公开(公告)号：US20130130230A1

公开(公告)日：2013-05-23

申请号：US13727042

申请日：2012-12-26

Applicant: TOHOKU UNIVERSITY ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Matsuhiko NISHIZAWA ,  Takeo MIYAKE ,  Syuhei YOSHINO ,  Takeo YAMADA ,  Kenji HATA

IPC: C12N9/00 ,  H01M8/16

CPC classification number: C12N9/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  C01B32/178 ,  C01B2202/04 ,  C01B2202/08 ,  C01B2202/34 ,  G01N27/3278 ,  H01M4/8846 ,  H01M4/9083 ,  H01M8/16 ,  Y02E60/527 ,  Y10S977/705 ,  Y10S977/714 ,  Y10S977/737 ,  Y10S977/747 ,  Y10S977/755

Abstract: The present invention answers the demands of power generating device and biosensor development and provides a flexible, free-standing type protein containing carbon nanotube film, and a sensor and power generating device each equipped with the carbon nanotube film as an electrode. According to the present invention a carbon nanotube free standing film is provided including a carbon nanotube aggregate formed by aggregating a plurality of carbon nanotubes, and a plurality of enzymes included between the plurality of carbon nanotubes. The carbon nanotube film may include a different protein to the enzyme and may include a surfactant agent between the plurality of carbon nanotubes.

Abstract translation: 本发明解决了发电装置和生物传感器开发的需要，提供了一种含有碳纳米管膜的柔性，独立型蛋白质，以及配备有碳纳米管膜作为电极的传感器和发电装置。 根据本发明，提供了一种碳纳米管自立膜，其包括通过聚集多个碳纳米管而形成的碳纳米管集合体和包含在多个碳纳米管之间的多种酶。 碳纳米管膜可以包括与酶不同的蛋白质，并且可以在多个碳纳米管之间包括表面活性剂。

公开(公告)号：US20180297848A1

公开(公告)日：2018-10-18

申请号：US16013195

申请日：2018-06-20

Applicant: ZEON CORPORATION ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Akiyoshi SHIBUYA ,  Kenji HATA ,  Motoo YUMURA

IPC: C01B32/158 ,  C01B32/16 ,  B01J23/745 ,  C23C16/455 ,  C23C16/44 ,  C01B32/05 ,  B82Y40/00 ,  B82Y30/00

Abstract: An apparatus for producing an aligned carbon nanotube includes: at least one injection section including at least one injection hole from which a raw material gas is injected to a base substrate; an exhaust vent for exhausting the raw material gas; and an exhaust section including a plurality of exhaust vents, the plurality of exhaust vents being provided so as to be closer to the exhaust vent than a plurality of injection holes included in the at least one injection hole of the at least one injection section.

公开(公告)号：US20170107416A1

公开(公告)日：2017-04-20

申请号：US15337450

申请日：2016-10-28

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Kenji HATA ,  Seisuke ATA

IPC: C09K5/14 ,  C08K7/00 ,  D04H13/00 ,  D01F9/12

CPC classification number: C09K5/14 ,  B82Y30/00 ,  C08J5/005 ,  C08J5/042 ,  C08K3/04 ,  C08K3/041 ,  C08K7/06 ,  D01F9/145 ,  H01B1/24 ,  Y10S977/742 ,  C08L21/00 ,  C08L101/00

Abstract: A CNT composite material includes a CNT group and carbon fibers dispersed in a matrix, the CNT composite material includes 0.01 wt % or more and 30 wt % or less of CNT aggregate. The CNT group includes a three dimensional network structure with a size of 10 μm or more and has a maximum distribution range of a differential pore volume of 0.01 μm or more and 10 μm or less in a range of 4 nm or more and 1000 μm or less of a pore diameter. The carbon fibers have a maximum distribution range of a differential pore volume of 1 μm or more and 100 μm or less in a range of 4 nm or more and 1000 μm or less of a pore diameter. A total specific surface area of the CNT aggregate and the carbon fibers is 10 m2/g or more and 500 m2/g or less.

