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    Water- and oil-repellent treatment of textile
    1.
    发明授权
    Water- and oil-repellent treatment of textile 有权
    防水和拒油处理纺织品

    公开(公告)号：US07678155B2

    公开(公告)日：2010-03-16

    申请号：US10408777

    申请日：2003-04-08

    Applicant: Ikuo Yamamoto ,  Kayo Kusumi ,  Mitsuhiro Usugaya ,  Ryosuke Hara ,  Takahito Kanbara

    Inventor： Ikuo Yamamoto ,  Kayo Kusumi ,  Mitsuhiro Usugaya ,  Ryosuke Hara ,  Takahito Kanbara

    IPC: D06M11/07 ,  D06M11/58 ,  D06M13/53

    CPC classification number: D06M15/277 ,  D06M11/05 ,  D06M13/46 ,  D06M15/41 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T428/2933 ,  Y10T442/2172 ,  Y10T442/2189 ,  Y10T442/227

    Abstract: Excellent water- and oil-repellency and soil releasability can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid containing a water- and oil-repellent agent and a stain blocking agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent contains at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifying agent.

    Abstract translation: 通过制备经处理的织物的方法可以获得优异的拒水拒油性和污垢释放性，其具有以下步骤：（1）制备含有拒水拒油剂和防污剂的处理液（2 ）将处理液的pH调节至最多7，（3）将处理液施加到纺织品上，（4）用蒸汽处理织物，（5）用水洗涤织物并使织物脱水， 防油剂含有选自含氟聚合物和含氟低分子化合物中的至少一种含氟化合物，防水防油剂或处理液含有阳离子性 乳化剂。

    TREATMENT FOR PAPER AND METHOD FOR TREATMENT OF PAPER
    2.
    发明申请
    TREATMENT FOR PAPER AND METHOD FOR TREATMENT OF PAPER 审中-公开
    纸张处理和纸张处理方法

    公开(公告)号：US20090155600A1

    公开(公告)日：2009-06-18

    申请号：US12067550

    申请日：2006-09-20

    Applicant: Mitsuhiro Usugaya ,  Michio Matsuda

    Inventor： Mitsuhiro Usugaya ,  Michio Matsuda

    IPC: B32B27/10

    CPC classification number: C09D133/16 ,  C08F120/32 ,  C08F220/32 ,  C08F220/38 ,  C09K3/32 ,  D21H17/33 ,  D21H19/20 ,  D21H21/16 ,  Y10T428/3154

    Abstract: A treatment for paper, containing (A) a fluorine-containing polymer comprising repeating units derived from a fluorine-containing monomer (a) represented by the general formula (I): CH2═C(—X)—C(═O)—Y—(CH2)m-Z-(CH2)n—Rf (I) wherein X is hydrogen, methyl, fluoro, chloro, CFX1X2 (wherein X1 and X2 are each hydrogen, fluoro, or chloro), or the like; Y is —O— or —NH—; Z is —S—, —SO—, or —SO2—; Rf is fluoroalkyl having 1 to 6 carbon atoms; m is 1 to 10; and n is 0 to 10.

    Abstract translation: 含有（A）包含由通式（I）表示的含氟单体（a）衍生的重复单元的含氟聚合物的纸的处理：CH2-C（-X）-C（-O） - 其中X为氢，甲基，氟，氯，CFX 1 X 2（其中X 1和X 2各自为氢，氟或氯）的Y-（CH 2）m Z-（CH 2）n -R f（I） Y是-O-或-NH-; Z是-S-，-SO-或-SO 2 - ; Rf是具有1至6个碳原子的氟代烷基; m为1〜10; n为0〜10。

    FLUORINE-CONTAINING COPOLYMER AND WATER- AND OIL-REPELLENT AGENT
    4.
    发明申请
    FLUORINE-CONTAINING COPOLYMER AND WATER- AND OIL-REPELLENT AGENT 审中-公开
    含氟的共聚物和水和油的代理

    公开(公告)号：US20110028059A1

    公开(公告)日：2011-02-03

    申请号：US12934604

    申请日：2009-03-27

    Applicant: Hisako Nakamura ,  Mitsuhiro Usugaya ,  Takashi Enomoto

    Inventor： Hisako Nakamura ,  Mitsuhiro Usugaya ,  Takashi Enomoto

    IPC: B32B5/02 ,  C08F220/22 ,  C08L27/12

    CPC classification number: C08F220/24 ,  C08F214/06 ,  C08F214/08 ,  C08F214/16 ,  C08F214/18 ,  D06M15/277 ,  Y10T442/2172

    Abstract: A water- and oil-repellent agent is an aqueous emulsion containing:(I) a fluorine-containing copolymer, (II) a surfactant, and (III) an aqueous medium. The fluorine-containing copolymer contains repeating units derived from (a) a fluorine-containing monomer containing a fluoroalkyl group having 1 to 6 carbon atoms and (b) a fluorine-free monomer selected from the group consisting of vinyl halide and vinylidene halide, wherein the fluorine-containing copolymer has a melt viscosity of 1,000 to 100,000 cP at a temperature of 100° C. under a load of 25 kgf/cm2.

