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公开(公告)号：US5959161A
公开(公告)日：1999-09-28
申请号：US179688
申请日：1998-10-27
IPC分类号： C07B57/00 , A01N31/04 , C07C29/00 , C07C29/09 , C07C29/14 , C07C29/159 , C07C29/56 , C07C29/78 , C07C29/86 , C07C35/08 , C07C45/45
CPC分类号： C07C29/00 , C07C29/09 , C07C2101/14
摘要： To offer a method of producing useful para-menthane-3,8-diol having the excellent repellent action to harmful living things, including noxious insects, in high purity and high yield, simply, and economically by the use of citronellal as a raw material compound.The above-mentioned problems are resolved by the production method of this invention wherein citronellal is treated with aqueous sulfuric acid solution of 0.02 to 1.0 wt. % in concentration to produce para-menthane-3,8-diol. In case of recovering the produced para-menthane-3,8-diol, a method is preferably adopted, wherein after the reaction product is extracted with an aliphatic hydrocarbon solvent of 5 to 8 in carbon number, the extract is cooled down at temperature higher than the melting point of said aliphatic hydrocarbon solvent and of -10.degree. C. or less to crystallize para-menthane-3,8-diol.
摘要翻译： 提供一种生产有效的对 - 薄荷烷-3,8-二醇的方法，其以高纯度和高产率，有效地利用香茅醛作为原料，对有害生物（包括有毒昆虫）具有优异的驱避作用 复合。 通过本发明的制备方法解决了上述问题，其中香茅醛用0.02-1.0wt。的硫酸水溶液处理。 产生对偏苯甲烷-3,8-二醇的浓度为％。 在回收生成的对 - 薄荷烷-3,8-二醇的情况下，优选采用方法，其中反应产物用碳数为5至8的脂族烃溶剂萃取后，将提取物在更高温度下冷却 比所述脂族烃溶剂的熔点低-10℃或更低以使对 - 薄荷烷-3,8-二醇结晶。
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公开(公告)号：US5780649A
公开(公告)日：1998-07-14
申请号：US706282
申请日：1996-09-04
申请人： Yoshifumi Yuasa , Masao Konno , Noboru Sano
发明人： Yoshifumi Yuasa , Masao Konno , Noboru Sano
IPC分类号： C07B53/00 , C07D307/20 , C07D307/33 , C07D307/32 , C07D307/02
CPC分类号： C07D307/33 , C07D307/20
摘要： A process for preparing optically active 3-hydroxy-.gamma.-butyrolactone or optically active 3-hydroxytetrahydrofuran through a short route and by using an easily available and inexpensive starting material and an inexpensive reagent easy to handle is disclosed. The process comprises cyclizing an optically active compound represented by formula (II): ##STR1## wherein Q represents an alkoxycarbonyl group having 1 to 4 carbon atoms or a hydroxymethyl group; X represents a halogen atom; and the asterisk * means an asymmetric carbon atom, under an acidic condition.
摘要翻译： 公开了一种通过短路线制备光学活性3-羟基-γ-丁内酯或光学活性3-羟基四氢呋喃的方法，并且通过使用易于获得且廉价的原料和易于处理的便宜的试剂。 该方法包括使由式（II）表示的光学活性化合物环化：其中Q表示具有1至4个碳原子的烷氧基羰基或羟甲基; X表示卤原子; 且在酸性条件下，星号*表示不对称碳原子。
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13.发明申请公开(公告)号：US20080213451A1
公开(公告)日：2008-09-04
申请号：US11991806
申请日：2006-09-08
申请人： Miharu Ogura , Yoshihiro Yaguchi , Makoto Emura , Toshihiro Takeda , Yoshifumi Yuasa , Shigeyuki Sasaki
发明人： Miharu Ogura , Yoshihiro Yaguchi , Makoto Emura , Toshihiro Takeda , Yoshifumi Yuasa , Shigeyuki Sasaki
CPC分类号： C11D3/50 , A23L27/2022 , A61K8/46 , A61Q11/00 , A61Q13/00 , A61Q19/00 , C11B9/0011
摘要： The present invention relates to a flavor composition or fragrance composition which can satisfy diversified requirements for flavored products, as well as to a flavor-improving agent which can improve the quality and release of aroma of a beverage or food. More particularly, the present invention relates to a flavor composition or fragrance composition which comprises an optically active S-alkyl 2-methylbutanethioate as an active ingredient, a flavor- or fragrance-added product, a flavor-improving agent which comprises an optically active S-alkyl 2-methylbutanethioate as an active ingredient, and a beverage or food having an improved flavor. The optically active S-alkyl 2-methylbutanethioate includes S-alkyl (R)-2-methylbutanethioate and S-alkyl (S)-2-methylbutanethioate.
