ITQ-31 crystalline solid, and a process for its preparation
    17.
    发明授权
    ITQ-31 crystalline solid, and a process for its preparation 失效
    ITQ-31结晶固体及其制备方法

    公开(公告)号:US07025948B2

    公开(公告)日:2006-04-11

    申请号:US11102879

    申请日:2005-04-11

    IPC分类号: C01B39/48

    CPC分类号: C01B37/005 C01B39/06

    摘要: The invention concerns a crystalline solid, designated ITQ-31, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxide, defined by the general formula XO2: mYO2:pZ2O3:qR:sF, in which R represents an organic nitrogen-containing template, X represents one or more tetravalent elements other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.

    摘要翻译: 本发明涉及一种称为ITQ-31的结晶固体,其具有以下给出的X射线衍射图。 所述固体具有以通式XO 2定义的氧化物摩尔数表示为无水碱的化学组成:mYO 2:pZ 2 qR:sF,其中R表示有机含氮模板,X表示一种或多种除锗以外的四价元素,Y表示锗,Z表示至少一种三价元素 F是氟。

    ITQ-31 crystalline solid, and a process for its preparation
    18.
    发明申请
    ITQ-31 crystalline solid, and a process for its preparation 失效
    ITQ-31结晶固体及其制备方法

    公开(公告)号:US20050244330A1

    公开(公告)日:2005-11-03

    申请号:US11102879

    申请日:2005-04-11

    CPC分类号: C01B37/005 C01B39/06

    摘要: The invention concerns a crystalline solid, designated ITQ-31, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxide, defined by the general formula XO2: mYO2:pZ2O3:qR:sF, in which R represents an organic nitrogen-containing template, X represents one or more tetravalent elements other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.

    摘要翻译: 本发明涉及一种称为ITQ-31的结晶固体,其具有以下给出的X射线衍射图。 所述固体具有以通式XO 2定义的氧化物摩尔数表示为无水碱的化学组成:mYO 2:pZ 2 qR:sF,其中R表示有机含氮模板,X表示一种或多种除锗以外的四价元素,Y表示锗,Z表示至少一种三价元素 F是氟。

    Catalyst based on a material with a hierarchical porosity comprising silicon, and a process for hydrocracking/hydroconversion and hydrotreatment of hydrocarbon feeds
    19.
    发明授权
    Catalyst based on a material with a hierarchical porosity comprising silicon, and a process for hydrocracking/hydroconversion and hydrotreatment of hydrocarbon feeds 有权
    基于具有分层孔隙率的材料的催化剂,包括硅,以及用于烃进料的加氢裂化/加氢转化和加氢处理的方法

    公开(公告)号:US08821714B2

    公开(公告)日:2014-09-02

    申请号:US12515862

    申请日:2007-10-29

    IPC分类号: C10G47/02

    摘要: The invention describes a catalyst comprising at least one material with a hierarchical porosity comprising silicon and at least one hydrodehydrogenating element from group VIB and/or group VIII of the periodic table of the elements. Said material with a hierarchical porosity comprising silicon is constituted by at least two elementary spherical particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 30 nm, said elementary spherical particles having a maximum diameter of 100 μm. The matrix based on silicon oxide may contain aluminum. The catalyst also optionally comprises at least one doping element in a controlled quantity selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally an element from group VIIA. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.

    摘要翻译: 本发明描述了一种催化剂,其包含至少一种具有分层孔隙率的材料,其包含硅和来自元素周期表的VIB族组和/或VIII族的至少一种脱氢元素。 具有包含硅的层状孔隙的所述材料由至少两个基本球形颗粒构成,每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体,其被介孔结构化,具有 孔径在1.5至30nm范围内,具有厚度在1至30nm范围内的非晶壁,所述基本球形颗粒的最大直径为100μm。 基于氧化硅的基体可以含有铝。 催化剂还任选地包含选自磷,硼和硅的受控量的至少一种掺杂元素,任选地,元素周期表的第VB族元素中的至少一种元素,以及任选的来自VIIA族的元素。 本发明还涉及使用所述催化剂的加氢裂化/加氢转化和加氢处理方法。