    Abstract translation: 拒水拒油剂是含有（I）含氟共聚物，（II）表面活性剂和（III）水性介质）的水性乳液。 所述含氟共聚物含有（a）含有碳原子数1〜6的氟烷基的含氟单体的重复单元和（b）选自卤乙烯和偏二卤乙烯的无氟单体，其中， 在25kgf / cm 2的负荷下，在100℃的温度下，含氟共聚物的熔融粘度为1,000〜100,000cP。

    WATER- AND OIL-REPELLENT TREATMENT OF TEXTILE
    5.
    发明申请
    WATER- AND OIL-REPELLENT TREATMENT OF TEXTILE 审中-公开
    水和油脂处理纺织品

    公开(公告)号：US20100143641A1

    公开(公告)日：2010-06-10

    申请号：US12705892

    申请日：2010-02-15

    Applicant: Ikuo Yamamoto ,  Kayo Kusumi ,  Mitsuhiro Usugaya ,  Ryosuke Hara ,  Takahito Kanbara

    Inventor： Ikuo Yamamoto ,  Kayo Kusumi ,  Mitsuhiro Usugaya ,  Ryosuke Hara ,  Takahito Kanbara

    IPC: D06M15/00 ,  D05C17/00

    CPC classification number: D06M15/277 ,  D06M11/05 ,  D06M13/46 ,  D06M15/41 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T428/2933 ,  Y10T442/2172 ,  Y10T442/2189 ,  Y10T442/227

    Abstract: Excellent water- and oil-repellency and soil releasability can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid containing a water- and oil-repellent agent and a stain blocking agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent contains at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifying agent.

    Abstract translation: 通过制备经处理的织物的方法可以获得优异的拒水拒油性和污垢释放性，其具有以下步骤：（1）制备含有拒水拒油剂和防污剂的处理液（2 ）将处理液的pH调节至最多7，（3）将处理液施加到纺织品上，（4）用蒸汽处理织物，（5）用水洗涤织物并使织物脱水， 防油剂含有选自含氟聚合物和含氟低分子化合物中的至少一种含氟化合物，防水防油剂或处理液含有阳离子性 乳化剂。

    FLUORINE-CONTAINING COPOLYMER, PAPER PROCESSING AGENT, AND COATING FILM-FORMING AGENT FOR COSMETIC PREPARATION
    6.
    发明申请
    FLUORINE-CONTAINING COPOLYMER, PAPER PROCESSING AGENT, AND COATING FILM-FORMING AGENT FOR COSMETIC PREPARATION 有权
    含氟聚合物，纸张加工剂和涂料成膜剂用于化妆品制备

    公开(公告)号：US20110027593A1

    公开(公告)日：2011-02-03

    申请号：US12935554

    申请日：2009-03-27

    Applicant: Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

    Inventor： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

    IPC: B32B27/10 ,  C08F220/22 ,  C08L27/12

    CPC classification number: D21H17/20 ,  A61K8/8152 ,  A61Q3/02 ,  A61Q5/06 ,  A61Q19/00 ,  B29C33/62 ,  C08F220/24 ,  C08F222/1006 ,  C09D133/16 ,  D21H19/20 ,  Y10T428/3154 ,  C08F220/26

    Abstract: Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH2═C(—X)—C(═O)—Y—[—(CH2)m—Z—]p—(CH2)n—Rf (wherein X represents a hydrogen atom; Y represents —O— or —NH—; Z represents a direct bond, —S— or —SO2—; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH2═C(X′)—C(═O)—O—(RO)q—H (wherein X′ represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group.

    Abstract translation: 公开了一种在水中具有足够稳定性的含氟共聚物，其能够为纸提供足够的耐油性。 含氟聚合物含有作为必要成分的（a）由通式（I）表示的含氟单体CH 2 = C（-X）-C（= O）-Y - [ - （CH 2）m-Z - ]对 - （CH 2）n -R f（其中X表示氢原子; Y表示-O-或-NH-; Z表示直接键，-S-或-SO 2 - ; Rf表示具有1- 6个碳原子; m是1-10的数; n是0-10的数; p是0或1）和（b）由通式（II）表示的含烷氧基的单体CH 2 = C（ X'）-C（= O）-O-（RO）q-H（其中X'表示氢原子或甲基; R表示具有2-4个碳原子的亚烷基，其中部分或全部氢原子 可以被羟基取代; q表示1-50的整数）。 含氟聚合物不含有具有氨基的单体。

    TREATMENT COMPRISING WATER- AND OIL-REPELLENT AGENT
    7.
    发明申请
    TREATMENT COMPRISING WATER- AND OIL-REPELLENT AGENT 审中-公开
    包括水和油剂的处理

    公开(公告)号：US20110020591A1

    公开(公告)日：2011-01-27

    申请号：US12934562

    申请日：2009-03-27

    Applicant: Hisako Nakamura ,  Mitsuhiro Usugaya

    Inventor： Hisako Nakamura ,  Mitsuhiro Usugaya

    IPC: D06M15/277 ,  D06L1/22 ,  D04H11/00 ,  B32B27/04

    CPC classification number: D06M15/05 ,  D06M11/07 ,  D06M11/51 ,  D06M11/68 ,  D06M13/236 ,  D06M13/428 ,  D06M15/277 ,  D06M15/295 ,  D06M15/33 ,  D06M15/333 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T442/2172

    Abstract: A textile having high fluorine adhesion rate, and excellent water- and oil-repellency can be obtained by a method of producing a treated textile, comprising steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent which comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer or a fluorine-containing low molecular weight compound, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the treatment liquid comprises a thermally gelling substance and a salt.

    Abstract translation: 通过生产处理过的织物的方法可以获得具有高氟附着率和优异的拒水拒油性的织物，其包括以下步骤：（1）制备包含拒水拒油剂的处理液，其包含 至少一种选自含氟聚合物或含氟低分子化合物的含氟化合物，（2）将处理液的pH调节至最多7，（3）将处理液施加到 纺织品，（4）用蒸汽处理织物，和（5）用水洗涤织物并使织物脱水，其中处理液体包含热胶凝物质和盐。

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