公开(公告)号：US20160137504A1

公开(公告)日：2016-05-19

申请号：US15003881

申请日：2016-01-22

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Kenji HATA ,  Takeo YAMADA ,  Chandramouli SUBRAMANIAM

IPC: C01B31/02 ,  H01B1/04

CPC classification number: C01B32/158 ,  C25D5/50 ,  C25D5/54 ,  C25D15/00 ,  H01B1/04

Abstract: A CNT metal composite material is provided depositing a metal into a plurality of CNTs is provided including 3% by weight or more and 70% by weight or less of the CNTs, a region is arranged with the metal uniformly distributed in a scanning electron microscope image magnified ten thousand times and the length of the region is at least 1 μm, a signal of the metal and a signal of carbon are not localized in a specific area in a two-dimensional elemental analysis image magnified ten thousand times, and a length of a region uniformly distributing the signal of the metal and the signal of carbon uniformly distributed is at least 1 μm, an allowable current density is at 6×106 A/cm2 or more, and volume resistivity is 1×10−6 Ω·cm or more and 5×10−3 Ω·cm or less.

Abstract translation: 提供了一种CNT金属复合材料，其将包含3重量％以上且70重量％以下的CNT的金属沉积到多个CNT中，将金属均匀分布在扫描电子显微镜图像中的区域 放大万次，区域长度至少为1μm，金属信号和碳信号不会放大在二维元素分析图像中的特定区域中，放大了一万倍，长度为 均匀分布金属信号的区域和碳均匀分布的信号的区域为至少1μm，容许电流密度为6×10 16 A / cm 2以上，体积电阻率为1×10 -6Ω·cm 以上且5×10-3＆OHgr·cm以下。

公开(公告)号：US20140291589A1

公开(公告)日：2014-10-02

申请号：US14191609

申请日：2014-02-27

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Kenji HATA ,  Seisuke ATA ,  Kazufumi KOBASHI

IPC: H01B1/24

CPC classification number: H01B1/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B2202/22 ,  C01B2202/34 ,  C01B2202/36 ,  C08K3/04 ,  C08K3/041 ,  C08K2201/011 ,  C08L101/00 ,  C08L27/12

Abstract: Provide is a carbon nanotube composite material and conductive material to solve the problems of the prior art described above by providing a high conductivity and showing excellent durability against repeated stress such as strain. A carbon nanotube composite material of the invention is a conductive material having carbon nanotubes dispersed in a matrix including observing a peak in each region of 110±10 cm−1, 190±10 cm−1 and 200 cm−1 or more in a Raman spectroscopic analysis at a wavelength of 633 nm, and a ratio R/R0 of an electrical resistance R after a load of repeated stress of 100 times at 10% elongation with respect to an electrical resistance R0 prior to applying a load is 5 or more. In addition, a conductive material of the invention comprises these characteristics of the carbon nanotube composite material.

Abstract translation: 提供一种碳纳米管复合材料和导电材料，以通过提供高导电性和显示出对诸如应变的重复应力显示出优异的耐久性来解决上述现有技术的问题。 本发明的碳纳米管复合材料是具有分散在基体中的碳纳米管的导电材料，包括在拉曼中观察到在110±10cm -1，190±10cm -1和200cm -1以上的各个区域的峰值 波长为633nm的光谱分析以及在施加负载之前相对于电阻R0在10％伸长率下重复应力为100次的负载后的电阻R的比R / R0为5以上。 此外，本发明的导电材料包括碳纳米管复合材料的这些特性。

公开(公告)号：US20140221533A1

公开(公告)日：2014-08-07

申请号：US14246195

申请日：2014-04-07

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Kenji HATA ,  Seisuke ATA

IPC: C09K5/14

CPC classification number: C09K5/14 ,  B82Y30/00 ,  C08J5/005 ,  C08J5/042 ,  C08K3/04 ,  C08K3/041 ,  C08K7/06 ,  D01F9/145 ,  Y10S977/742 ,  C08L21/00 ,  C08L101/00 ,  C08L27/12

Abstract: A carbon nanotube composite material having carbon nanotubes and carbon fibers dispersed in a matrix is provided wherein a carbon nanotube group formed from a plurality of the carbon nanotubes is present between the carbon fibers, an average diameter of the carbon fibers is 1 μm or more and 50 μm or less, an average diameter of the carbon nanotubes is 0.7 nm or more and 50 nm or less, the carbon nanotubes are included in a range of 0.01 wt % or more and 30 wt % or less and the carbon fibers are included in a range of 10 wt % or more and 60 wt % or less with respect to 100 wt % of the carbon nanotube composite material, thermal conductivity of the matrix is less than 10 W/mK, and the carbon nanotube composite material includes thermal conductivity in a direction of 10 W/mK or more.

