-containing polymer. The fluorine-containing polymer may be prepared by polymerizing a fluorine-containing monomer in the presence of a mercapto group-containing organopolysiloxane. The fluorine-containing polymer may be applied to paper by coating onto pre-formed paper, or by applying the polymer as a size during a papermaking process.
摘要翻译： 提供防油纸用于食品加工和/或包装通过用含氟聚合物处理已经产生疏油性的食品。 含氟聚合物可以通过在含巯基的有机聚硅氧烷的存在下聚合含氟单体来制备。 含氟聚合物可以通过涂布在预成型纸上或通过在造纸过程中以聚合物的尺寸施加到纸上。
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15.发明申请公开(公告)号：US20110057142A1
公开(公告)日：2011-03-10
申请号：US12866074
申请日：2009-02-04
申请人： Ikuo Yamamoto , Tetsuya Masutani , Shinichi Minami , Peter Cheshire Hupfield , Avril E. Surgenor , Samantha Reed
发明人： Ikuo Yamamoto , Tetsuya Masutani , Shinichi Minami , Peter Cheshire Hupfield , Avril E. Surgenor , Samantha Reed
IPC分类号： C08F18/20 , D06M15/263
CPC分类号： C08F283/12 , C08F290/068 , C08F290/148 , C08L51/003 , C08L51/085 , C09D151/003 , C09D151/085 , C08L2666/02
摘要： A fluorosilicone reaction product of a vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a vinyl functional organopolysiloxane.
摘要翻译： 公开了一种乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟硅酮反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）乙烯基官能的有机聚硅氧烷制备。
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公开(公告)号：US20060054053A1
公开(公告)日：2006-03-16
申请号：US10541451
申请日：2004-01-22
CPC分类号： C09D183/10 , C08G65/007 , C09D5/00
摘要： There is provided a coating composition which comprises (A) a synthetic resin having functional group, (B) a stain-proofing component which is a liquid polydialkylsiloxane having functional group or a liquid fluoropolyether having functional group and (C) a curing agent, and the composition is excellent in a stain-proofing property, particularly removability of oily stain, thereby enabling scribbling to be easily wiped off, and is suitable for outdoor coating being excellent in weather resistance and adhesion.
摘要翻译： 提供一种涂料组合物，其包含（A）具有官能团的合成树脂，（B）具有官能团的液体聚二烷基硅氧烷或具有官能团的液体氟聚醚的防污组分和（C）固化剂，和 该组合物的防污性，特别是油性污渍的可除去性优异，从而可以容易地擦去涂布，适用于耐候性和粘合性优异的室外涂布。
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公开(公告)号：US08293840B2
公开(公告)日：2012-10-23
申请号：US12684334
申请日：2010-01-08
IPC分类号： C08L27/04
CPC分类号： C09D183/10 , C08G65/007 , C09D5/00
摘要： There is provided a coating composition which comprises (A) a synthetic resin having functional group, (B) a stain-proofing component which is a liquid polydialkylsiloxane having functional group or a liquid fluoropolyether having functional group and (C) a curing agent, and the composition is excellent in a stain-proofing property, particularly removability of oily stain, thereby enabling scribbling to be easily wiped off, and is suitable for outdoor coating being excellent in weather resistance and adhesion.
摘要翻译： 提供一种涂料组合物，其包含（A）具有官能团的合成树脂，（B）具有官能团的液体聚二烷基硅氧烷或具有官能团的液体氟聚醚的防污组分和（C）固化剂，和 该组合物的防污性，特别是油性污渍的可除去性优异，从而可以容易地擦去涂布，适用于耐候性和粘合性优异的室外涂布。
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公开(公告)号：US07807752B2
公开(公告)日：2010-10-05
申请号：US10541451
申请日：2004-01-22
CPC分类号： C09D183/10 , C08G65/007 , C09D5/00
摘要： There is provided a coating composition which comprises (A) a synthetic resin having functional group, (B) a stain-proofing component which is a liquid polydialkylsiloxane having functional group or a liquid fluoropolyether having functional group and (C) a curing agent, and the composition is excellent in a stain-proofing property, particularly removability of oily stain, thereby enabling scribbling to be easily wiped off, and is suitable for outdoor coating being excellent in weather resistance and adhesion.
摘要翻译： 提供一种涂料组合物，其包含（A）具有官能团的合成树脂，（B）具有官能团的液体聚二烷基硅氧烷或具有官能团的液体氟聚醚的防污组分和（C）固化剂，和 该组合物的防污性，特别是油性污渍的可除去性优异，从而可以容易地擦去涂布，适用于耐候性和粘合性优异的室外涂布。
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19.发明申请WATER-REPELLENT OIL-REPELLENT ANTIFOULING AGENT HAVING GOOD SOLUBILITY IN SOLVENT 审中-公开具有溶剂中良好溶解性的耐水防油剂公开(公告)号：US20100227173A1
公开(公告)日：2010-09-09
申请号：US12599790
申请日：2008-05-14
申请人： Akihiko Ueda , Masahiko Maeda , Tetsuya Masutani
发明人： Akihiko Ueda , Masahiko Maeda , Tetsuya Masutani
IPC分类号： C08L33/16 , C08F220/22 , B32B27/00
CPC分类号： C04B41/4846 , C03C17/32 , C03C2217/76 , C04B41/009 , C04B2111/203 , C04B2111/27 , C08F214/186 , C08F220/22 , C08F220/24 , Y10T428/3154 , C04B41/463 , C04B41/483 , C04B41/4922 , C04B14/048 , C04B14/28
摘要： Disclosed is a water-repellent oil-repellent antifouling agent containing a fluorine-containing polymer for a treatment for providing water repellency, oil repellency and antifouling property. The fluorine-containing polymer has a repeating unit (A) derived from a fluorine-containing acrylate monomer, and a repeating unit (B) derived from at least one non-fluorine acrylate monomer selected from the group consisting of a monomer (B1) having a cyclic hydrocarbon group and a monomer (B2) having a short chain hydrocarbon group. This water-repellent oil-repellent antifouling agent has good solubility in solvents, and exhibits excellent effects on various bases, especially on masonries.
摘要翻译： 公开了含有含氟聚合物的防水防油防污剂，用于提供防水性，防油性和防污性的处理。 含氟聚合物具有由含氟丙烯酸酯单体衍生的重复单元（A）和由至少一种选自以下的非氟丙烯酸酯单体衍生的重复单元（B）：单体（B1），其具有 环状烃基和具有短链烃基的单体（B2）。 该防水防油防污剂在溶剂中的溶解性良好，对各种碱，特别是在砌体上表现出优异的效果。
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公开(公告)号：US20070066780A1
公开(公告)日：2007-03-22
申请号：US10559810
申请日：2004-06-07
IPC分类号： C08F16/24
CPC分类号： C08F220/24 , C04B41/4842
摘要： A fluoropolymer for masonry treatment produced from (A) a fluoromonomer which has been substituted in the α-position by a X group and is represented by the formula (I): and (B) a monomer having a functional group reactive with active hydrogen. It imparts excellent water- and oil-repellency and unsusceptibility to fouling to masonries.
摘要翻译： （A）通过X基团在α位被X基团取代并由式（I）表示的（A）含氟单体制备的用于石工处理的含氟聚合物：和（B）具有与活性氢反应的官能团的单体。 它赋予了优异的拒水拒油性和对砖石结垢的不可接受性。
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