公开(公告)号：US09988759B2

公开(公告)日：2018-06-05

申请号：US13063809

申请日：2009-09-11

申请人： Shinichi Minami ,  Takashi Enomoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Mitsuhiro Usugaya ,  Rumi Takeuchi ,  Ikuo Yamamoto ,  Peter Cheshire Hupfield

发明人： Shinichi Minami ,  Takashi Enomoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Mitsuhiro Usugaya ,  Rumi Takeuchi ,  Ikuo Yamamoto ,  Peter Cheshire Hupfield

IPC分类号： B32B27/04 ,  D06M15/643 ,  C08F283/12 ,  C08F290/06 ,  D06M15/277 ,  D06M15/356

CPC分类号： D06M15/6436 ,  C08F283/122 ,  C08F290/068 ,  D06M15/277 ,  D06M15/3568 ,  Y10T442/2172 ,  C08F220/24 ,  C08F220/68

摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.

公开(公告)号：US20110287678A1

公开(公告)日：2011-11-24

申请号：US13063809

申请日：2009-09-11

申请人： Shinichi Minami ,  Takashi Enomoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Mitsuhiro Usugaya ,  Rumi Takeuchi ,  Ikuo Yamamoto ,  Peter Cheshire Hupfield

发明人： Shinichi Minami ,  Takashi Enomoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Mitsuhiro Usugaya ,  Rumi Takeuchi ,  Ikuo Yamamoto ,  Peter Cheshire Hupfield

IPC分类号： B32B5/02 ,  C09K3/00 ,  C08G77/28

CPC分类号： D06M15/6436 ,  C08F283/122 ,  C08F290/068 ,  D06M15/277 ,  D06M15/3568 ,  Y10T442/2172 ,  C08F220/24 ,  C08F220/68

摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.

摘要翻译： 可以从含有以下的含氟聚合物获得能够赋予基材优异的防水拒油性，耐污性和感觉的表面处理剂：（A）包含以下物质的单体： （A1）下式的含氟单体：CH2 = C（-X）-C（= O）-Y-Z-Rf其中X为氢原子，一价有机基团或卤素原子，Y为 -O-或-NH-，Z为直接键或二价有机基团，Rf为碳原子数1〜20的氟烷基，（A2）具有环状烃基的（甲基）丙烯酸酯单体，（ B）至少一种选自巯基官能的有机聚硅氧烷，乙烯基官能的有机聚硅氧烷，（甲基）丙烯酰胺官能的有机聚硅氧烷和（甲基）丙烯酸酯官能团的官能的有机聚硅氧烷。

公开(公告)号：US20110124803A1

公开(公告)日：2011-05-26

申请号：US12935344

申请日：2009-03-12

申请人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Takashi Enomoto ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Samantha Reed ,  Avril E. Surgenor

发明人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Takashi Enomoto ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Samantha Reed ,  Avril E. Surgenor

IPC分类号： C09D183/08 ,  C08L83/08

CPC分类号： C08F283/122 ,  C08F14/18 ,  C08F14/22 ,  C08F214/186 ,  C08F283/124 ,  C08J3/03 ,  C08J2383/10 ,  D06M15/277 ,  D06M15/3568 ,  D06M15/643 ,  D06M15/6436 ,  D06M15/657 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50 ,  C08F2/30

摘要： A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.

摘要翻译： 公开了巯基或乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟硅酮反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）巯基或乙烯基官能的有机聚硅氧烷制备。

公开(公告)号：US08552106B2

公开(公告)日：2013-10-08

申请号：US12935344

申请日：2009-03-12

申请人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Takashi Enomoto ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Samantha Reed ,  Avril E. Surgenor

发明人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Takashi Enomoto ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Samantha Reed ,  Avril E. Surgenor

IPC分类号： C08L83/00

CPC分类号： C08F283/122 ,  C08F14/18 ,  C08F14/22 ,  C08F214/186 ,  C08F283/124 ,  C08J3/03 ,  C08J2383/10 ,  D06M15/277 ,  D06M15/3568 ,  D06M15/643 ,  D06M15/6436 ,  D06M15/657 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50 ,  C08F2/30

摘要： A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.

摘要翻译： 公开了巯基或乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟化硅反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）巯基或乙烯基官能的有机聚硅氧烷制备。

公开(公告)号：US08927667B2

公开(公告)日：2015-01-06

申请号：US12866074

申请日：2009-02-04

申请人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Avril E. Surgenor ,  Samantha Reed

发明人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Avril E. Surgenor ,  Samantha Reed

IPC分类号： C08F283/12 ,  C08F18/20

CPC分类号： C08F283/12 ,  C08F290/068 ,  C08F290/148 ,  C08L51/003 ,  C08L51/085 ,  C09D151/003 ,  C09D151/085 ,  C08L2666/02

摘要： A fluorosilicone reaction product of a vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a vinyl functional organopolysiloxane.