Abstract translation: 提供一种碳纳米管复合材料，其具有分散在基体中的碳纳米管和碳纤维，其中由碳纤维之间存在由多个碳纳米管形成的碳纳米管组，碳纤维的平均直径为1μm以上， 50μm以下，碳纳米管的平均直径为0.7nm以上且50nm以下，碳纳米管的含量为0.01重量％以上且30重量％以下，碳纤维包含在 相对于100重量％的碳纳米管复合材料为10重量％以上且60重量％以下的范围，基体的热导率小于10W / m·K，碳纳米管复合材料包含导热率 方向为10W / mK以上。

公开(公告)号：US20140093694A1

公开(公告)日：2014-04-03

申请号：US14095049

申请日：2013-12-03

Applicant: National Institute of advanced Industrial Science and Technology

Inventor： Kenji HATA ,  Yuuhei HAYAMIZU ,  Takeo YAMADA

IPC: C01B31/02

CPC classification number: C01B31/022 ,  B81B2203/0127 ,  B81C1/0038 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/158 ,  C01B2202/08 ,  C01B2202/10 ,  Y10T156/1028 ,  Y10T156/1041 ,  Y10T428/24479 ,  Y10T428/24521 ,  Y10T428/24612 ,  Y10T428/24851 ,  Y10T428/249924 ,  Y10T428/30

Abstract: A method of producing a carbon nanotube film structure having a substrate and a carbon nanotube layer, comprises a placing step of placing a carbon nanotube film comprising a plurality of carbon nanotubes aligned in one direction within a film plane on the substrate; and a densifying step of applying a densifying treatment to the carbon nanotube film thereby forming the carbon nanotube layer having the weight density of the carbon nanotube to 0.1 g/cm3 or more. Thus, a problem of island-like shrinkage caused while a highly densified CNT layer is being manufactured is solved, and a high-quality CNT film structure wherein the aligned CNT layer having a high density and uniform thickness is deposited on the substrate.

Abstract translation: 一种具有基板和碳纳米管层的碳纳米管膜结构体的制造方法，其特征在于，包括：在基板的膜面内配置包含在一个方向上排列的多个碳纳米管的碳纳米管膜的放置工序; 以及对碳纳米管膜进行致密处理的致密化步骤，从而形成碳纳米管的重量密度为0.1g / cm 3以上的碳纳米管层。 因此，解决了在制造高度致密化的CNT层时引起的岛状收缩的问题，并且在基板上沉积具有高密度和均匀厚度的排列CNT层的高质量CNT膜结构。

公开(公告)号：US20130337707A1

公开(公告)日：2013-12-19

申请号：US13916957

申请日：2013-06-13

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Kenji HATA ,  Don N. FUTABA

IPC: C01B31/00

CPC classification number: C01B32/158 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/168 ,  C01B32/174 ,  C01P2004/03 ,  C01P2004/13 ,  C01P2004/45 ,  C01P2004/50 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/13 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/32 ,  C01P2006/80 ,  Y10T428/2982 ,  Y10T442/10

Abstract: The present invention is a carbon nanotube aggregate having a three-dimensional shape. The carbon nanotube aggregate having a three-dimensional shape includes a first surface, a second surface and a side surface, wherein a carbon nanotube of the first surface has a Herman orientation coefficient greater than −0.1 and smaller than 0.2, a carbon nanotube of the second surface has a Herman orientation coefficient greater than −0.1 and smaller than 0.2, and a carbon nanotube of the side surface has degree of orientation in which a Herman orientation coefficient is 0.2 or more and 0.99 or less, and the first surface and second surface are mutually arranged in parallel and the side surface is perpendicular with respect to the first surface and second surface.

