Abstract:
A regenerated cathode active material comprises a core material comprising lithium and a transition metal oxide, the core material having a surface, wherein the core material is a recycled cathode active material that has been re-lithiated. At least two different lithium-ion conducting species are on the surface of the core material, and the at least two different lithium-ion conducting species are selected from AlF3, Li3PO4, and a lithium metal oxide. Another regenerated cathode active material for use in a lithium-ion battery comprises a core material comprising a transition metal oxide and lithium, the core material having a surface, and multiple lithium-ion conducting species on the surface, wherein the core material is a recycled cathode active material that has been re-lithiated.
Abstract:
A method of preparing an electrode for a lithium-ion battery includes mixing a magnetic, electrically conductive material with a lithium conductive polymer; forming tubes of the polymer and magnetic, electrically conductive material; mixing the tubes with a slurry of an electrode material; coating a current collector with the slurry; and applying a magnetic field to the slurry to align the tubes within the slurry in relation to the current collector. The aligned tubes form electrical and ionic conductive pathways within the slurry. The tubes have a length less than half a thickness of the slurry.
Abstract:
A non-carbon support particle is provided for use in electrocatalyst. The non-carbon support particle consists essentially of titanium dioxide and ruthenium dioxide. The titanium and ruthenium can have a mole ratio ranging from 1:1 to 9:1 in the non-carbon support particle. Also disclosed are methods of preparing the non-carbon support and electrocatalyst taught herein.
Abstract:
A rolling press for the manufacture of a battery electrode includes a first roller of a non-conductive material, a base of a non-conductive material spaced from the first roller equal to a desired thickness of the battery electrode, and a conductivity detector having a first electrode configured to contact a first side of the battery electrode and a second electrode configured to contact a second side of the battery electrode.
Abstract:
Methods of preparing fuel cell electrodes having catalyst with high density catalyst support are provided. One method of fabricating a fuel cell electrode comprises adjusting an active catalyst particle loading to increase catalyst layer thickness to within a desired range.
Abstract:
Electrocatalysts having non-corrosive, non-carbon support particles are provided as well as the method of making the electrocatalysts and the non-corrosive, non-carbon support particles. Embodiments of the non-corrosive, non-carbon support particle consists essentially of titanium dioxide and ruthenium dioxide. The electrocatalyst can be used in fuel cells, for example.
Abstract:
Methods for the rapid synthesis of catalyst are provided, as well as catalyst formed from such methods. One method of the rapid synthesis of catalyst comprises forming a homogenous solution comprising a precious metal precursor and a catalyst substrate, reducing the precious metal precursor to precious metal nanoparticles, and depositing the precious metal nanoparticles onto the catalyst substrate to form catalyst particles. The reducing and depositing steps comprise controlling a rate of increase in temperature of the solution with microwave irradiation until the solution is a predetermined temperature and maintaining the solution at the predetermined temperature with microwave irradiation. The method further comprises detecting completion of the reduction and deposition and ceasing microwave irradiation upon detection.
Abstract:
Electrocatalysts having non-corrosive, non-carbon support particles are provided as well as the method of making the electrocatalysts and the non-corrosive, non-carbon support particles. Embodiments of the non-corrosive, non-carbon support particle consists essentially of titanium dioxide and ruthenium dioxide. The electrocatalyst can be used in fuel cells, for example.
Abstract:
Methods and apparatus are provided for discharging a Li—S battery having at least one battery unit comprising a lithium-containing anode and a sulfur-containing cathode with an electrolyte layer there between. One method comprises electrochemically surface treating the sulfur-containing cathode during discharge of the battery. A method of electrochemically surface treating a cathode of a lithium-sulfide battery comprises applying at least one oxidative voltage pulse during a pulse application period while the lithium-sulfur battery discharges and controlling pulse characteristics during the pulse application period, the pulse characteristics configured to affect a morphology of lithium sulfide forming on the sulfur-containing cathode during discharge.
Abstract:
Provided are methods and apparatus for charging a lithium sulfur (Li—S) battery. The Li—S battery has at least one unit cell comprising a lithium-containing anode and a sulfur-containing cathode with an electrolyte layer there between. One method provides controlled application of voltage pulses at the beginning of the charging process. An application period is initiated after a discharge cycle of the Li—S battery is complete. During the application period, voltage pulses are provided to the Li—S battery. The voltage pulses are less than a constant current charging voltage. Constant current charging is initiated after the application period has elapsed.