摘要翻译： 公开了一种乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟硅酮反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）乙烯基官能的有机聚硅氧烷制备。

公开(公告)号：US20100018659A1

公开(公告)日：2010-01-28

申请号：US12375086

申请日：2007-07-24

申请人： Peter Cheshire Hupfield ,  Tetsuya Masutani ,  Shinichi Minami ,  Ikuo Yamamoto

发明人： Peter Cheshire Hupfield ,  Tetsuya Masutani ,  Shinichi Minami ,  Ikuo Yamamoto

IPC分类号： D21H17/34 ,  C08F14/18

CPC分类号： C09D133/16 ,  C08F283/122 ,  D21H17/59 ,  D21H21/16 ,  Y10T428/31663 ,  C08F220/24

摘要： A greaseproof paper is provided for use in food processing and/or packaging of foods in which paper has been rendered oleophobic by treatment with a fluorine-containing polymer. The fluorine-containing polymer may be prepared by polymerizing a fluorine-containing monomer in the presence of a mercapto group-containing organopolysiloxane. The fluorine-containing polymer may be applied to paper by coating onto pre-formed paper, or by applying the polymer as a size during a papermaking process.

摘要翻译： 提供防油纸用于食品加工和/或包装通过用含氟聚合物处理已经产生疏油性的食品。 含氟聚合物可以通过在含巯基的有机聚硅氧烷的存在下聚合含氟单体来制备。 含氟聚合物可以通过涂布在预成型纸上或通过在造纸过程中以聚合物的尺寸施加到纸上。

公开(公告)号：US08022156B2

公开(公告)日：2011-09-20

申请号：US12375086

申请日：2007-07-24

申请人： Peter Cheshire Hupfield ,  Tetsuya Masutani ,  Shinichi Minami ,  Ikuo Yamamoto

发明人： Peter Cheshire Hupfield ,  Tetsuya Masutani ,  Shinichi Minami ,  Ikuo Yamamoto

IPC分类号： C08F30/08

CPC分类号： C09D133/16 ,  C08F283/122 ,  D21H17/59 ,  D21H21/16 ,  Y10T428/31663 ,  C08F220/24

摘要： A greaseproof paper is provided for use in food processing and/or packaging of foods in which paper has been rendered oleophobic by treatment with a fluorine-containing polymer. The fluorine-containing polymer may be prepared by polymerizing a fluorine-containing monomer in the presence of a mercapto group-containing organopolysiloxane. The fluorine-containing polymer may be applied to paper by coating onto pre-formed paper, or by applying the polymer as a size during a papermaking process.

摘要翻译： 提供防油纸用于食品加工和/或包装通过用含氟聚合物处理已经产生疏油性的食品。 含氟聚合物可以通过在含巯基的有机聚硅氧烷的存在下聚合含氟单体来制备。 含氟聚合物可以通过涂布在预成型纸上或通过在造纸过程中以聚合物的尺寸施加到纸上。

公开(公告)号：US20110057142A1

公开(公告)日：2011-03-10

申请号：US12866074

申请日：2009-02-04

申请人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Avril E. Surgenor ,  Samantha Reed

发明人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Avril E. Surgenor ,  Samantha Reed

IPC分类号： C08F18/20 ,  D06M15/263

CPC分类号： C08F283/12 ,  C08F290/068 ,  C08F290/148 ,  C08L51/003 ,  C08L51/085 ,  C09D151/003 ,  C09D151/085 ,  C08L2666/02

摘要： A fluorosilicone reaction product of a vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a vinyl functional organopolysiloxane.

摘要翻译： 公开了一种乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟硅酮反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）乙烯基官能的有机聚硅氧烷制备。

公开(公告)号：US07973107B2

公开(公告)日：2011-07-05

申请号：US11913814

申请日：2006-05-08

申请人： Ikuo Yamamoto ,  Shinichi Minami ,  Tetsuya Masutani ,  Peter C. Hupfield ,  Avril E. Surgenor

发明人： Ikuo Yamamoto ,  Shinichi Minami ,  Tetsuya Masutani ,  Peter C. Hupfield ,  Avril E. Surgenor

IPC分类号： C08L83/06

CPC分类号： D06M15/277 ,  C08F283/122 ,  C08G77/26 ,  C08G77/28 ,  C08G77/442 ,  D06M15/6436 ,  D06M15/657 ,  D06M2200/11 ,  Y10T428/31663 ,  Y10T442/60 ,  C08F220/24 ,  C08F214/18

摘要： A fluorosilicone reaction product of a mercapto functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto functional organopolysiloxane.

摘要翻译： 公开了巯基官能化有机聚硅氧烷和含氟单体的氟硅酮反应产物及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟代硅氧烷反应产物由（A）式CH 2 = C（X）COOYRf的含氟单体和（B）巯基官能的有机聚硅氧烷制备。

公开(公告)号：US20090030143A1

公开(公告)日：2009-01-29

申请号：US11913814

申请日：2006-05-08

申请人： Ikuo Yamamoto ,  Shinichi Minami ,  Tetsuya Masutani ,  Peter C. Hupfield ,  Avril E. Surgenor

发明人： Ikuo Yamamoto ,  Shinichi Minami ,  Tetsuya Masutani ,  Peter C. Hupfield ,  Avril E. Surgenor

IPC分类号： C08L83/06 ,  C08G77/14

CPC分类号： D06M15/277 ,  C08F283/122 ,  C08G77/26 ,  C08G77/28 ,  C08G77/442 ,  D06M15/6436 ,  D06M15/657 ,  D06M2200/11 ,  Y10T428/31663 ,  Y10T442/60 ,  C08F220/24 ,  C08F214/18

摘要： A fluorosilicone reaction product of a mercapto functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto functional organopolysiloxane.

摘要翻译： 公开了巯基官能化有机聚硅氧烷和含氟单体的氟硅酮反应产物及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟硅酮反应产物由（A）式为CH2-C（X）COOYRf的含氟单体和（B）巯基官能的有机聚硅氧烷制备。