Abstract translation: 本发明是具有三维形状的碳纳米管集合体。 具有三维形状的碳纳米管集合体包括第一表面，第二表面和侧表面，其中第一表面的碳纳米管的Herman取向系数大于-0.1且小于0.2，碳纳米管 第二表面的Herman取向系数大于-0.1且小于0.2，并且侧表面的碳纳米管具有Herman取向系数为0.2以上且0.99以下的取向度，第一表面和第二表面 平行地相互排列并且侧表面相对于第一表面和第二表面垂直。

公开(公告)号：US20130299212A1

公开(公告)日：2013-11-14

申请号：US13928840

申请日：2013-06-27

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Kenji HATA ,  Takeo YAMADA ,  Chandramouli SUBRAMANIAM

IPC: H01B1/00 ,  C25D7/00

CPC classification number: H01B1/00 ,  B82Y30/00 ,  C25D5/02 ,  C25D5/10 ,  C25D5/50 ,  C25D5/54 ,  C25D7/00 ,  C25D7/006 ,  H01B1/02 ,  H01B1/04 ,  H01B1/18

Abstract: Provided are a CNT plating metal composite with high conductivity and wherein metal plating is plated onto the inside of a high-density CNT aggregate, and a production method for same. Also provided is a method for patterning the CNT plating metal composite. A CNT metal composite is provided including a CNT aggregate formed by adhering a metal onto a plurality of CNTs, wherein when an X-ray diffraction analysis is performed using a Cu-Kα ray as a radiation source, an intensity ratio between a peak having the greatest intensity belonging to the metal and a peak having the greatest intensity belonging to an oxide of the metal is 10 or more and the volume resistance is 2×10−6 Ωcm or more and 5×10−3 Ωcm or less.

Abstract translation: 提供一种具有高导电性的CNT电镀金属复合材料，其中金属电镀被镀在高密度CNT集合体的内部及其制造方法。 还提供了用于图案化CNT电镀金属复合材料的方法。 提供了一种CNT金属复合体，其包括通过将金属粘附到多个CNT上形成的CNT集合体，其中当使用Cu-Kalpha射线作为辐射源进行X射线衍射分析时，具有 属于金属的最大强度和属于金属的氧化物的具有最大强度的峰值为10以上，体积电阻为2×10 -6Ω以上5×10 -3Ω以下。

公开(公告)号：US20130176659A1

公开(公告)日：2013-07-11

申请号：US13687222

申请日：2012-11-28

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Kenji HATA ,  Ali IZADI-NAJAFABADI

IPC: H01G11/04

CPC classification number: H01G11/04 ,  B82Y30/00 ,  H01G11/36 ,  H01G11/70 ,  H01G11/82 ,  Y02E60/13

Abstract: An electric double-layer capacitor comprises a first polarizing electrode and a second polarizing electrode including a carbon nanotube aggregate formed by aggregating a plurality of carbon nanotubes and an electrolyte solution being immersed between the plurality of carbon nanotubes, the first polarizing electrode and the second polarizing electrode are provided with a conductivity of 0.5 S/cm; an electrode partially connected to the first polarizing electrode and the second polarizing electrode; and a separator arranged between the first polarizing electrode and the second polarizing electrodes; wherein the carbon nanotube aggregate has a relative surface area of 800 m2/g or more and 2,600 m2/g or less, a density of 0.5 g/cm3 or more and 1.5 g/cm3 or less and a pore size distribution maximum of 1 nm or more and 10 nm or less.

Abstract translation: 电双层电容器包括第一极化电极和第二极化电极，所述第二极化电极包括通过聚集多个碳纳米管而形成的碳纳米管集合体和浸渍在所述多个碳纳米管之间的电解质溶液，所述第一极化电极和所述第二极化 电极的电导率为0.5S / cm; 部分地连接到第一极化电极和第二极化电极的电极; 以及分隔件，设置在所述第一极化电极和所述第二极化电极之间; 其中所述碳纳米管集合体的相对表面积为800m 2 / g以上且2600m 2 / g以下，密度为0.5g / cm 3以上至1.5g / cm 3以下，孔径分布最大值为1nm 以上且10nm以下。