摘要翻译： 本发明涉及可以满足调味产品多样化要求的风味组合物或香料组合物，以及能够改善饮料或食品香气质量和释放的风味改善剂。 更具体地说，本发明涉及一种风味组合物或香料组合物，其包含光学活性的2-甲基丁硫醇S-烷基酯作为活性成分，加入香料或香料的产品，风味剂改进剂，其包含光学活性的S - 烷基2-甲基丁硫醇盐作为活性成分，以及具有改善风味的饮料或食品。 光学活性的2-甲基丁硫醇S-烷基酯包括（R）-2-甲基丁硫烷酸S-烷基酯和（S）-2-甲基丁硫醇S-烷基酯。
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14.发明申请公开(公告)号：US20050001733A1
公开(公告)日：2005-01-06
申请号：US10731060
申请日：2003-12-09
CPC分类号： G08C23/04 , G08C17/02 , G08C19/28 , G08C2201/20
摘要： Herein disclosed is a wireless electric appliance system, comprising an electric appliance having assigned thereto a control code, and a wireless remote control apparatus having assigned thereto an operation code to be matched with the control code. The electric appliance is operably connected with the electric appliance. The electric appliance includes storage means for storing therein the control code; and transmitting means for transmitting a signal including the control code stored in the storage means to the wireless remote control apparatus. The wireless remote control apparatus includes storage means for storing therein the operation code; receiving means for receiving the signal including the control code assigned to the electric appliance from the electric appliance; judging means for judging whether or not the operation code stored in the storage means is matched with the control code of the signal received by the receiving means, and control means for controlling the operation of the wireless remote control apparatus based on a result judged by the judging means.
摘要翻译： 这里公开的是一种无线电器系统，包括具有控制码的电器，以及具有与控制码匹配的操作码的无线遥控装置。 电器与电器可操作地连接。 该电器包括用于在其中存储控制码的存储装置; 以及发送装置，用于将包括存储在存储装置中的控制码的信号发送到无线遥控装置。 无线遥控装置包括用于在其中存储操作码的存储装置; 接收装置，用于从电器接收包括分配给电器的控制代码的信号; 用于判断存储在存储装置中的操作码是否与由接收装置接收的信号的控制码相匹配的判断装置，以及用于根据由所述接收装置判断的结果来控制无线遥控装置的操作的控制装置 判断手段。
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15.发明授权(S)-2-aralkyl-3-chloropropionic acid and process for the preparation thereof 失效（S）-2-芳烷基-3-氯丙酸及其制备方法
公开(公告)号：US5587510A
公开(公告)日：1996-12-24
申请号：US448310
申请日：1995-05-23
申请人： Masao Konno , Yoshifumi Yuasa
发明人： Masao Konno , Yoshifumi Yuasa
摘要： The present invention provides a novel 2-aralkyl-3-chloropropionic acid and a process for the preparation thereof. A novel 2-aralkyl-3-chloropropionic acid is represented by the general formula (1): ##STR1## and can be prepared by asymmetrically hydrogenating a (Z)-2-aralkylidene-3-chloropropionic acid represented by the general formula (II): ##STR2## with a complex of a bidentate phosphine with ruthenium as a catalyst in the presence of a tertiary amine.
摘要翻译： 本发明提供新的2-芳烷基-3-氯丙酸及其制备方法。 新型2-芳烷基-3-氯丙酸由通式（1）表示：将由通式（II）表示的（Z）-2-芳烷叉-3-氯丙酸： 其中在叔胺存在下，二齿膦与钌作为催化剂的络合物。
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